Rchr

J-GLOBAL ID：200901050987444075 Update date: Jan. 30, 2024

Tobita Hiromi

トビタヒロミ | Tobita Hiromi

Affiliation and department：
Job title： Program-Specific Professor
Homepage URL (2)： http://db.tohoku.ac.jp/whois/detail/0e6ea5aef10652e5d7231398c741b822.html , http://db.tohoku.ac.jp/whois/e_detail/0e6ea5aef10652e5d7231398c741b822.html

Research field (1)： Inorganic and coordination chemistry

Research keywords (5)： Photochemistry , Metal Cluster , Endohedral Metallofullerene , Transition Metal Complex , Silylene complex

Research theme for competitive and other funds (29)：

2004 - 現在 Synthesis, properties, and chemical modification of endohedral metallofullerenes
1995 - 現在 Synthesis, Structures, Properties, and Reactivities of Complexes Having Peculiar Transition Metal-Main Group Element Bonds
1986 - 現在 Syntheses, Structures, properties, and Reactivities of Novel Transition Metal-Main Group Element Clusters
1985 - 現在 Synthesis, Structrures, Properties, and Reactivities of Transition Metal Complexes Containing Organosilicon, -germanium, and -tin Ligands
2018 - 2020 Development of Molecular Device Functions Making Use of Unique Orbital Interaction between Lithium Encapsulated Fullerene and Transition Metals

2015 - 2020 Development of Molecular Conversion Reactions Taking Advantage of the Reactivity of Transition Metal-Silicon/Germanium Multiple Bonds

2015 - 2018 Syntheses of active metal complexes that bear low-valent Group 14 element species as a Lewis acidic reactive site

2012 - 2017 Syntheses and Catalytic Function of Transition-metal Complexes Having Reactive Heavier Main Group ElementMetal Multiple Bonds

2011 - 2012 Development of the Chemistry of Transition Metal Complexes UsingLithium Encapsulated Fullerene as a Ligand

2010 - 2012 Reaction Search and Function Development for the Unsaturated Bonding Systems between Transition Metals and Heavier Group 14 Elements

2006 - 2009 Construction and Functions of the Unsaturated Bonds between Heavier Main Group Elements and Transition Metals

2006 - 2007 Construction of Novel Silicon-Transition Metal Multiple Bonds, Elucidation of the Mechanisms for Their Reactions, and Their Expansion to Catalytic Reactions

2002 - 2005 Construction and Functions of Dynamic Complexes Composed of Transition Metal/Efetero-Element Systems

2003 - 2004 ケイ素およびリンを含む小員環状遷移金属錯体の合成とその無機化合物合成への応用

2002 - 2004 Development of Novel Transformation Reactions of Silicon Compounds Utilizing Specific Reactivity of Transition Metal-Silylene Complexes

2002 - 2003 多様な典型元素-遷移金属結合を環内に含む多元素メタラサイクルの合成と性質

2001 - 2001 第3周期以降の多様な典型元素を環内に含む新規メタラサイクルの合成と性質

2000 - 2001 Synthesis and Properties of Transition Metal Complexes Having New Chelate Ligands with Silicon as a Coordinating Atom

2000 - 2000 混合金属型遷移金属-カルコゲンユニットの選択的集積化と活性化

1999 - 2000 単核シリレン錯体から出発する非対称なシリレン架橋二核錯体の合成

1997 - 2000 The Chemistry of Linkages between Main Group Elements and Transition Metals

1985 - 1999 Synthesis, Structures, Properties, and Reactivities of Transition Metal Complexes Coordinated with Novel Cyclopentadienyl Derivatives

1997 - 1999 Specific Chemical Conversion Based on the Cooperative Effect of Two Transition Metal Fragments in Close Proximity

1997 - 1998 Synthesis of Stable Silylene and Germylene Complexes and the Mechanistic Studies on Catalytic Reactions Utilizing Them

1995 - 1996 Chemistry of Transition Metal Supramolecules

1992 - 1992 錯体合成を指向したかさ高い一級および二級シランと遷移金属との反応の研究

1991 - 1991 シリリンおよびゲルミリンを配位子とする遷移金属錯体の合成と性質

1990 - 1990 置換シクロペンタジエニル配位子の特徴を生かした錯体の動的挙動のNMR的研究

1989 - 1990 Photo Chemical Syntheses and Reactivities of Organometallic Compounds Containing 4B Elements

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Papers (199)：

Keita Sato, Takashi Komuro, Tomohiro Osawa, Hisako Hashimoto, Hiromi Tobita. Iridium Complexes with a Naphthyridine-Based Si,N-Ligand: Synthesis and Catalytic Activity toward Olefin Hydrogenation. Organometallics. 2022. 41. 18. 2612-2621
Takashi Komuro, Daiki Mochizuki, Hisako Hashimoto, Hiromi Tobita. Iridium and rhodium complexes bearing a silyl-bipyridine pincer ligand: synthesis, structures and catalytic activity for C-H borylation of arenes. Dalton Transactions. 2022
Takashi Komuro, Junpei Asagami, Hironori Higashi, Keita Sato, Hisako Hashimoto, Hiromi Tobita. Catalysts for Regio- and Stereoselective C(sp3)-H Deuteration of Tricyclohexylphosphine with Benzene-d6 Generated via Dehydrochlorination of Chlorido(dihydrido)iridium Complexes Containing a Xanthene-Based Bis(silyl) Chelate Ligand. Organometallics. 2021
Keita Sato, Takashi Komuro, Hisako Hashimoto, Hiromi Tobita. Bifunctional Rhodium Complex Featuring a Silyl-1,8-naphthyridine Si,N-Chelate Ligand: Cooperation of Metal and Pendant Base for Capture and Bond-weakening of BH3. Chemistry Letters. 2020. 49. 11. 1431-1434
Tara Prasad Dhungana, Hisako Hashimoto, Mausumi Ray, Hiromi Tobita. Synthesis of a Molybdenum Hydrido(hydrogermylene) Complex and Its Conversion to a Germylyne Complex: Another Route through Dehydrogenation with Nitriles. Organometallics. 2020

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MISC (30)：

飛田博実. 遷移金属-ケイ素/ゲルマニウム多重結合の化学二重結合と三重結合の構築法および反応性. Organometallic News. 2016. 1. 8-15
青柳忍, 佐道祐貴, 西堀英治, 澤博, 岡田洋史, 飛田博実, 笠間泰彦, 北浦良, 篠原久典. 「Li@C₆₀」(PF₆)の構造と相転移. 日本物理学会講演概要集. 2012. 67. 1. 922
Hisako Hashimoto, Hiromi Tobita. Heavier Analogs of Carbene Complexes: Syntheses of a New Type of Silylene and Germylene Complexes and Their Reactions with Unsaturated Organic Compounds. JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN. 2012. 70. 2. 131-141
飛田博実. 遷移金属-ケイ素三重結合の構築新しいケイ素(II)化学種を鍵前駆体として. 化学. 2011. 66. 10. 64-65
飛田博実. そなえよつねに(Be Prepared)-大震災からの教訓-. ケイ素化学協会誌. 2011. 28. 3-4

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Books (16)：

Efficient Methods for Preparing Silicon Compounds
Academic Press 2016
基本無機化学第3版
東京化学同人 2016
2013 ナノカーボン技術大全 “Li内包フラーレンの大量合成技術”
2013
“現代ケイ素化学” 体系的な基礎概念と応用に向けて
化学同人 2013
有機金属化学の最前線-多様な元素を使いこなす- 現代化学増刊44
2011

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Lectures and oral presentations (52)：

Fascinated by Transition Metal-Silicon/Germanium Multiple Bonds -From Synthesis to Catalysis-
(2019)
Dehydrogenative Formation of Metal-E (E = Ge, Si) Triple-Bonded Complexes from REH3 and Their Reactivity to Organic Molecules
(16th International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019) 2019)
Hydroboration of Nitriles Catalyzed by a Ruthenium-Bis(silyl) Chelate Complex and Subsequent Deborylative N-Arylation
(7th Asian Silicon Symposium 2019)
Reactions of Transition Metal-Silicon Triple-Bonded Complexes with Various Unsaturated Organic Molecules
(The 18th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry 2018)
Recent Developments in the Chemistry of Tungsten-Germanium/Silicon Triple -Bonded Complexes
(43rd International Conference on Coordination Chemistry (ICCC2018) 2018)

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Education (2)：

- 1982 Tohoku University Graduate School, Division of Natural Science 化学
- 1977 Tohoku University Faculty of Science 化学第二学科

Professional career (1)：

理学博士 (Tohoku University)

Work history (9)：

2022/04 - 現在 Tohoku University Institute for Excellence in Higher Education Program-Specific Professor
2021/08 - 2022/03 Tohoku University Institute for Excellence in Higher Education
2001/06 - 2020/03 Graduate School of Science, Tohoku University Professor
1995/04 - 2001/05 Graduate School of Science, Tohoku University Associate Professor
1992/04 - 1995/03 Faculty of Science, Tohoku University Associate Professor

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Committee career (24)：

2021/06 - 現在公益財団法人日本化学研究会理事長
2006/04 - 現在 The Society of Silicon Chemistry Japan 常任理事
2006/04 - 現在ケイ素化学協会常任理事
2004/04 - 現在 National Institution for Academic Degrees and University Evaluation 学位審査会専門委員
2004/04 - 現在大学評価・学位授与機構学位審査会専門委員

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Awards (3)：

2019/11 - ケイ素化学協会ケイ素化学協会賞特異な遷移金属-ケイ素/ゲルマニウム結合を持つ錯体の合成と性質
2010/07/23 - International Conference on Organometallic Chemistry 24th International Conference on Organometallic Chemistry Poster Award
1988/04 - 日本化学会 The Chemical Society of Japan Award for Young Chemists 興味ある構造を有する新規な有機ケイ素化合物の合成,反応およびその遷移金属錯体化学への応用

Association Membership(s) (5)：

日本化学研究会 , 近畿化学協会 , ケイ素化学協会 , Japan Society of Coordination Chemistry , 日本化学会

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