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J-GLOBAL ID:200902000162093802   Reference number:85A0444463

Reaction of cyanomethyl complex (η5-C5H5)Re(NO)(PPh3)(CH2CN) with n-BuLi/TMEDA; Generation, stereospecific alkylation, and basicity of a transition-metal-substituted carbanion.

n-BuLi/TMEDAとシアノメチル錯体(η5-C5H5)Re(NO)(PPh3)(CH2CN)の反応 遷移金属置換カルバニオンの発生,立体特異的アルキル化および塩基性度
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Material:
Volume: 107  Issue: 13  Page: 4103-4104  Publication year: Jun. 26, 1985 
JST Material Number: C0254A  ISSN: 0002-7863  CODEN: JACSAT  Document type: Article
Article type: 短報  Country of issue: United States (USA)  Language: ENGLISH (EN)
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Category name(code) classified by JST.
6A and 7A groups  ,  Group 6 and group 7 organic compounds  ,  Stereochemistry of organic reaction  ,  Acid-base equilibrium 

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