Art

J-GLOBAL ID：200902000184454620   Reference number：88A0324349

Synthesis and crystal structure of two trinuclear molybdenum clusters containing a loose coordination site, {Mo₃(μ₃-S)(μ-S)₃[S₂P(OEt)₂]₄-(C₃H₃ON)} CH₃CN (I) and {Mo₃-(μ₃-O)(μ-S)₃[S₂P(OEt)₂]₄-(C₃H₃ON)] (II).

自由な配座サイトを持つ二種の三核モリブデンクラスタ{Mo₃(μ₃-S)(μ-S)₃[S₂P(OEt)₂]₄(C₃H₃ON)}・CH₃CN(I)と{Mo₃(μ₃-O)(μ-S)₃[S₂P(OEt)₂]₄(C₃H₃ON)}(II)の合成と結晶構造

Author (5)： LU S F (Fujian Inst. Research on the Structure of Matter, Academia Sinica, Fuzhou, CHN) ,  SHANG M Y (Fujian Inst. Research on the Structure of Matter, Academia Sinica, Fuzhou, CHN) ,  HUANG J Q (Fujian Inst. Research on the Structure of Matter, Academia Sinica, Fuzhou, CHN) ,  HUANG J L (Fujian Inst. Research on the Structure of Matter, Academia Sinica, Fuzhou, CHN) ,  LU J X (Fujian Inst. Research on the Structure of Matter, Academia Sinica, Fuzhou, CHN)
Material： Scientia Sinica. Series B. Chemical, Biological, Agricultural, Medical & Earth Sciences  (Chugoku Kagaku)
Volume： 31  Issue： 2  Page： 147-160  Publication year： Feb. 1988 
JST Material Number： D0497B  Document type： Article
Article type： 原著論文  Country of issue： China (CHN)  Language： ENGLISH (EN)

Thesaurus term： molybdenum complex ,  polynuclear complex ,  bridged complex ,  molecular compound ,  oxo complex ,  thio complex ,  chemical synthesis ,  complex formation ,  molecular cluster ,  crystal structure ,  X-ray diffraction ,  single crystal ,  molecular structure ,  monoclinic system ,  triclinic system ,  crystal packing ,  mass spectrum ,  infrared absorption spectrum ,  NMR ,  phosphoric acid derivative ,  thio acid ,  inorganic acid ester ,  nitrogen heterocyclic compound ,  oxygen heterocyclic compound ,  deoxysugar ,  aliphatic nitrile
Semi thesaurus term： thermal parameter ,  thiophosphate(ester) ,  oxazole ,  acetonitrile

JST classification (2)： 6A and 7A groups  (CE01080F) ,  Crystal structure of complex of transition metals(excluding iron group)  (BK09030X)

Terms in the title (5)： 配座 ,  核 ,  モリブデン ,  クラスタ ,  結晶構造