Art

J-GLOBAL ID：200902001844467549   Reference number：92A0787170

Reactions of 1,2-Propadienyl Sulfides with Aldehydes and Acetals Catalyzed by BF₃ OEt₂.

BF₃・OEt₂を触媒とする1,2-プロパジエニルスルフィドとアルデヒドおよびアセタールとの反応

Author (3)： NARASAKA K (Univ. Tokyo, Tokyo) ,  SHIBATA T (Univ. Tokyo, Tokyo) ,  HAYASHI Y (Univ. Tokyo, Tokyo)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 65  Issue： 10  Page： 2825-2830  Publication year： Oct. 1992 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： acid catalytic reaction ,...
Semi thesaurus term： Aldol condensation ,...

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=92A0787170&from=J-GLOBAL&jstjournalNo=G0450A") }}

JST classification (2)： Aliphatic sulfides,disulfides  (CF03130C) ,  Aliphatic aldehydes  (CF03180F)

Substance index (30)： 1-フェニル-2-(メチルチオ)-2,3-ブタジエン ,  2-メチル-3-(メチルチオ)-3,4-ペンタジエン ,  2-(メチルチオ)-2,3-ブタジエン ,  (3Z)-1,4-Diphenyl-2-methylene-3-(methylthio)-3-buten-1-ol ,  (5Z)-1,6-Diphenyl-4-methylene-5-(methylthio)-5-hexen-3-ol ,  (5Z)-2-Methyl-4-methylene-5-(methylthio)-6-phenyl-5-hexen-3-ol ,  (3Z)-1-Cyclohexyl-4-phenyl-2-methylene-3-(methylthio)-3-buten-1-ol ,  1-Phenyl-4-methyl-2-methylene-3-(methylthio)-3-penten-1-ol ,  1-Phenyl-6-methyl-4-methylene-5-(methylthio)-5-hepten-3-ol ,  2,6-Dimethyl-4-methylene-5-(methylthio)-5-hepten-3-ol ,  1-Cyclohexyl-4-methyl-2-methylene-3-(methylthio)-3-penten-1-ol ,  2-Methyl-4-methylene-3-(methylthio)-2,6-decadien-5-ol ,  1-Phenyl-2-methylene-3-(methylthio)-3-buten-1-ol ,  1-Phenyl-4-methylene-5-(methylthio)-5-hexen-3-ol ,  2-Methyl-4-methylene-5-(methylthio)-5-hexen-3-ol ,  1-Cyclohexyl-2-methylene-3-(methylthio)-3-buten-1-ol ,  1-(Trimethylsilyl)-1-(methylthio)-1,2-propanediene ,  1-(Trimethylsilyl)-3-hydroxy-2-methylene-3-phenylpropan-1-one ,  1-(Trimethylsilyl)-3-hydroxy-2-methylene-5-phenylpentan-1-one ,  1-(Trimethylsilyl)-3-hydroxy-2-methylenedodecan-1-one ,  1-(Trimethylsilyl)-3-hydroxy-2-methylene-3-cyclohexylpropan-1-one ,  1-(Trimethylsilyl)-3-hydroxy-2-methylene 5-phenyl-4-penten-1-one ,  1-(tert-Butyldimethylsilyl)-1-(methylthio)-1,2-propanediene ,  1-(Trimethylsilyl)-3-methoxy-2-methylene-3-phenylpropan-1-one ,  1-(Trimethylsilyl)-3-methoxy-2-methylene-5-phenyl-4-penten-1-one ,  1-(Trimethylsilyl)-3-methoxy-2-methylene-5-phenylpentan-1-one ,  1-(Trimethylsilyl)-3-methoxy-2-methylene-3-cyclohexylpropan-1-one ,  1-(tert-Butyldimethylsilyl)-3-methoxy-2-methylene-3-phenylpropan-1-one ,  1-(tert-Butyldimethylsilyl)-3-methoxy-2-methylene-5-phenylpentan-1-one ,  1-(tert-Butyldimethylsilyl)-3-methoxy-2-methylene-3-cyclohexylpropan-1-one

Reference (32)：

• 1) a) D. J. Pasto, Tetrahedron, 40, 2805 (1984).
•  b) W. Smadja, Chem. Rev., 83, 263 (1983).
•  c) “The Chemistry of Ketenes, Allenes, and Related Compounds,” ed by S. Patai, John Wiley & Sons, Chichester (1980), Part 1 and 2.
• 2) E. J. Corey, C.-M. Yu, and D.-H. Lee, J. Am. Chem. Soc., 112, 878 (1990);
•  M. Suzuki, Y. Morita, and R. Noyori, J. Org. Chem., 55, 441 (1990);

Terms in the title (4)： BF3 ,  触媒 ,  アルデヒド ,  アセタール