Art

J-GLOBAL ID：200902001934578960   Reference number：90A0718686

An improved cyanoalkylation method of aldehydes catalyzed by electrogenerated base in a DMF-H₂O system.

DMF-H₂O系における電解塩基を触媒とするアルデヒドのシアノアルキル化の改良法

Author (3)： TORII S (Okayama Univ., Okayama) ,  KAWAFUCHI H (Toyama National Coll. Technology, Toyama) ,  INOKUCHI T (Okayama Univ., Okayama)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 63  Issue： 8  Page： 2430-2432  Publication year： Aug. 1990 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： condensation reaction ,...
Semi thesaurus term： シアノアルキル化 ,...

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JST classification (3)： Aliphatic aldehydes  (CF03180F) ,  Aromatic monocyclic aldehydes  (CF05160X) ,  Aromatic monocyclic nitriles,isocyanides  (CF05210D)

Substance index (23)： Furfural ,  Thiophene-2-carbaldehyde ,  Benzaldehyde ,  4,8-Dimethyl-7-nonenal ,  Octanal ,  Phenylacetonitrile ,  3-Hydroxy-2-phenyl-3-(furan-2-yl)propanenitrile ,  3-Hydroxy-2-phenyl-3-(thiophen-2-yl)propanenitrile ,  2,3-Diphenyl-3-hydroxypropiononitrile ,  3-Hydroxy-2-phenyl-3-(3,7-dimethyl-6-octen-1-yl)propanenitrile ,  3-Hydroxy-2-phenyl-3-heptylpropanenitrile ,  3-Hydroxy-2-phenyl-3-(furan-2-yl)propanoic acid ethyl ester ,  3-Hydroxy-2-phenyl-3-(thiophen-2-yl)propanoic acid ethyl ester ,  α-(α-Hydroxybenzyl)benzeneacetic acid ethyl ester ,  3-Hydroxy-2-phenyl-3-(3,7-dimethyl-6-octen-1-yl)propanoic acid ethyl ester ,  3-Hydroxy-2-phenyl-3-heptylpropanoic acid ethyl ester ,  3-Hydroxy-2-(phenylthio)-3-(furan-2-yl)propanenitrile ,  3-Hydroxy-2-(phenylthio)-3-(thiophen-2-yl)propanenitrile ,  3-Hydroxy-2-(phenylthio)-3-phenylpropanenitrile ,  3-Hydroxy-2-(phenylthio)-3-(3,7-dimethyl-6-octen-1-yl)propanenitrile ,  3-Hydroxy-2-(phenylthio)-3-heptylpropanenitrile ,  Phenylacetic acid ethyl ,  (Phenylthio)acetonitrile

Reference (11)：

• 1) a) T. Shono, Denki Kagaku, 52, 8 (1984);
•  b) J. H. P. Utley, “Topics in Current Chemistry,” Springer-Verlag, Heidelberg (1987), Vol. 142, p. 131.
• 2) W. J. M. van Tilborg, C. J. Smit, and J. J. Scheele, Tetrahedron Lett., 1977, 2113.
• 3) a) A. J. Bellamy, J. Chem. Soc., Chem. Commun., 1975, 944;
•  b) L. Kistenbrügger, P. Mischke, J. Voss, and G. Wiegand, Liebigs Ann. Chem., 1980, 461.

Terms in the title (9)： DMF ,  H2O ,  電解 ,  塩基 ,  触媒 ,  アルデヒド ,  シア ,  アルキル化 ,  改良法