Art

J-GLOBAL ID：200902165177429881   Reference number：02A0385925

Synthesis of a compound having the essential structural unit for the hetisine-type of aconite alkaloids.

本質的にヘチシン型アコニットアルカロイドと同等の構造ユニットを持つ化合物の合成

Author (2)： MURATAKE H (Res. Foundation Itsuu Lab., Tokyo, JPN) ,  NATSUME M (Res. Foundation Itsuu Lab., Tokyo, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 43  Issue： 16  Page： 2913-2917  Publication year： Apr. 15, 2002 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,...
Semi thesaurus term： *bridged compound

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JST classification (1)： Condensed derivatives of pyrroles  (CF07077C)

Substance index (23)： 1-Bromo-2-(2-iodoethyl)-4-methoxybenzene ,  2-(2-Bromo-5-methoxyphenethyl)-3-(nitromethyl)cyclohexanone ,  6-(2-Bromo-5-methoxyphenethyl)-1,4-dioxaspiro[4.5]decane-7-carbaldehyde ,  (4aS)-7-Methoxy-3,4,4a,9,10,10a-hexahydrospiro[phenanthrene-1(2H),2′-[1,3]dioxolane]-4a-carbaldehyde ,  (4aS)-4aα-(1,3-Dioxolane-2-yl)-7-methoxy-3,4,4a,9,10,10aα-hexahydrospiro[phenanthrene-1(2H),2′-[1,3]dioxolane] ,  (4aR)-4aα-(1,3-Dioxolane-2-yl)-3,4,4a,4bβ,5,6,7,9,10,10aβ-decahydrospiro[phenanthrene-1(2H),2′-[1,3]dioxolane]-7-one ,  (4aR)-4aα-(1,3-Dioxolane-2-yl)-3,4,4a,4bβ,5,6,7,9,10,10aβ-decahydrospiro[phenanthrene-1(2H),2′-[1,3]dioxolane]-7β-ol ,  (4aR)-N,N-Dimethyl-4aα-(1,3-dioxolane-2-yl)-3,4,4a,4bβ,5,6,8a,9,10,10aβ-decahydrospiro[phenanthrene-1(2H),2′-[1,3]dioxolane]-8aβ-acetamide ,  (4aR)-4aα-(1,3-Dioxolane-2-yl)-3,4,4a,4bβ,5,6,8a,9,10,10aβ-decahydrospiro[phenanthrene-1(2H),2′-[1,3]dioxolane]-8aβ-ethanol ,  (4aR)-4aα-(1,3-Dioxolane-2-yl)-8aβ-[2-(pivaloyloxy)ethyl]-3,4,4a,4bβ,5,6,8a,9,10,10aβ-decahydrospiro[phenanthrene-1(2H),2′-[1,3]dioxolane] ,  (1R,11S)-8aα-Bromo-10aα-[2-(pivaloyloxy)ethyl]-11-[2-(trimethylsiloxy)ethoxy]-1α,4bβ-methano-1,4,4aβ,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthrene-8-one ,  (1R,11S)-10aα-[2-(Pivaloyloxy)ethyl]-11-[2-(methoxymethoxy)ethoxy]-1α,4bβ-methano-1,4,4aβ,4b,5,6,7,8,10,10a-decahydrophenanthrene-8-one ,  (1R,11S)-8α-Hydroxy-11-[2-(methoxymethoxy)ethoxy]-1α,4bβ-methano-1,4,4aβ,4b,5,6,7,8,10,10a-decahydrophenanthrene-10aα-ethanol ,  (1R,11S)-8-Methyl-10aα-(2-acetoxyethyl)-11-[2-(methoxymethoxy)ethoxy]-1α,4bβ-methano-1,4,4aβ,4b,5,6,7,9,10,10a-decahydrophenanthrene-9-one ,  (1R,11S)-8-Methyl-9-oxo-10aα-(2-acetoxyethyl)-11-[2-(methoxymethoxy)ethoxy]-1α,4bβ-methano-1,4,4aβ,4b,5,6,7,9,8,8a,10,10a-dodecahydrophenanthrene-8β-carbonitrile ,  (1R,11S)-8-Methyl-9-oxo-10aα-(2-acetoxyethyl)-11-(2-hydroxyethoxy)-1α,4bβ-methano-1,4,4aβ,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthrene-8β-carbonitrile ,  (1R,11S)-8-Methyl-9-oxo-10aα-(2-acetoxyethyl)-11-(2-bromoethoxy)-1α,4bβ-methano-1,4,4aβ,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthrene-8β-carbonitrile ,  (1R,11S)-8-Methyl-9-oxo-10aα-(2-acetoxyethyl)-11-hydroxy-1α,4bβ-methano-1,4,4aβ,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthrene-8β-carbonitrile ,  (1R,13S)-8-Methyl-10aα-(2-hydroxyethyl)-13-hydroxy-1α,4bβ-methano-9,8aβ-(epiminomethano)-1,4,4aβ,4b,5,6,7,8,8a,10a-decahydrophenanthrene-11-carboxylic acid tert-butyl ester ,  (1R,13S)-8-Methyl-10aα-[2-(tert-butoxycarbonyloxy)ethyl]-13-hydroxy-1α,4bβ-methano-9,8aβ-(epiminomethano)-1,4,4aβ,4b,5,6,7,8,8a,10a-decahydrophenanthrene-11-carboxylic acid tert-butyl ester ,  (1R,13S)-8-Methyl-10aα-(2-hydroxyethyl)-13-hydroxy-1α,4bβ-methano-9β,8aβ-(epiminomethano)-1,4,4aβ,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthrene-11-carboxylic acid tert-butyl ester ,  (1R,13S)-8-Methyl-10aα-[2-(benzoyloxy)ethyl]-13-hydroxy-1α,4bβ-methano-9β,8aβ-(epiminomethano)-1,4,4aβ,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthrene-11-carboxylic acid tert-butyl ester ,  16-(Benzoyloxy)-16-demethylene-12,16-secohetisan-12-ene

Terms in the title (3)： アコニットアルカロイド ,  同等 ,  構造ユニット