Art

J-GLOBAL ID：200902212380843098   Reference number：04A0870902

Bromoporphyrins as Versatile Synthons for Modular Construction of Chiral Porphyrins: Cobalt-Catalyzed Highly Enantioselective and Diastereoselective Cyclopropanation

キラルなポルフィリン類のモジュラ型構築用多目的シントンとしてのブロモポルフィリン類 コバルト触媒を用いた高エナンチオ選択的かつジアステレオ選択的なシクロプロパン化

Author (3)： CHEN Y (Univ. Tennessee, Tennessee) ,  FIELDS K B (Univ. Tennessee, Tennessee) ,  ZHANG X P (Univ. Tennessee, Tennessee)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 126  Issue： 45  Page： 14718-14719  Publication year： Nov. 17, 2004 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *macrocyclic compound ,...
Semi thesaurus term： bridged compound

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JST classification (2)： Eight or more-membered heterocyclic compounds  (CF07120T) ,  Cobalt bnd nickel complexes  (CE01092Y)

Substance index (42)： 5,15-Diphenyl-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis(4-tert-butylphenyl)-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis[4-(trifluoromethyl)phenyl]-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis(pentafluorophenyl)-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis(4-acetylphenyl)-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis(2,4,6-trimethylphenyl)-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis(2,6-dimethoxyphenyl)-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis(3,5-dimethoxyphenyl)-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis(3,5-di-tert-butylphenyl)-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis(1-propylbutyl)-10,20-bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  5,15-Bis(2,6-dibromophenyl)-21H,23H-porphyrin ,  (S)-2,2-Dimethylcyclopropanecarboxamide ,  (2R)-1-[(R)-α-Methylbenzyl]aziridine-2β-carboxamide ,  (R)-2-Methoxypropionamide ,  (S)-2-Methoxypropionamide ,  5,15-Diphenyl-10,20-bis[2,6-bis[[(S)-2,2-dimethylcyclopropan-1α-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Diphenyl-10,20-bis[2,6-bis[[(2R)-1-[(R)-α-methylbenzyl]aziridine-2β-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Diphenyl-10,20-bis[2,6-bis[[(R)-2-methoxypropionyl]amino]phenyl]-21H,23H-porphyrin ,  5,15-Diphenyl-10,20-bis[2,6-bis[[(S)-2-methoxypropionyl]amino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(4-tert-butylphenyl)-10,20-bis[2,6-bis[[[(1S)-2,2-dimethylcyclopropyl]carbonyl]amino]phenyl]-21H,23H-porphyrin ,  5,15-Bis[4-(trifluoromethyl)phenyl]-10,20-bis[2,6-bis[[(S)-2,2-dimethylcyclopropane-1α-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(pentafluorophenyl)-10,20-bis[2,6-bis[[(S)-2,2-dimethylcyclopropane-1α-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(4-acetylphenyl)-10,20-bis[2,6-bis[[(S)-2,2-dimethylcyclopropane-1α-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(2,4,6-trimethylphenyl)-10,20-bis[2,6-bis[[(S)-2,2-dimethylcyclopropane-1α-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(2,6-dimethoxyphenyl)-10,20-bis[2,6-bis[[(S)-2,2-dimethylcyclopropane-1α-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(3,5-dimethoxyphenyl)-10,20-bis[2,6-bis[[(S)-2,2-dimethylcyclopropane-1α-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(3,5-di-tert-butylphenyl)-10,20-bis[2,6-bis[[(S)-2,2-dimethylcyclopropyl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(3,5-di-tert-butylphenyl)-10,20-bis[2,6-bis[[(R)-2-methoxypropionyl]amino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(3,5-di-tert-butylphenyl)-10,20-bis[2,6-bis[[(S)-2-methoxypropionyl]amino]phenyl]-21H,23H-porphyrin ,  5,15-Bis(1-propylbutyl)-10,20-bis[2,6-bis[[(S)-2,2-dimethylcyclopropan-1α-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  5,15-Bis[2,6-bis[[(S)-2,2-dimethylcyclopropan-1α-yl]carbonylamino]phenyl]-21H,23H-porphyrin ,  Styrene ,  Diazoacetic acid ethyl ,  2-Diazoacetic acid tert-butyl ester ,  4-(Dimethylamino)pyridine ,  (1R)-1β-(Ethoxycarbonyl)-2α-phenylcyclopropane ,  2β-Phenyl-1α-cyclopropanecarboxylic acid ethyl ester ,  (1α)-2α-Phenylcyclopropanecarboxylic acid ethyl ester ,  2β-Phenyl-1β-cyclopropanecarboxylic acid ethyl ester ,  2α-Phenylcyclopropane-1β-carboxylic acid tert-butyl ester ,  2α-Phenylcyclopropane-1α-carboxylic acid tert-butyl ester ,  2β-Phenylcyclopropane-1β-carboxylic acid tert-butyl ester

Terms in the title (8)： キラル ,  ポルフィリン類 ,  構築 ,  多目的 ,  シントン ,  コバルト触媒 ,  ジアステレオ選択 ,  シクロプロパン化