Art

J-GLOBAL ID：200902212400285208   Reference number：09A0293044

Catalyst and base controlled site-selective sp² and sp³ direct arylation of azine N-oxides

触媒と塩基によって支配されるアジンN-オキシドの部位選択的なsp²及びsp³の直接アリール化

Author (3)： SCHIPPER Derek J. (Center for Catalysis Res. and Innovation, Univ. of Ottawa, Dep. of Chemistry, 10 Marie Curie, Ottawa, Ontario ...) ,  CAMPEAU Louis-charles (Center for Catalysis Res. and Innovation, Univ. of Ottawa, Dep. of Chemistry, 10 Marie Curie, Ottawa, Ontario ...) ,  FAGNOU Keith (Center for Catalysis Res. and Innovation, Univ. of Ottawa, Dep. of Chemistry, 10 Marie Curie, Ottawa, Ontario ...)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 65  Issue： 16  Page： 3155-3164  Publication year： Apr. 18, 2009 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,  *oxide ,  *arylation ,  chemical synthesis ,  catalytic reaction ,  palladium catalyst ,  palladium complex ,  base(alkali) ,  potassium carbonate ,  reaction mechanism ,  cholinergic drug ,  regiospecific reaction ,  benzylisoquinoline alkaloid ,  phenol ether ,  polynuclear aromatic compound

JST classification (4)： Nitrogen heterocycles in general  (CF07040G) ,  Substitution reaction  (CF02020B) ,  Platinum family element complexes  (CE01100E) ,  Synthesis of drugs  (GV01030F)

Substance index (18)： 1-Bromo-3,5-dimethylbenzene ,  2-Methylpyridine 1-oxide ,  2-Methylquinoline 1-oxide ,  4-Chlorotoluene ,  4-Bromotoluene ,  Sodium tert-butoxide ,  Papaverine ,  2-(4-Methylbenzyl)pyridine 1-oxide ,  2-(3,5-Dimethylbenzyl)pyridine 1-oxide ,  2,3-Lutidine 1-oxide ,  2-(3,5-Dimethylbenzyl)-3-methylpyridine 1-oxide ,  2-(4-Methylbenzyl)quinoline 1-oxide ,  2,3-Dimethylpyrazine 1-oxide ,  3-Methylisoquinoline 2-oxide ,  2,3-Dimethyl-6-(4-methylphenyl)pyrazine 1-oxide ,  1-(4-Methylphenyl)-3-methylisoquinoline 2-oxide ,  2-(2-Methylbenzyl)-6-(4-methylphenyl)pyridine 1-oxide ,  1-(α-Hydroxybenzyl)-6,7-dimethoxyisoquinoline 2-oxide

Terms in the title (7)： 触媒 ,  塩基 ,  支配 ,  アジン ,  N-オキシド ,  Sp3 ,  アリール化