Art

J-GLOBAL ID：200902212454842773   Reference number：03A0089051

An efficient strategy for the modification of α-cyclodextrin: direct conversion of one or two adjacent 6-OHs to phthalimides.

α-シクロデキストリンの効率的な修飾戦略 1個又は近接する2個の6-OH基のフタルイミドへの直接変換

Author (4)： YUAN D-Q (Nagasaki Univ., Nagasaki, JPN) ,  YANG C (Nagasaki Univ., Nagasaki, JPN) ,  FUKUDA T (Nagasaki Univ., Nagasaki, JPN) ,  FUJITA K (Nagasaki Univ., Nagasaki, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 44  Issue： 3  Page： 565-568  Publication year： Jan. 13, 2003 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *cyclodextrin ,...

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JST classification (1)： Polysaccharides  (CF10054P)

Substance index (15)： α-Cyclodextrin ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,14,19,24-Pentakis(hydroxymethyl)-29-(phthalimidylmethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane ,  6-Amino-6-deoxy-α-cyclodextrin ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,14,19-Tetrakis(hydroxymethyl)-24,29-bis(phthalimidylmethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,14,24-Tetrakis(hydroxymethyl)-19,29-bis(phthalimidylmethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,19,24-Tetrakis(hydroxymethyl)-14,29-bis(phthalimidylmethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane ,  Phthalimide ,  Azodicarboxylic acid diethyl ,  Triphenylphosphine ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,14,19-Tetrakis(hydroxymethyl)-24,29-bis(aminomethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,14,24-Tetrakis(hydroxymethyl)-19,29-bis(aminomethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,19,24-Tetrakis(hydroxymethyl)-14,29-bis(aminomethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,14,19-Tetrakis(hydroxymethyl)-24,29-bis(4-nitrobenzoylaminomethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,14,24-Tetrakis(hydroxymethyl)-19,29-bis(4-nitrobenzoylaminomethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane ,  (2R,4R,5S,7R,9R,10S,12R,14R,15S,17R,19R,20S,22R,24R,25S,27R,29R,30S,31R,32R,33R,34R,35R,36R,37R,38R,39R,40R,41R,42R)-4,9,19,24-Tetrakis(hydroxymethyl)-14,29-bis(4-nitrobenzoylaminomethyl)-31,32,33,34,35,36,37,38,39,40,41,42-dodecahydroxy-2,5:7,10:12,15:17,20:22,25:27,30-hexaethano-1,3,6,8,11,13,16,18,21,23,26,28-dodecaoxacyclotriacontane

Terms in the title (6)： α-シクロデキストリン ,  修飾 ,  戦略 ,  OH基 ,  フタルイミド ,  直接変換