Art

J-GLOBAL ID：200902212503919930   Reference number：07A0715330

Enantioselective γ-Deprotonation of Alkyl-Substituted O-1,3-Butadien-2-yl Carbamates and Regioselective Asymmetric Homoaldol Reaction

アルキル置換O-1,3-ブタジエン-2-イル=カルバマートのエナンチオ選択的γ-脱プロトンと位置選択的不斉ホモアルドール反応

Author (4)： BOU CHEDID Roland (Westfaelische Wilhelms-Univ. Muenster, Muenster, DEU) ,  FROEHLICH Roland (Westfaelische Wilhelms-Univ. Muenster, Muenster, DEU) ,  WIBBELING Birgit (Westfaelische Wilhelms-Univ. Muenster, Muenster, DEU) ,  HOPPE Dieter (Westfaelische Wilhelms-Univ. Muenster, Muenster, DEU)
Material： European Journal of Organic Chemistry  (Eur J Org Chem)
Volume： 2007  Issue： 19  Page： 3179-3190  Publication year： 2007 
JST Material Number： W1026A  ISSN： 1434-193X  CODEN： EJOCFK  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *diene ,...
Semi thesaurus term： *Aldol condensation ,...

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JST classification (2)： Alkenes  (CF03030T) ,  Regiochemistry of organic reaction  (CF02140G)

Substance index (14)： Spartein ,  Butyl lithium ,  Diisopropylcarbamic acid (1Z)-1-propylidene-3-methyl-2-butenyl ester ,  Diisopropylcarbamic acid (1Z)-1-(1-cyclopentenyl)-4-methyl-1-pentenyl ester ,  Diisopropylcarbamic acid (1S)-1-lithio-1-[(E)-1-propenyl]-3-methyl-2-butenyl ester ,  Diisopropylcarbamic acid (1Z,3S,4S)-4-hydroxy-1-(2-methyl-1-propenyl)-3,5,5-trimethyl-1-hexenyl ester ,  Diisopropylcarbamic acid (1Z,3S,4R)-4-hydroxy-1-(2-methyl-1-propenyl)-3,5-dimethyl-1-hexenyl ester ,  Diisopropylcarbamic acid (1Z,3S,4R)-4-hydroxy-1-(2-methyl-1-propenyl)-3-methyl-1-hexenyl ester ,  Diisopropylcarbamic acid (1Z,3S,4S)-4-(4-bromophenyl)-4-hydroxy-3-methyl-1-(2-methyl-1-propenyl)-1-butenyl ester ,  Diisopropylcarbamic acid (2E)-1-[(1E,2S)-2-[1-hydroxy-1-methylethyl]cyclopentylidene]-4-methyl-2-pentenyl ester ,  Diisopropylcarbamic acid (1S,2E)-1-(2-cyclopentenyl)-1-lithio-4-methyl-2-pentenyl ester ,  Diisopropylcarbamic acid (1Z,2E)-1-[(2R)-2-[(1R)-1-hydroxy-2,2-dimethylpropyl]cyclopentylidene]-4-methyl-2-pentenyl ester ,  Diisopropylcarbamic acid (1Z,2E)-1-[(2R)-2-[(1S)-1-hydroxy-2-methylpropyl]cyclopentylidene]-4-methyl-2-pentenyl ester ,  Diisopropylcarbamic acid (1Z,2E)-1-[(2R)-2-[(R)-hydroxy(4-bromophenyl)methyl]cyclopentylidene]-4-methyl-2-pentenyl ester

Terms in the title (7)： 置換 ,  ブタジエン ,  カルバマート ,  脱プロトン ,  位置選択 ,  ホモ ,  アルドール反応