Art

J-GLOBAL ID：201702247516566355   Reference number：17A0492563

Indium-catalysed amide allylation of α-iminoamide: highly enantioselective synthesis of amide functionalised α-methylene-γ-butyrolactams

インジウム触媒によるα-イミノアミドのアミドアリル化:アミド官能化α-メチレン-γ-ブチロラクタム類の高エナンチオ選択的合成

Author (5)： Sengoku Tetsuya (Department of Applied Chemistry, Faculty of Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan. [e-mail]) ,  Kokubo Kana ,  Sakamoto Masami ,  Takahashi Masaki ,  Yoda Hidemi
Material： Organic & Biomolecular Chemistry  (Org Biomol Chem)
Volume： 15  Issue： 2  Page： 320-323  Publication year： 2017 
JST Material Number： A0499C  ISSN： 1477-0520  CODEN： OBCRAK  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： metal catalyst ,  indium complex ,  catalytic reaction ,  asymmetric synthesis ,  molecular structure ,  stereoselectivity ,  *lactam ,  allylation ,  amide ,  *addition reaction ,  cyclization reaction ,  amidation
Semi thesaurus term： indium catalyst ,  enantioselectivity

JST classification (2)： Pyrroles  (CF07076L) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (14)： N,N′-Diphenyl-2-methylene-4-phenyl-4-(p-methoxyphenylamino)glutaramide ,  N-(4-Methylphenyl)-N′-phenyl-2-methylene-4-phenyl-4-(p-methoxyphenylamino)glutaramide ,  N-(4-Methoxyphenyl)-N′-phenyl-2-methylene-4-phenyl-4-(p-methoxyphenylamino)glutaramide ,  N-(4-(tert-Butyl)phenyl)-N′-phenyl-2-methylene-4-phenyl-4-(p-methoxyphenylamino)glutaramide ,  N-(1-Naphthyl)-N′-phenyl-2-methylene-4-phenyl-4-(p-methoxyphenylamino)glutaramide ,  N-(4-Chlorophenyl)-N′-phenyl-2-methylene-4-phenyl-4-(p-methoxyphenylamino)glutaramide ,  N-Pentyl-N′-phenyl-2-methylene-4-phenyl-4-(p-methoxyphenylamino)glutaramide ,  N,N′-Diphenyl-2-methylene-4-(4-methoxyphenyl)-4-(p-methoxyphenylamino)glutaramide ,  N,N′-Diphenyl-2-methylene-4-(4-(trifluoromethyl)phenyl)-4-(p-methoxyphenylamino)glutaramide ,  N,N′-Diphenyl-2-methylene-4-(1-naphthyl)-4-(p-methoxyphenylamino)glutaramide ,  N-Boc-N,2-Diphenyl-4-methylene-5-oxopyrrolidine-2-carboxamide ,  N-Boc-N-Phenyl-2-(4-methoxyphenyl)-4-methylene-5-oxopyrrolidine-2-carboxamide ,  N-Boc-N-Phenyl-2-(4-(trifluoromethyl)phenyl)-4-methylene-5-oxopyrrolidine-2-carboxamide ,  N-Boc-N-Phenyl-2-(1-naphthyl)-4-methylene-5-oxopyrrolidine-2-carboxamide

Terms in the title (7)： インジウム触媒 ,  アミド ,  アリル化 ,  官能化 ,  メチレン ,  γ-ブチロラクタム ,  エナンチオ選択的合成