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J-GLOBAL ID：201702278774215356   Reference number：17A0361708

Radical reactivity of α,β,β-trifluoroacrylic ester: Facile approach to γ-silyloxy-α,β,β-trifluorobutyric acid derivatives involving regioselective nucleophilic radical addition reaction

α,β,βtrifluoroacrylicエステルのラジカル反応性位置選択的求核ラジカル付加反応を含むγ-シリルオキシ-α,β,β-トリフルオロ酪酸誘導体への容易なアプローチ【Powered by NICT】

Author (5)： Tamamoto Ken (Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan) ,  Yamada Shigeyuki (Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan) ,  Higashi Masao (Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan) ,  Konno Tsutomu (Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan) ,  Ishihara Takashi (Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan)
Material： Journal of Fluorine Chemistry  (J Fluor Chem)
Volume： 190  Page： 23-30  Publication year： 2016 
JST Material Number： B0438C  ISSN： 0022-1139  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Abstract/Point： In this paper are disclosed ne...

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Thesaurus term： organic compound ,  nucleophilic addition reaction ,  diastereomer ,  precursor(substance) ,  elimination reaction ,  protocol ,  cycloaddition ,  pharmacology ,  *reactivity ,  fluorination ,  cyclic ether ,  *radical reaction
Semi thesaurus term： *ラジカル付加 , 【Automatic Indexing@JST】

Author keywords (4)： Keyword Fluorinated alkenes ,  Radical addition ,  Regioselective addition ,  Organofluorine compounds

JST classification (1)： Aliphatic halogen compounds  (CF03050P)

Terms in the title (6)： エステル ,  ラジカル反応 ,  位置選択 ,  核 ,  ラジカル付加 ,  酪酸誘導体