文献

J-GLOBAL ID：201702217339789134   整理番号：17A0749075

Rh錯体強いπ-酸性ジベンゾ[a,e]シクロオクタテトラエン配位子を触媒とするフェニルアセチレンの水上重合【Powered by NICT】

On-Water Polymerization of Phenylacetylene Catalyzed by Rh Complexes Bearing Strong π-Acidic Dibenzo[a,e]cyclooctatetraene Ligand

著者 (14件)： Zhang Pengfei (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Wang Hanghang (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Shi Xiaosong (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Yan Xinwen (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Wu Xiaolu (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Zhang Shaowen (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Yao Bo (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Feng Xiao (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Zhi Junge (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Li Xiaofang (School of Chemistry and Chemical Engineering, Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Tong Bin (School of Material Science and Engineering, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Shi Jianbin (School of Material Science and Engineering, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Wang Lin (School of Mechatronical Engineering, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China) ,  Dong Yuping (School of Material Science and Engineering, Beijing Institute of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, China)
資料名： Journal of Polymer Science. Part A. Polymer Chemistry  (Journal of Polymer Science. Part A. Polymer Chemistry)
巻： 55  号： 4  ページ： 716-725  発行年： 2017年 
JST資料番号： C0337C  ISSN： 0887-624X  CODEN： JPLCAT  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： アメリカ合衆国 (USA)  言語： 英語 (EN)

抄録/ポイント： 強いπ-酸性ジベンゾ[a,e]シクロオクタテトラエン(dbcot)ジエン配位子を有する新しい単核中性および水溶性カチオン性ロジウム(Rh)錯体を合成し,構造的に特性化した。フェニルアセチレンの重合において,dbcot Rh錯体は,有機溶媒および水性媒体の両方で対応するタラベースRh錯体よりも高い触媒活性を示し,cis含有量,中程度の分子量の99%までの高いcis-トランソイダルのPPAを与え,,中程度広い分子量分布に変化した。さらに,置換フェニルアセチレンの水上重合を空気雰囲気下でこれらの錯体によって達成される,重合速度の3~CLXIII倍加速は有機溶媒に比較して水溶液重合で観察された。フェニルアセチレン影響に関するRh錯体,溶媒,重合温度,および置換基の性質高分子の収率,立体選択性,分子量,および分子量分布について。添加で,水溶性カチオン性Rh錯体は,三回再使用できた。Copyright 2017 Wiley Publishing Japan K.K. All Rights reserved. Translated from English into Japanese by JST.【Powered by NICT】

シソーラス用語： *触媒 ,  立体選択性 ,  分子量 ,  *ロジウム ,  有機溶媒 ,  水溶性 ,  分子量分布 ,  *錯体 ,  カチオン ,  *酸性 ,  高分子 ,  触媒活性 ,  再利用 ,  *重合 ,  芳香族炭化水素 ,  アセチレン化合物

著者キーワード (5件)： 付加重合 ,  共役重合体 ,  ロジウム錯体 ,  水上 ,  立体特異的重合体

分類 (1件)： 重合触媒,重合開始剤  (CG04070V)

物質索引 (1件)： フェニルアセチレン

タイトルに関連する用語 (9件)： Rh ,  錯体 ,  酸性 ,  シクロオクタテトラエン ,  配位子 ,  触媒 ,  フェニルアセチレン ,  水上 ,  重合