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J-GLOBAL ID：201702230300426501   整理番号：17A0412326

非レドックス金属イオンは簡単なPd(OAc)2触媒による飽和C-C結合の酸化的脱水素を促進した【Powered by NICT】

Non-redox metal ions promoted oxidative dehydrogenation of saturated CC bond by simple Pd(OAc)₂ catalyst

著者 (7件)： Lou Chenlin (School of Chemistry and Chemical Engineering, Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, Huazhong University of Science and T...) ,  Qin Shuhao (School of Chemistry and Chemical Engineering, Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, Huazhong University of Science and T...) ,  Zhang Sicheng (School of Chemistry and Chemical Engineering, Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, Huazhong University of Science and T...) ,  Lv Zhanao (School of Chemistry and Chemical Engineering, Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, Huazhong University of Science and T...) ,  Senan Ahmed M. (School of Chemistry and Chemical Engineering, Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, Huazhong University of Science and T...) ,  Chen Zhuqi (School of Chemistry and Chemical Engineering, Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, Huazhong University of Science and T...) ,  Yin Guochuan (School of Chemistry and Chemical Engineering, Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, Huazhong University of Science and T...)
資料名： Catalysis Communications  (Catalysis Communications)
巻： 90  ページ： 5-9  発行年： 2017年 
JST資料番号： W1328A  ISSN： 1566-7367  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： オランダ (NLD)  言語： 英語 (EN)

抄録/ポイント： 簡単なPd(OAc)2触媒に非酸化還元金属イオンを添加すると,飽和C-C結合の酸化的脱水素を著しく促進でき,活性向上はLewis酸強度に依存した。触媒のUV-vis及びNMR特性化により,その場生成した異核Pd(II)/Zn(II)二量体は脱水素のための重要な活性種であることを提案した。Copyright 2017 Elsevier B.V., Amsterdam. All rights reserved. Translated from English into Japanese by JST.【Powered by NICT】

シソーラス用語： Lewis酸 ,  *脱水素 ,  *金属イオン ,  NMR【磁気共鳴】 ,  *触媒 ,  キャラクタリゼーション ,  *酸化的脱水素 ,  二量体 ,  *酸化還元反応

著者キーワード (4件)： 酸化的脱水素 ,  パラジウム(II) ,  Lewis酸 ,  活性ヘテロ二金属種

分類 (2件)： 貴金属触媒  (CB06122I) ,  酸化,還元  (CF02060T)

タイトルに関連する用語 (8件)： レドックス ,  金属イオン ,  Pd ,  触媒 ,  飽和 ,  C-C結合 ,  酸化的脱水素 ,  促進