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J-GLOBAL ID：201702240650464968   整理番号：17A0376505

溶液処理した有機太陽電池のための3,3′-ジフルオロ-2,2′-ビチオフェン中央ユニットを持つオリゴチオフェン小分子【Powered by NICT】

Oligothiophene-based small molecules with 3,3′-difluoro-2,2′-bithiophene central unit for solution-processed organic solar cells

著者 (16件)： Kan Bin (State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), School of Materials Science and Engineering, Nankai University, Tianjin, 300071, China) ,  Kan Bin (Key Laboratory of Functional Polymer Materials and the Centre of Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China) ,  Zhang Qian (State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), School of Materials Science and Engineering, Nankai University, Tianjin, 300071, China) ,  Zhang Qian (Key Laboratory of Functional Polymer Materials and the Centre of Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China) ,  Wan Xiangjian (State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), School of Materials Science and Engineering, Nankai University, Tianjin, 300071, China) ,  Wan Xiangjian (Key Laboratory of Functional Polymer Materials and the Centre of Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China) ,  Ke Xin (State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), School of Materials Science and Engineering, Nankai University, Tianjin, 300071, China) ,  Ke Xin (Key Laboratory of Functional Polymer Materials and the Centre of Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China) ,  Wang Yunchuang (State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), School of Materials Science and Engineering, Nankai University, Tianjin, 300071, China) ,  Wang Yunchuang (Key Laboratory of Functional Polymer Materials and the Centre of Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China) ,  Feng Huanran (State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), School of Materials Science and Engineering, Nankai University, Tianjin, 300071, China) ,  Feng Huanran (Key Laboratory of Functional Polymer Materials and the Centre of Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China) ,  Zhang Mingtao (State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), School of Materials Science and Engineering, Nankai University, Tianjin, 300071, China) ,  Zhang Mingtao (Key Laboratory of Functional Polymer Materials and the Centre of Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China) ,  Chen Yongsheng (State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), School of Materials Science and Engineering, Nankai University, Tianjin, 300071, China) ,  Chen Yongsheng (Key Laboratory of Functional Polymer Materials and the Centre of Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China)
資料名： Organic Electronics  (Organic Electronics)
巻： 38  ページ： 172-179  発行年： 2016年 
JST資料番号： W1352A  ISSN： 1566-1199  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： オランダ (NLD)  言語： 英語 (EN)

抄録/ポイント： 二つの新しいオリゴチオフェン系小分子,すなわちDRCN6T FとDRCN8T F,末端基として中央ビルディングブロックと2-(1,1-ジシアノメチレン)-ロダニンとして3,3′-ジフルオロ-2,2′-ビチオフェン,を設計し,合成した。非フッ素化対応物DRCN6TとDRCN8Tと比較して,DRCN6T FとDRCN8T Fは拡張された分子間相互作用と低いHOMOエネルギー準位を示した。しかし,2.26%と5.07%のPCEはDRCN6T FとDRCN8T F基づく最適化デバイスで得られ,それぞれ,非フッ素化分子DRCN6TとDRCN8Tよりも低かった。DRCN6T FとDRCN8T Fに対しては相対的に不十分な性能は,主にそれらの低い短絡電流密度によって引き起こされた,好ましくない形態と低い電荷キャリア移動度に起因していた。Copyright 2017 Elsevier B.V., Amsterdam. All rights reserved. Translated from English into Japanese by JST.【Powered by NICT】

シソーラス用語： 末端基 ,  HOMO ,  キャリア移動度 ,  エネルギー準位 ,  *小分子 ,  フッ素化 ,  最適化 ,  分子間相互作用
準シソーラス用語： 短絡電流密度 ,  ビルディングブロック ,  *オリゴチオフェン ,  *有機太陽電池 ,  *溶液処理 , 【Automatic Indexing@JST】

著者キーワード (4件)： 有機太陽電池 ,  小分子 ,  オリゴチオフェン ,  ふっ素化中央装置

分類 (2件)： 高分子固体の物理的性質  (CG02024U) ,  有機化合物の電気伝導  (BM03045F)

タイトルに関連する用語 (4件)： 溶液処理 ,  有機太陽電池 ,  オリゴチオフェン ,  小分子