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J-GLOBAL ID：201702245208743079   整理番号：17A0442392

YF_3によるLiF-NaF-KF共晶中でのグラファイトアノードの電気化学的挙動【Powered by NICT】

Electrochemical Behavior of Graphite Anode in LiF-NaF-KF Eutectic with YF₃

著者 (34件)： Tian Lifang (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Tian Lifang (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Tian Lifang (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  Huang Wei (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Huang Wei (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Huang Wei (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  Jiang Feng (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Jiang Feng (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Jiang Feng (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  Zheng Haiyang (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Zheng Haiyang (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Zheng Haiyang (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  Zhu Tiejian (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Zhu Tiejian (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Zhu Tiejian (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  She Changfeng (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  She Changfeng (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  She Changfeng (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  Wang Xianbin (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Wang Xianbin (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Wang Xianbin (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  Wang Xianbin (University of Chinese Academy of Sciences, Beijing 100049, China) ,  Long Dewu (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Long Dewu (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Long Dewu (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  Gong Yu (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Gong Yu (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Gong Yu (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  Wu Guozhong (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Wu Guozhong (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Wu Guozhong (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China) ,  Li Qingnuan (Division of Radiochemistry and Engineering, Shanghai Institute of Applied Physics (SINAP), Chinese Academy of Sciences (CAS), Shanghai 201800, China) ,  Li Qingnuan (Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800, China) ,  Li Qingnuan (Center of Excellence TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800, China)
資料名： Electrochimica Acta  (Electrochimica Acta)
巻： 225  ページ： 392-398  発行年： 2017年 
JST資料番号： B0535B  ISSN： 0013-4686  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： イギリス (GBR)  言語： 英語 (EN)

抄録/ポイント： グラファイトアノードの電極反応と電解プロセスは823KでYF_3とLiF-NaF-KF(FLiNaK, 46.5 11.5 42.0mo1%)共晶で調べた。二つの異なるタイプの反応はグラファイトアノード上に観察された。黒鉛は電位範囲 2V(対Ni~2+/Ni,以下同様)の炭素モノ-および二酸化炭素へ酸化し,電位は8Vに陥ったとき,炭素ふっ化物が生成した。添加では,数種のふっ化物製品は逆サイクリックボルタンメトリースキャン,報告されていないが約 0.22Vで還元されることができた。アノード電位変動はガス状生成物の形成と同様にアノード表面積と電流密度の変化に起因する定電流電解中に6と8Vの間で見出された。RamanとX線光電子分光法の両方は電解後の黒鉛アノードに及ぼすふっ素化/酸化生成物の化学状態を調べるために採用した。フルオロカーボン種の形成は,グラファイト表面上の障害の原因である。Copyright 2017 Elsevier B.V., Amsterdam. All rights reserved. Translated from English into Japanese by JST.【Powered by NICT】

シソーラス用語： *グラファイト ,  フッ化物 ,  *電気化学的挙動 ,  X線光電子分光法 ,  電位 ,  脂肪族フッ素化合物 ,  表面積 ,  フッ素化 ,  二酸化炭素 ,  電流密度 ,  電解 ,  炭素 ,  *共晶
準シソーラス用語： 定電流電解 ,  電極反応 , 【Automatic Indexing@JST】

著者キーワード (5件)： FLiNaK ,  黒鉛負極 ,  electrolysis ,  電流密度 ,  陽極電位

分類 (2件)： 電気化学反応  (CB07050F) ,  二次電池  (YB04030K)

タイトルに関連する用語 (5件)： LIF ,  NaF ,  KF ,  共晶 ,  電気化学的挙動