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J-GLOBAL ID：201802212883510817   整理番号：18A0609119

高移動度と近赤外発光を示す電子輸送凝集が誘起する発光ルミノゲン(AIEgens)へのペリレンジイミド置換トリフェニルエチレンの合理的設計【Powered by NICT】

Rational Design of Perylenediimide-Substituted Triphenylethylene to Electron Transporting Aggregation-Induced Emission Luminogens (AIEgens) with High Mobility and Near-Infrared Emission

著者 (15件)： Zhao Zheng (Guangdong Provincial Key Laboratory of Brain Science, Disease and Drug Development, Shenzhen Research Institute, No. 9 Yuexing 1st RD, South Area, Hi-tech Park, Nanshan, Shenzhen, 518057, China) ,  Zhao Zheng (Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute of Molecular Functional Materials, Division of Life Science and state Key Laboratory of Molecular Neuroscience, The ...) ,  Gao Simin (Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, China) ,  Zheng Xiaoyan (Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute of Molecular Functional Materials, Division of Life Science and state Key Laboratory of Molecular Neuroscience, The ...) ,  Zhang Pengfei (Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute of Molecular Functional Materials, Division of Life Science and state Key Laboratory of Molecular Neuroscience, The ...) ,  Wu Wenting (Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, China) ,  Kwok Ryan T. K. (Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute of Molecular Functional Materials, Division of Life Science and state Key Laboratory of Molecular Neuroscience, The ...) ,  Xiong Yu (Guangdong Provincial Key Laboratory of Brain Science, Disease and Drug Development, Shenzhen Research Institute, No. 9 Yuexing 1st RD, South Area, Hi-tech Park, Nanshan, Shenzhen, 518057, China) ,  Leung Nelson L. C. (Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute of Molecular Functional Materials, Division of Life Science and state Key Laboratory of Molecular Neuroscience, The ...) ,  Chen Yuncong (Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute of Molecular Functional Materials, Division of Life Science and state Key Laboratory of Molecular Neuroscience, The ...) ,  Gao Xike (Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, China) ,  Lam Jacky W. Y. (Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute of Molecular Functional Materials, Division of Life Science and state Key Laboratory of Molecular Neuroscience, The ...) ,  Tang Ben Zhong (Guangdong Provincial Key Laboratory of Brain Science, Disease and Drug Development, Shenzhen Research Institute, No. 9 Yuexing 1st RD, South Area, Hi-tech Park, Nanshan, Shenzhen, 518057, China) ,  Tang Ben Zhong (Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute of Molecular Functional Materials, Division of Life Science and state Key Laboratory of Molecular Neuroscience, The ...) ,  Tang Ben Zhong (Guangdong Innovative Research Team, SCUT-HKUST Joint Research Laboratory, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, 510640, China)
資料名： Advanced Functional Materials  (Advanced Functional Materials)
巻： 28  号： 11  ページ： ROMBUNNO.201705609  発行年： 2018年 
JST資料番号： W1336A  ISSN： 1616-301X  CODEN： AFMDC6  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： ドイツ (DEU)  言語： 英語 (EN)

抄録/ポイント： 高電子移動度と強い固相発光の両方を有する有機材料は先進有機オプトエレクトロニクスへの重要性からがは稀である。本論文では,数変化ペリレンジイミド(PDI)単位(TriPE nPDIs, n=1 3)のtriphenylethylenesを合成し,それらの光学的および電荷輸送特性を系統的に調べた。すべての分子は近赤外(NIR)発光強い固相を示し,それらのいくつかは凝集増強発光特性を示した。TriPE nPDIsを用いた有機電界効果トランジスタ(OFET)を作製した。TriPE3pdiは最大量子収率≒30%,0.01cm以上~2V~ 1s~ 1の最適化された電子移動度,これまでに報告されたNIR発光を有する凝集誘起蛍光発光体の中で最高の値で最高の性能を示した。光物理特性研究と理論的計算は分子立体配座はTriPE nPDIの光学的性質に重要な役割を果たすことを示しているが,膜の微細構造研究からの結果は,膜の結晶性は,OFET素子性能に大きな影響を及ぼすことを明らかにした。Copyright 2018 Wiley Publishing Japan K.K. All Rights reserved. Translated from English into Japanese by JST.【Powered by NICT】

シソーラス用語： *発光 ,  オプトエレクトロニクス ,  *凝集 ,  結晶度 ,  立体配座 ,  量子収量 ,  光学的性質 ,  固相 ,  微細構造 ,  有機材料 ,  *近赤外線
準シソーラス用語： 蛍光発光 ,  電荷輸送 ,  電子移動度 ,  *電子輸送 , 【Automatic Indexing@JST】

著者キーワード (5件)： 集合誘起発光 ,  近赤外発光 ,  有機電界効果トランジスタ ,  ペリレンジイミド ,  テトラフェニルエチレン

分類 (5件)： 炭素とその化合物  (YB02060D) ,  その他の光学的効果  (BM08040H) ,  有機化合物の電気伝導  (BM03045F) ,  セラミック・陶磁器の製造  (YC03020V) ,  有機化合物の薄膜  (BK14070L)

タイトルに関連する用語 (10件)： 高移動度 ,  近赤外発光 ,  電子輸送 ,  凝集 ,  誘起 ,  ルミノゲン ,  ペリレンジイミド ,  置換 ,  トリフェニルエチレン ,  設計