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J-GLOBAL ID：201802243754636518   整理番号：18A1062832

可視光光酸化還元触媒により可能になったアルキルラジカルの生成のための脱硫戦略【JST・京大機械翻訳】

A Desulfurative Strategy for the Generation of Alkyl Radicals Enabled by Visible-Light Photoredox Catalysis

著者 (13件)： Xue Fei (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Wang Falu (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Liu Jiazhen (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Di Jiamei (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Liao Qi (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Lu Huifang (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Zhu Min (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  He Liping (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  He Huan (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Zhang Dan (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Song Hao (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Liu Xiao-Yu (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China) ,  Qin Yong (Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, Sichuan Research Center of Precision Engineering Technology for Small Molecule Drugs, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China)
資料名： Angewandte Chemie  (Angewandte Chemie)
巻： 130  号： 22  ページ： 6777-6781  発行年： 2018年 
JST資料番号： A0396A  ISSN： 0044-8249  CODEN： ANCEAD  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： アメリカ合衆国 (USA)  言語： 英語 (EN)

抄録/ポイント： ここでは,可視光酸化還元触媒による一次,二次および三級アルキルラジカルを生成するための新しい脱硫法を提示した。スルフィンアミド中間体からのN中心ラジカルの生成とそれに続くフラグメンテーションを含むプロセスは,対応するアルキルラジカル種を形成するために重要である。この戦略は温和な反応条件,広い基質範囲(>60例),良好な官能基許容性を特徴とする共役付加反応に成功裏に適用された。Copyright 2018 Wiley Publishing Japan K.K. All Rights reserved. Translated from English into Japanese by JST.【JST・京大機械翻訳】

シソーラス用語： *ラジカル ,  *脱硫 ,  基質 ,  中間体 ,  *可視光 ,  フラグメンテーション ,  *アルキルラジカル
準シソーラス用語： *還元触媒 ,  共役付加 ,  反応条件 ,  スルフィンアミド , 【Automatic Indexing@JST】

著者キーワード (5件)： アルキルラジケール ,  脱硫 ,  Konjugerte付加 ,  光還元触媒 ,  放射性カリウム

分類 (2件)： 光化学反応,ラジカル反応  (CF02090A) ,  付加反応,脱離反応  (CF02030M)

タイトルに関連する用語 (5件)： 可視光 ,  光酸化還元触媒 ,  アルキルラジカル ,  脱硫 ,  戦略