文献

J-GLOBAL ID：202002253814678111   整理番号：20A2645110

末端基上の塩素および臭素置換の位置の変更は高性能アクセプタおよび効率的な有機太陽電池を可能にする【JST・京大機械翻訳】

Altering the Positions of Chlorine and Bromine Substitution on the End Group Enables High-Performance Acceptor and Efficient Organic Solar Cells

著者 (28件)： Luo Zhenghui (Hong Kong University of Science and Technology-Shenzhen Research Institute, No. 9 Yuexing First RD, Hi-Tech Park, Nanshan, Shenzhen, 518057, P. R. China) ,  Luo Zhenghui (Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong, 999077, China) ,  Ma Ruijie (Hong Kong University of Science and Technology-Shenzhen Research Institute, No. 9 Yuexing First RD, Hi-Tech Park, Nanshan, Shenzhen, 518057, P. R. China) ,  Ma Ruijie (Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong, 999077, China) ,  Chen Zhanxiang (Department of Chemistry, Wuhan University, Wuhan, 430072, China) ,  Xiao Yiqun (Department of Physics, Chinese University of Hong Kong, New Territories, Hong Kong, 999077, China) ,  Zhang Guangye (eFlexPV Limited (China), Plant B701, Guofu Cultural Creative Industry Plant Area, No. 16, Lanjing Middle Road, Zhukeng Community, Longtian Street, Pingshan, Shenzhen, 518057, China) ,  Liu Tao (Hong Kong University of Science and Technology-Shenzhen Research Institute, No. 9 Yuexing First RD, Hi-Tech Park, Nanshan, Shenzhen, 518057, P. R. China) ,  Liu Tao (Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong, 999077, China) ,  Sun Rui (The Institute for Advanced Studies, Wuhan University, Wuhan, 430072, China) ,  Sun Rui (Department of Materials Science and Engineering and The Shenzhen Key Laboratory for Printed Organic Electronics Southern, University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China) ,  Zhan Qun (Shenzhen Key Laboratory of Polymer Science and Technology, College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060, China) ,  Zou Yang (Shenzhen Key Laboratory of Polymer Science and Technology, College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060, China) ,  Zhong Cheng (Department of Chemistry, Wuhan University, Wuhan, 430072, China) ,  Chen Yuzhong (Hong Kong University of Science and Technology-Shenzhen Research Institute, No. 9 Yuexing First RD, Hi-Tech Park, Nanshan, Shenzhen, 518057, P. R. China) ,  Chen Yuzhong (Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong, 999077, China) ,  Sun Huiliang (Department of Materials Science and Engineering and The Shenzhen Key Laboratory for Printed Organic Electronics Southern, University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China) ,  Chai Gaoda (Hong Kong University of Science and Technology-Shenzhen Research Institute, No. 9 Yuexing First RD, Hi-Tech Park, Nanshan, Shenzhen, 518057, P. R. China) ,  Chai Gaoda (Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong, 999077, China) ,  Chen Kai (Hong Kong University of Science and Technology-Shenzhen Research Institute, No. 9 Yuexing First RD, Hi-Tech Park, Nanshan, Shenzhen, 518057, P. R. China) ,  Chen Kai (Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong, 999077, China) ,  Guo Xugang (Department of Materials Science and Engineering and The Shenzhen Key Laboratory for Printed Organic Electronics Southern, University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China) ,  Min Jie (The Institute for Advanced Studies, Wuhan University, Wuhan, 430072, China) ,  Lu Xinhui (Department of Physics, Chinese University of Hong Kong, New Territories, Hong Kong, 999077, China) ,  Yang Chuluo (Department of Chemistry, Wuhan University, Wuhan, 430072, China) ,  Yang Chuluo (Shenzhen Key Laboratory of Polymer Science and Technology, College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060, China) ,  Yan He (Hong Kong University of Science and Technology-Shenzhen Research Institute, No. 9 Yuexing First RD, Hi-Tech Park, Nanshan, Shenzhen, 518057, P. R. China) ,  Yan He (Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong, 999077, China)
資料名： Advanced Energy Materials  (Advanced Energy Materials)
巻： 10  号： 44  ページ： e2002649  発行年： 2020年 
JST資料番号： W2778A  ISSN： 1614-6832  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： アメリカ合衆国 (USA)  言語： 英語 (EN)

抄録/ポイント： 有機半導体の化学構造の微妙な変化は,特に非フラーレン小分子アクセプタ(SMA)に対して,それらの光電子特性とデバイス性能の劇的な変化を誘起することが広く認識されている。例えば,アクセプタ-ドナー-アクセプタ型SMAsにおける末端基のハロゲン化は,末端基の特性を調節するための有効な戦略であり,従って,SMA全体である。以前の位置変調は1つの置換基のみに焦点を当てていたが,本研究では,末端ユニット上の2つのハロゲン置換基(塩素と臭素)の位置を操作することにより,3つの異性体SMA(BTP-ClBr,BTP-ClBr1,およびBTP-ClBr2)の開発を示した。BTP-ClBrはブルーシフト吸収,浅い最低非占有分子軌道エネルギーレベル,およびBTP-ClBr1およびBTP-ClBr2に比べて弱い結晶化傾向を示す。最適PM6:BTP-ClBr有機太陽電池デバイスにおいて,電力変換効率(16.82%)と優れたフィルファクタ(FF)(0.79)を実現した。より高いFFは,より長い電荷再結合寿命,より速い光電流減衰,弱い二分子再結合,およびPM6:BTP-ClBrに対するより好ましいドメインサイズを含むキャラクタリゼーションの結果と一致し,これは,SMAの物理化学的性質に強く影響する置換サイトにおける微妙な変化からすべて起こる。Copyright 2020 Wiley Publishing Japan K.K. All rights reserved. Translated from English into Japanese by JST.【JST・京大機械翻訳】

シソーラス用語： *アクセプタ ,  エネルギー準位 ,  結晶化 ,  再結合 ,  ドナー ,  有機半導体 ,  *塩素 ,  *臭素 ,  ハロゲン化 ,  *末端基 ,  青方偏移 ,  小分子
準シソーラス用語： フィルファクタ ,  *有機太陽電池 ,  電力変換効率 , 【Automatic Indexing@JST】

著者キーワード (5件)： 分子充填 ,  有機太陽電池 ,  電力変換効率 ,  小分子アクセプタ ,  置換位置

分類 (3件)： 太陽電池  (NC03084O) ,  電池一般  (YB04010O) ,  光伝導,光起電力  (BM03050J)

タイトルに関連する用語 (6件)： 末端基 ,  塩素 ,  臭素 ,  置換 ,  アクセプタ ,  有機太陽電池