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J-GLOBAL ID：202102217684994519   整理番号：21A0181472

NNNNN-ピンサー多座ピロリル希土類-金属アミド-クロリドまたはジアルキル錯体の合成および反応性【JST・京大機械翻訳】

Synthesis and Reactivity of NNNNN-Pincer Multidentate Pyrrolyl Rare-Earth-Metal Amido-Chloride or Dialkyl Complexes

著者 (12件)： Sheng Weiming (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Xu Xiaolong (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Zhou Shuangliu (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Zhang Xiuli (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Huang Zeming (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Du Jun (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Zhang Lijun (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Wei Yun (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Zhu Xiancui (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Cui Peng (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Wang Shaowu (Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Anhui, People’s Republic of China) ,  Wang Shaowu (Anhui Laboratory of Functional Complexes for Materials Chemistry and Application, College of Chemical and Environmental Engineering, Anhui Polytechnic University, Anhui, People’s Republic of China)
資料名： Organometallics  (Organometallics)
巻： 39  号： 24  ページ： 4525-4534  発行年： 2020年 
JST資料番号： E0965A  ISSN： 0276-7333  CODEN： ORGND7  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： アメリカ合衆国 (USA)  言語： 英語 (EN)

抄録/ポイント： (Me_3Si)_2N]_3RE-(μ-Cl)-Li-(THF)_3と{2,5-[CH_3N-(CH_2CH_2)_2NCH_2]_2}-C_4H_2NH(1)との反応により,NNNNN-ピンサー多座ピロリル希土類-金属アミド-塩化物錯体,ε1:κ3-2,5-[CH_3N-(CH_2CH_2)_2NCH_2]_2C_4H_2N}-RECl-[N-(SiMe_3)_2](RE=Y(2a),Sm(2b),Dy(2c),Er(2d),Yb(2e))を合成した。化合物1とRE-(CH_2SiMe_3)_3(THF)_2との反応は,希土類-金属ジアルキル錯体,{η1:κ2-2,5-[CH_3N-(CH_2CH_2)_2NCH_2]_2C_4H_2N}-Sc-(CH_2SiMe_3)_2(3a)と,ΔΨ1:κ3-2,5-[CH_3N-(CH_2CH_2)_2NCH_2]_2C_4H_2N}-RE-(CH_2SiMe_3)_2(RE=Y(3b),Dy(3c),Er(3d),Yb(3e),Lu(3f))を与えた。”,(CH_3N-(CH_2CH_2)_2NCH_2]_2C_4H_2N}-RE-(CH_2SiMe_3)_2(RE=Y(3b),Dy(3c),Er(3d),Yb(3e),Lu(3f)))を与えた(CH_2SiMe_3)_2(CH_3N-(CH_2CH_2)_2NCH_2]_2C_4H_2N}-RE-(CH_2SiMe_3)_2(RE=Y(3b))。錯体3とジメチルアニリンとのさらなる反応は,NNNNN-ピンサー多座ピロリル配位子を有する希土類-金属ジアミド錯体を与えたが,付加的DMAPの条件下では,希土類-金属イミド錯体はなかった。すべての錯体を,分光学的方法,元素分析,および単結晶X線回折によって特性評価した。ピンサー多座ピロリル希土類-金属ジアルキル錯体は,カルボジイミドまたはイソチオシアナートへのアミンの付加に対して高い触媒活性を示し,置換グアニジン類およびチオ尿素類を与えた。Copyright 2021 American Chemical Society All rights reserved. Translated from English into Japanese by JST.【JST・京大機械翻訳】

シソーラス用語： 元素分析 ,  触媒活性 ,  *塩化物 ,  アミン ,  イソチオシアン酸塩 ,  イミド錯体 ,  キャラクタリゼーション ,  ウレア化合物 ,  有機硫黄化合物
準シソーラス用語： グアニジン類 ,  分光学 ,  単結晶X線回折 , 【Automatic Indexing@JST】

分類 (1件)： 第3族元素の錯体  (CE01060J)

物質索引 (2件)： チオ尿素 ,  カルボジイミド

タイトルに関連する用語 (5件)： 希土類 ,  アミド ,  クロリド ,  錯体 ,  反応性