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J-GLOBAL ID：202102284532495102   整理番号：21A2330489

非晶質高分子膜からの結晶性COF膜のスケーラブルな製造【JST・京大機械翻訳】

Scalable Fabrication of Crystalline COF Membranes from Amorphous Polymeric Membranes

著者 (28件)： Fan Chunyang (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Fan Chunyang (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Wu Hong (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Wu Hong (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Wu Hong (Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin, 300072, China) ,  Guan Jingyuan (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Guan Jingyuan (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  You Xinda (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  You Xinda (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Yang Chao (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Yang Chao (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Wang Xiaoyao (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Wang Xiaoyao (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Cao Li (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Cao Li (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Shi Benbing (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Shi Benbing (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Peng Quan (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Peng Quan (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Kong Yan (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Kong Yan (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Wu Yingzhen (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Wu Yingzhen (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Khan Niaz Ali (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Khan Niaz Ali (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Jiang Zhongyi (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) ,  Jiang Zhongyi (Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China) ,  Jiang Zhongyi (Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou, 350207, China)
資料名： Angewandte Chemie  (Angewandte Chemie)
巻： 133  号： 33  ページ： 18199-18206  発行年： 2021年 
JST資料番号： A0396A  ISSN： 0044-8249  CODEN： ANCEAD  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： アメリカ合衆国 (USA)  言語： 英語 (EN)

抄録/ポイント： 共有結合性有機フレームワーク(COF)膜は広範な応用性を持つが,スケーラブルな製造は挑戦的である。ここでは,単量体交換による非晶質高分子膜から結晶COF膜への無秩序-秩序変換を実証した。溶液処理を用いて非晶質膜を調製し,置換単量体を最終骨格の化学的および熱力学的安定性に基づいて選択した。可逆的イミン結合により,非晶質膜内の元の単量体を置換し,無秩序ネットワークから秩序骨格への変態を駆動した。分子内水素結合の導入は結晶COFが非晶質膜形態をインプリントすることを可能にする。COF膜は80°Cで0.53Scm-1までプロトン伝導性を収穫した。本戦略は,COF膜の大規模作製のための非晶質高分子および結晶性COF膜を架橋し,材料処理に関する指針を提供する。Copyright 2021 Wiley Publishing Japan K.K. All rights reserved. Translated from English into Japanese by JST.【JST・京大機械翻訳】

シソーラス用語： 陽子 ,  ネットワーク ,  加工性 ,  単量体 ,  *非晶質 ,  *結晶度 ,  *高分子膜 ,  共有結合 ,  分子内水素結合 ,  熱力学的安定度
準シソーラス用語： *非晶質高分子 ,  プロトン伝導率 ,  溶液処理 ,  非晶質膜 , 【Automatic Indexing@JST】

著者キーワード (5件)： 共有結合有機骨格 ,  無秩序から秩序 ,  膜 ,  陽子輸送 ,  溶液加工性

分類 (4件)： 金属薄膜  (BK14030T) ,  分子化合物  (CE02000C) ,  有機化合物の薄膜  (BK14070L) ,  高分子固体の構造と形態学  (CG02022M)

タイトルに関連する用語 (3件)： 非晶質高分子 ,  結晶性 ,  COF