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J-GLOBAL ID：202202286098665006   整理番号：22A0727434

SnO_2Electron輸送膜とCsPbI_3の間のバッファ層として酢酸テトラブチルアンモニウムを有する全無機ペロブスカイト太陽電池【JST・京大機械翻訳】

All-Inorganic Perovskite Solar Cells with Tetrabutylammonium Acetate as the Buffer Layer between the SnO₂ Electron Transport Film and CsPbI₃

著者 (17件)： Zhong Hang (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Li Wenbo (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Huang Yin (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Cao Duoling (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Zhang Congqiang (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Bao Huaxi (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Guo Zhiguang (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Wan Li (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Zhang Xu (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Zhang Xiuhua (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Li Yuebin (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Ren Xiaoming (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Wang Xianbao (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...) ,  Eder Dominik (Institute of Materials Chemistry, Technische Universitaet Wien, Austria) ,  Wang Kai (Dalian National Laboratory for Clean Energy, iChEM, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Liaoning, China) ,  Liu Shengzhong Frank (Dalian National Laboratory for Clean Energy, iChEM, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Liaoning, China) ,  Wang Shimin (Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei Key Laboratory of Polymer Materials, Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Materials Science and Engineering, Hubei University...)
資料名： ACS Applied Materials & Interfaces  (ACS Applied Materials & Interfaces)
巻： 14  号： 4  ページ： 5183-5193  発行年： 2022年 
JST資料番号： W2329A  ISSN： 1944-8244  CODEN： AAMICK  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： アメリカ合衆国 (USA)  言語： 英語 (EN)

抄録/ポイント： 全無機CsPbI_3ペロブスカイトは,他の光起電力デバイスとの組み合わせでタンデムセルで大きな可能性を有する。しかし,CsPbI_3ペロブスカイト太陽電池(PSC)は依然として大きな課題に直面し,有機-無機PSCに比べて低い電力変換効率(PCE)をもたらす。本研究では,SnO_2電子輸送層(ETL)とCsPbI_3全無機ペロブスカイト膜界面の間の緩衝層としてテトラブチルアンモニウムアセテート(TBAAc)を初めて導入した。TBAAcはSnO_2 ETLの伝導率を改善するだけでなく,SnO_2 ETLと3D CsPbI_3全無機ペロブスカイト膜の間に1D TBAPbI_3層を形成し,それによってCsPbI_3ペロブスカイトの表面欠陥を増強させ,高効率炭素対電極(CE)ベースのCsPbI_3太陽電池を作製した。FTO/SnO_2/TBAAc/CsPbI_3/C構造を有する炭素-CEベース正孔輸送層(HTL)フリーPSCを作製した。チャンピオンCsPbI_3PSCの開回路電圧(V_oc),短絡電流密度(J_sc),PCE,およびフィルファクタは,それぞれ1.08V,17.48mA/cm2,12.79,および67.8%に同時に増強された。このPCEは,現在,上記の平面構造炭素-CE系CsPbI_3PSCに対して報告された高効率の1つである。さらに,最適化デバイスは優れた安定性を示し,350時間後に初期PCEの83%以上を保持した。本研究はSnO_2ETLとCsPbI_3ペロブスカイト層の同時最適化の容易な方法を提供し,安定で高効率な炭素-CE系CsPbI_3PSCを作製した。Copyright 2022 American Chemical Society All rights reserved. Translated from English into Japanese by JST.【JST・京大機械翻訳】

シソーラス用語： 界面 ,  効率 ,  最適化 ,  *太陽電池 ,  炭素 ,  直列接続 ,  一次元 ,  三次元 ,  *バッファ層
準シソーラス用語： 高効率 ,  開回路電圧 ,  フィルファクタ ,  電力変換効率 ,  対極 ,  短絡電流密度 ,  *ペロブスカイト太陽電池 , 【Automatic Indexing@JST】

著者キーワード (5件)： 無機ペロブスカイト ,  CsPbI_3 ,  炭素対電極 ,  界面工学 ,  安定性

分類 (1件)： 太陽電池  (NC03084O)

タイトルに関連する用語 (4件)： 輸送 ,  バッファ層 ,  酢酸テトラブチルアンモニウム ,  ペロブスカイト太陽電池