Rchr
J-GLOBAL ID:200901050987444075
Update date: Aug. 08, 2024
Tobita Hiromi
トビタ ヒロミ | Tobita Hiromi
Affiliation and department:
Job title:
Program-Specific Professor
Homepage URL (2):
http://db.tohoku.ac.jp/whois/detail/0e6ea5aef10652e5d7231398c741b822.html
,
http://db.tohoku.ac.jp/whois/e_detail/0e6ea5aef10652e5d7231398c741b822.html
Research field (1):
Inorganic and coordination chemistry
Research keywords (5):
Photochemistry
, Metal Cluster
, Endohedral Metallofullerene
, Transition Metal Complex
, Silylene complex
Research theme for competitive and other funds (29):
- 2004 - 現在 Synthesis, properties, and chemical modification of endohedral metallofullerenes
- 1995 - 現在 Synthesis, Structures, Properties, and Reactivities of Complexes Having Peculiar Transition Metal-Main Group Element Bonds
- 1986 - 現在 Syntheses, Structures, properties, and Reactivities of Novel Transition Metal-Main Group Element Clusters
- 1985 - 現在 Synthesis, Structrures, Properties, and Reactivities of Transition Metal Complexes Containing Organosilicon, -germanium, and -tin Ligands
- 2018 - 2020 Development of Molecular Device Functions Making Use of Unique Orbital Interaction between Lithium Encapsulated Fullerene and Transition Metals
- 2015 - 2020 Development of Molecular Conversion Reactions Taking Advantage of the Reactivity of Transition Metal-Silicon/Germanium Multiple Bonds
- 2015 - 2018 Syntheses of active metal complexes that bear low-valent Group 14 element species as a Lewis acidic reactive site
- 2012 - 2017 Syntheses and Catalytic Function of Transition-metal Complexes Having Reactive Heavier Main Group ElementMetal Multiple Bonds
- 2011 - 2012 Development of the Chemistry of Transition Metal Complexes UsingLithium Encapsulated Fullerene as a Ligand
- 2010 - 2012 Reaction Search and Function Development for the Unsaturated Bonding Systems between Transition Metals and Heavier Group 14 Elements
- 2006 - 2009 Construction and Functions of the Unsaturated Bonds between Heavier Main Group Elements and Transition Metals
- 2006 - 2007 Construction of Novel Silicon-Transition Metal Multiple Bonds, Elucidation of the Mechanisms for Their Reactions, and Their Expansion to Catalytic Reactions
- 2002 - 2005 Construction and Functions of Dynamic Complexes Composed of Transition Metal/Efetero-Element Systems
- 2003 - 2004 ケイ素およびリンを含む小員環状遷移金属錯体の合成とその無機化合物合成への応用
- 2002 - 2004 Development of Novel Transformation Reactions of Silicon Compounds Utilizing Specific Reactivity of Transition Metal-Silylene Complexes
- 2002 - 2003 多様な典型元素-遷移金属結合を環内に含む多元素メタラサイクルの合成と性質
- 2001 - 2001 第3周期以降の多様な典型元素を環内に含む新規メタラサイクルの合成と性質
- 2000 - 2001 Synthesis and Properties of Transition Metal Complexes Having New Chelate Ligands with Silicon as a Coordinating Atom
- 2000 - 2000 混合金属型遷移金属-カルコゲンユニットの選択的集積化と活性化
- 1999 - 2000 単核シリレン錯体から出発する非対称なシリレン架橋二核錯体の合成
- 1997 - 2000 The Chemistry of Linkages between Main Group Elements and Transition Metals
- 1985 - 1999 Synthesis, Structures, Properties, and Reactivities of Transition Metal Complexes Coordinated with Novel Cyclopentadienyl Derivatives
- 1997 - 1999 Specific Chemical Conversion Based on the Cooperative Effect of Two Transition Metal Fragments in Close Proximity
- 1997 - 1998 Synthesis of Stable Silylene and Germylene Complexes and the Mechanistic Studies on Catalytic Reactions Utilizing Them
- 1995 - 1996 Chemistry of Transition Metal Supramolecules
- 1992 - 1992 錯体合成を指向したかさ高い一級および二級シランと遷移金属との反応の研究
- 1991 - 1991 シリリンおよびゲルミリンを配位子とする遷移金属錯体の合成と性質
- 1990 - 1990 置換シクロペンタジエニル配位子の特徴を生かした錯体の動的挙動のNMR的研究
- 1989 - 1990 Photo Chemical Syntheses and Reactivities of Organometallic Compounds Containing 4B Elements
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Papers (204):
-
Takashi Komuro, Kohei Hayasaka, Kasumi Takahashi, Nozomu Ishiwata, Kota Yamauchi, Hiromi Tobita, Hisako Hashimoto. Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles. Dalton Transactions. 2024. 53. 9. 4041-4047
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Masahiro Matsuoka, Koichi Nagata, Ryoma Ohno, Tsukasa Matsuo, Hiromi Tobita, Hisako Hashimoto. Neutral Chromium Complex with a Cr≡Si Triple Bond: Synthesis and Photoinduced H-H and Benzene C-H Bond Activation. Chemistry - A European Journal. 2023. 30. 9
-
Hisako Hashimoto, Kohei Watanabe, Takashi Yoshimoto, Naoki Hayakawa, Tsukasa Matsuo, Hiromi Tobita. Neutral Silylyne Complex of Molybdenum: Synthesis, Properties, and Access to Silaiminoacyl Complexes via [2+3] Cycloaddition. Chemistry - A European Journal. 2023. 29. 70
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Takahito Watanabe, Yoshikazu Miyazaki, Koya Inomata, Hiromi Tobita, Hisako Hashimoto. C-H and H-H Bond Activation by a Cationic Germylyne Complex. Organometallics. 2023. 42. 9. 846-858
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Koichi Nagata, Hirotaka Omura, Masahiro Matsuoka, Hiromi Tobita, Hisako Hashimoto. Photoinduced One-Pot Synthesis of a Chromium Germylyne Complex and Its Formation Mechanism. Organometallics. 2023. 42. 11. 1131-1138
more...
MISC (30):
Books (16):
-
Efficient Methods for Preparing Silicon Compounds
Academic Press 2016
-
基本無機化学 第3版
東京化学同人 2016
-
2013 ナノカーボン技術大全 “Li内包フラーレンの大量合成技術”
2013
-
“現代ケイ素化学” 体系的な基礎概念と応用に向けて
化学同人 2013
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有機金属化学の最前線-多様な元素を使いこなす- 現代化学増刊44
2011
more...
Lectures and oral presentations (52):
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Fascinated by Transition Metal-Silicon/Germanium Multiple Bonds -From Synthesis to Catalysis-
(2019)
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Dehydrogenative Formation of Metal-E (E = Ge, Si) Triple-Bonded Complexes from REH3 and Their Reactivity to Organic Molecules
(16th International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019) 2019)
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Hydroboration of Nitriles Catalyzed by a Ruthenium-Bis(silyl) Chelate Complex and Subsequent Deborylative N-Arylation
(7th Asian Silicon Symposium 2019)
-
Reactions of Transition Metal-Silicon Triple-Bonded Complexes with Various Unsaturated Organic Molecules
(The 18th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry 2018)
-
Recent Developments in the Chemistry of Tungsten-Germanium/Silicon Triple -Bonded Complexes
(43rd International Conference on Coordination Chemistry (ICCC2018) 2018)
more...
Education (2):
- - 1982 Tohoku University Graduate School, Division of Natural Science 化学
- - 1977 Tohoku University Faculty of Science 化学第二学科
Professional career (1):
Work history (9):
- 2022/04 - 現在 Tohoku University Institute for Excellence in Higher Education Program-Specific Professor
- 2021/08 - 2022/03 Tohoku University Institute for Excellence in Higher Education
- 2001/06 - 2020/03 Graduate School of Science, Tohoku University Professor
- 1995/04 - 2001/05 Graduate School of Science, Tohoku University Associate Professor
- 1992/04 - 1995/03 Faculty of Science, Tohoku University Associate Professor
- 1985/05 - 1992/03 Faculty of Science, Tohoku University Reasearch Associate
- 1984/05 - 1985/04 Institute for Fundamental Research, Kao Corporation Researcher
- 1982/05 - 1984/04 Massachusetts Institute of Technology (MIT) Postdoctoral Research Associate
- 1982/04 - Faculty of Science, Tohoku University JSPS Postdoctoral Fellow
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Committee career (24):
- 2021/06 - 現在 公益財団法人 日本化学研究会 理事長
- 2006/04 - 現在 The Society of Silicon Chemistry Japan 常任理事
- 2006/04 - 現在 ケイ素化学協会 常任理事
- 2004/04 - 現在 National Institution for Academic Degrees and University Evaluation 学位審査会専門委員
- 2004/04 - 現在 大学評価・学位授与機構 学位審査会専門委員
- 2002/04 - 現在 近畿化学協会 幹事
- 2002/04 - 現在 近畿化学協会 幹事
- 2015/08 - 2021/06 日本化学研究会 常務理事
- 2016/03 - 2017/02 日本化学会東北支部 支部長
- 2016/03 - 2017/02 日本化学会東北支部 支部長
- 2014/04 - 2016/03 The Society of Silicon Chemistry Japan 会長
- 2014/04 - 2016/03 ケイ素化学協会 会長
- 2013/04 - 2016/02 日本化学会東北支部 代議員
- 2013/04 - 2016/02 日本化学会東北支部 代議員
- 2007/04 - 2015/08 日本化学研究会 理事
- 2007/04 - 2015/08 日本化学研究会 理事
- 2011/03 - 2013/02 日本化学会東北支部 化学教育議長
- 2011/03 - 2013/02 日本化学会東北支部 化学教育議長
- 2008/10 - 2010/09 Japan Society of Coordination Chemistry 理事
- 2008/10 - 2010/09 錯体化学会 理事
- 2004/03 - 2007/02 Chemical Society of Japan Editor for Chemistry Letters
- 2004/03 - 2007/02 日本化学会 速報誌編集委員
- 2002/10 - 2004/09 Japan Society of Coordination Chemistry 理事
- 2002/10 - 2004/09 錯体化学会 理事
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Awards (3):
- 2019/11 - ケイ素化学協会 ケイ素化学協会賞 特異な遷移金属-ケイ素/ゲルマニウム結合を持つ錯体の合成と性質
- 2010/07/23 - International Conference on Organometallic Chemistry 24th International Conference on Organometallic Chemistry Poster Award
- 1988/04 - 日本化学会 The Chemical Society of Japan Award for Young Chemists 興味ある構造を有する新規な有機ケイ素化合物の合成,反応およびその遷移金属錯体化学への応用
Association Membership(s) (5):
日本化学研究会
, 近畿化学協会
, ケイ素化学協会
, Japan Society of Coordination Chemistry
, 日本化学会
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