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J-GLOBAL ID：200902007423994696   Reference number：90A0101820

Lewis acid promoted condensation of allylalkoxysilanes with carbonyl compounds. Synthesis of tetrahydropyrans.

Lewis酸触媒によるアリルアルコキシシランとカルボニル化合物の縮合 テトラヒドロピラン類の合成

Author (4)： WEI Z Y (Inst. Chemistry, Academia Sinica, Beijing, CHN) ,  WANG D (Inst. Chemistry, Academia Sinica, Beijing, CHN) ,  LI J S (Inst. Chemistry, Academia Sinica, Beijing, CHN) ,  CHAN T H (McGill Univ., Quebec, CAN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 54  Issue： 24  Page： 5768-5774  Publication year： Nov. 24, 1989 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： silanols ,...
Semi thesaurus term： hydropyrans ,...

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JST classification (3)： Pyranes  (CF07092R) ,  Organosilicon compounds  (CF08030C) ,  Aliphatic aldehydes  (CF03180F)

Substance index (23)： Allyl(α-methylbenzyloxy)dimethylsilane ,  Allyl[α-(methoxycarbonyl)benzyloxy]dimethylsilane ,  Allyl(hexan-2-yloxy)dimethylsilane ,  Allyl(benzyloxy)dimethylsilane ,  Allylphenoxydimethylsilane ,  Allyl[[(1R,3R,4S)-p-menthan-3-yl]oxy]dimethylsilane ,  Allyl[[(1R,5R)-7,7-dimethylbicyclo[3.1.1]hept-2-en-2-yl]oxy]dimethylsilane ,  Allyl[[(2R)-2-[(R)-4-methyl-3-cyclohexen-1-yl]propyl]oxy]dimethylsilane ,  (2R,6S)-4-Chloro-2,6-dipropyltetrahydro-2H-pyran ,  (2R,6S)-4-Chloro-2,6-dihexyltetrahydro-2H-pyran ,  (2R,6S)-4-Chloro-2,6-diisopropyltetrahydro-2H-pyran ,  (2R,6S)-4-Chloro-2,6-dicyclohexyltetrahydro-2H-pyran ,  (2R,6S)-4-Fluoro-2,6-dipropyltetrahydro-2H-pyran ,  (2R,6S)-4-Fluoro-2,6-dihexyltetrahydro-2H-pyran ,  (2R,6S)-4-Fluoro-2,6-diisopropyltetrahydro-2H-pyran ,  (2R,6S)-4-Fluoro-2,6-dioctyltetrahydro-2H-pyran ,  (2R,6S)-4-[α-(Methoxycarbonyl)benzyloxy]-2,6-dipropyltetrahydro-2H-pyran ,  (2R,6S)-4-[α-(Methoxycarbonyl)benzyloxy]-2,6-dihexyltetrahydro-2H-pyran ,  (2R,6S)-4-[α-(Methoxycarbonyl)benzyloxy]-2,6-diisopropyltetrahydro-2H-pyran ,  (2R,6S)-4-[α-(Methoxycarbonyl)benzyloxy]-2,6-dioctyltetrahydro-2H-pyran ,  rel-(2α^*,6α^*)-4-クロロ-2-プロピル-6-ヘキシルテトラヒドロ-2H-ピラン ,  rel-(2α^*,6α^*)-4-クロロ-2-プロピル-6-フェニルテトラヒドロ-2H-ピラン ,  rel-(2α^*,4α^*)-4-クロロ-2-イソプロピル-1-オキサスピロ[5.5]ウンデカン

Terms in the title (4)： Lewis酸触媒 ,  カルボニル化合物 ,  縮合 ,  テトラヒドロピラン類