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J-GLOBAL ID:200902011308902408   Reference number:88A0157999

1H,1H-perfluoroalkylation of enol silyl ethers with (1H,1H-perfluoroalkyl)-phenyliodonium triflates. A new method for the preparation of β- and δ-trifluoromethyl carbonyl compounds and their higher perfluoroalkyl homologues.

(1H,1H-ペルフルオロアルキル)フェニルヨードニウムトリフラートによるエノールシリルエーテルの1H,1H-ペルフルオロアルキル化 β-およびδ-トリフルオロメチルカルボニル化合物とそれらの高級ペルフルオロアルキル化同族体合成の新方法
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Material:
Volume: 60  Issue: 10  Page: 3823-3825  Publication year: Oct. 1987 
JST Material Number: G0450A  ISSN: 0009-2673  CODEN: BCSJA8  Document type: Article
Article type: 短報  Country of issue: Japan (JPN)  Language: ENGLISH (EN)
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Aliphatic ketones  ,  Aromatic monocyclic ketones  ,  Cyclohexanes  ,  7 or more-membered monocyclic alicyclic compounds  ,  Organosilicon compounds 
Reference (17):
  • 1) Presented at 52th National Meeting of Japanese Chemical Society, Abstract II, p. 1588 (1Z03), Apr. 1, 1986 (Kyoto).
  • 2) N. Ishikawa and Y. Kobayashi, “Fusso no Kag\\={o}butsu-sono Kagaku to \\={O}y\\={o},” Kodansha, Tokyo (1979);
  •  “Biomedicinal Aspects of Fluorine Chemistry,” ed by R. Filler and Y. Kobayashi, Kodansha Ltd., Tokyo (1982);
  •  R & D Report No. 6, “Fusso Kagobutsu no Saisentan \\={O}y\\={o} Gijutsu,” ed by N. Ishikawa, CMC, Tokyo (1981);
  •  “Preparation, Properties, and Industrial Applications of Organofluorine Compounds,” ed by R. E. Banks, Ellis Horwood Ltd., 1982 (Chichester).
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