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J-GLOBAL ID：200902023507885685   Reference number：92A0034972

Mechanism for Color Development in Purple Flower of Commumelina communis.

Coumelina communisの紫色の花弁における発色機構

Author (4)： KONDO T (Nagoya Univ., Nagoya, JPN) ,  YOSHIDA K (Sugiyama Jogakuen Univ., Nagoya, JPN) ,  YOSHIKANE M (Nagoya Univ., Nagoya, JPN) ,  GOTO T (Nagoya Univ., Nagoya, JPN)
Material： Agricultural and Biological Chemistry  (Agric Biol Chem)
Volume： 55  Issue： 11  Page： 2919-2921  Publication year： Nov. 1991 
JST Material Number： G0021A  ISSN： 0002-1369  CODEN： ABCHA6  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： purple ,...
Semi thesaurus term： コンメリニン ,...

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JST classification (1)： Development,growth,differentiation  (EH02030U)

Substance index (5)： Protodelphin ,  Flavocommelin ,  3′,4′,5′,7-Tetrahydroxy-3-[6-O-(4-hydroxy-cis-cinnamoyl)-β-D-glucopyranosyloxy]-5-[6-O-(3-hydroxy-1,3-dioxopropyl)-β-D-glucopyranosyloxy]flavylium ,  Delphinidin 3-O-β-glucoside ,  3-[6-O-(4-Hydroxycinnamoyl)-β-D-glucopyranosyloxy]-3′,4′,5,5′,7-pentahydroxyflavylium

Reference (11)：

• 1) K. Hayashi, Y. Abe and S. Mitsui, Proc. Jpn. Acad., 34, 373 (1958); S. Mitsui, K. Hayashi and S. Hattori, Proc. Jpn. Acad., 35, 169 (1959).
• 2) T. Goto, T. Kondo, H. Tamura and S. Takase, Tetrahedron Lett., 24, 4863 (1983).
• 3) K. Takeda and S. Mitsui, Bot. Mag. (Tokyo), 79, 578 (1966).4a) H. Tamura, T. Kondo and T. Goto, Tetrahedron Lett., 27, 1801 (1986); T. Goto, H. Tamura, T. Kawai, T. Hoshino, N. Harada and T. Kondo, Ann. N. Y. Acad. Sci., 471, 38 (1986).4b) T. Goto, Prog. Chem. Org. Nat. Prod., 52, 158 (1987).4c) T. Goto and T. Kondo, Angew. Chem. Int. Ed. Engl, 30, 17 (1991).
• 5) Column, Asahipak ODP-50; solvent, 0.5% TFA/10% CH₃CN aq. to 0.5% TFA/30% CH₃CN in a linear gradient for 30min.
• 6) Malonyl-m-awobanin (3) TFA salt: FABMS m/z 843; ¹H-NMR (10% TFAd-CD₃OD at 25°C and 500 MHz) J_α,β=13.0Hz and the other signals are very similar to malonylawobanin.

Terms in the title (3)： 紫色 ,  花弁 ,  発色