Art

J-GLOBAL ID：200902053339687224   Reference number：90A0602889

An endo-selective ionic Diels. Alder reaction of α,β-enone and α,β-enal acetals catalyzed by electrogenerated acid.

電解発生した酸の触媒作用によるα,β-エノンおよびα,β-エナールアセタールのendo選択的イオン性Diels-Alder反応

Author (3)： INOKUCHI T (Okayama Univ., Okayama, JPN) ,  TANIGAWA S (Okayama Univ., Okayama, JPN) ,  TORII S (Okayama Univ., Okayama, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 55  Issue： 12  Page： 3958-3961  Publication year： Jun. 08, 1990 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： vinyl compound ,...
Semi thesaurus term： bridged compound ,...

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JST classification (4)： Dioxoles,oxathioles,dithioles  (CF07079K) ,  Cyclopentanes  (CF04040L) ,  Cyclization reaction,ring-opening reaction  (CF02050I) ,  Electrochemical reaction  (CB07050F)

Substance index (10)： (1β,4β)-2α-(2-Methyl-1,3-dioxolan-2-yl)bicyclo[2.2.1]hept-5-ene ,  (1β,4β)-2α-(2-Ethyl-1,3-dioxolan-2-yl)bicyclo[2.2.1]hept-5-ene ,  (1β,4β)-2α-(1,3-Dioxolan-2-yl)bicyclo[2.2.1]hept-5-ene ,  (1β,4β)-2α-(2-Methyl-1,3-dioxolan-2-yl)bicyclo[2.2.2]oct-5-ene ,  (1β,4β)-2α-(2-Ethyl-1,3-dioxolan-2-yl)bicyclo[2.2.2]oct-5-ene ,  (1β,4β)-2α-(2-Methyl-1,3-dioxolan-2-yl)-3β-methylbicyclo[2.2.1]hept-5-ene ,  (1β,4β)-2α-(2-Methyl-1,3-dioxolan-2-yl)-2β-methylbicyclo[2.2.1]hept-5-ene ,  (1β,4β)-2α-(Diethoxymethyl)bicyclo[2.2.1]hept-5-ene ,  (1β,4β)-2α-(5,5-Dimethyl-1,3-dioxan-2-yl)bicyclo[2.2.1]hept-5-ene ,  2-(1,2-Dimethyl-1-cyclohexen-4-yl)-2-methyl-1,3-dioxolane

Terms in the title (6)： 電解 ,  酸 ,  触媒作用 ,  エノン ,  イオン性 ,  Diels-Alder反応