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J-GLOBAL ID：200902084253204665   Reference number：91A0339752

Construction of trifluoromethylated quarternary carbons via Diels-Alder reactions of 2-(trifluoromethyl)propenoic acid derivatives: Application to the synthesis of 16,16,16-trifluororetinal.

2-(トリフルオロメチル)プロペン酸誘導体のDiels-Alder反応によるトリフルオロメチル化四級炭素の構築 16,16,16-トリフルオロレチナールの合成への応用

Author (5)： HANZAWA Y (Tokyo Coll. Pharmacy, Tokyo, JPN) ,  SUZUKI M (Tokyo Coll. Pharmacy, Tokyo, JPN) ,  KOBAYASHI Y (Tokyo Coll. Pharmacy, Tokyo, JPN) ,  TAGUCHI T (Tokyo Coll. Pharmacy, Tokyo, JPN) ,  IITAKA Y (Teikyo Univ.)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 56  Issue： 5  Page： 1718-1725  Publication year： Mar. 01, 1991 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...
Semi thesaurus term： bridged compound ,...

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JST classification (4)： Cyclohexanes  (CF04050W) ,  Vitamin A  (EB07020A) ,  Aliphatic carboxylic acids,peroxycarboxylic acids,thiocarboxylic acids  (CF03200E) ,  Bridged bicyclic carbocyclic compounds  (CF06100Q)

Substance index (19)： 16,16,16-Trifluororetinal ,  (1S,4S)-2-(Trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2β-carboxylic acid ,  (1R,4R)-2-(Trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2β-carboxylic acid ,  (1S,4S)-2-(Trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2β-carboxylic acid [(R)-tetrahydro-4,4-dimethyl-2-oxofuran]-3-yl ester ,  (1R,4R)-2-(Trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2β-carboxylic acid [(R)-tetrahydro-4,4-dimethyl-2-oxofuran]-3-yl ester ,  2-(Trifluoromethyl)acrylic acid ,  α-(Trifluoromethyl)acrylic acid 2,2,2-trifluoroethyl ester ,  2-(Trifluoromethyl)propenoic acid [(R)-tetrahydro-4,4-dimethyl-2-oxofuran]-3-yl ester ,  4-Methyl-1-(trifluoromethyl)-3-cyclohexene-1-carboxylic acid ,  4-Methyl-1-(trifluoromethyl)-3-cyclohexene-1-carboxylic acid 2,2,2-trifluoroethyl ester ,  4-Methyl-1-(trifluoromethyl)-3-cyclohexene-1-carboxylic acid [(R)-tetrahydro-4,4-dimethyl-2-oxofuran]-3-yl ester ,  3-Methyl-1-(trifluoromethyl)-3-cyclohexene-1-carboxylic acid ,  1-Methyl-4-(trifluoromethyl)-2-oxabicyclo[2.2.2]octan-3-one ,  3a,6,7,7a-Tetrahydro-7a-(trifluoromethyl)isobenzofuran-1(3H)-one ,  1-(Trifluoromethyl)-4-oxo-2-cyclohexene-2-carboxylic acid 2,2,2-trifluoroethyl ester ,  3-Methyl-1-(trifluoromethyl)-4-oxo-2-cyclohexene-2-carboxylic acid 2,2,2-trifluoroethyl ester ,  3-Methyl-1-(trifluoromethyl)-4-oxo-2-cyclohexene-2-carboxylic acid [(R)-tetrahydro-4,4-dimethyl-2-oxofuran]-3-yl ester ,  18,18,18-Trifluororetinal ,  (2E,4E,6E)-7-[[3,4,4a,5,6,7-Hexahydro-8-(trifluoromethyl)-4a-methylnaphthalen]-2-yl]-3-methyl-2,4,6-octatrienal

Terms in the title (7)： プロペン酸 ,  誘導体 ,  Diels-Alder反応 ,  トリフルオロメチル化 ,  炭素 ,  構築 ,  応用