Art

J-GLOBAL ID：200902101338312680   Reference number：99A0066839

Tin- or magnesium-mediated diastereoselective aldol-type reactions for the asymmetric synthesis of α-substituted serines.

α-置換セリンの不斉合成のためのすず-又はマグネシウム-介在立体特異的アルドール型反応

Author (7)： SANO S (Univ. Tokushima, Tokushima, JPN) ,  MIWA T (Univ. Tokushima, Tokushima, JPN) ,  LIU X-K (Univ. Tokushima, Tokushima, JPN) ,  ISHII T (Univ. Tokushima, Tokushima, JPN) ,  TAKEHISA T (Univ. Tokushima, Tokushima, JPN) ,  SHIRO M (Rigaku Corp., Tokyo, JPN) ,  NAGAO Y (Univ. Tokushima, Tokushima, JPN)
Material： Tetrahedron: Asymmetry  (Tetrahedron Asym)
Volume： 9  Issue： 20  Page： 3615-3618  Publication year： Oct. 23, 1998 
JST Material Number： T0907A  ISSN： 0957-4166  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *asymmetric synthesis ,...
Semi thesaurus term： *Aldol condensation

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JST classification (2)： Amino acids  (CF10070V) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (15)： Benzaldehyde ,  Pentanal ,  Isobutyraldehyde ,  (5S)-2,5-Dihydro-3,6-diethoxy-5β-isopropylpyrazine-2-carboxylic acid ethyl ester ,  (2R,3S)-2-Amino-2-(hydroxymethyl)-3-hydroxy-4-methylpentanoic acid ethyl ester ,  (2R,3R)-2-Amino-2-(hydroxymethyl)-3-hydroxyheptanoic acid ethyl ester ,  (2R)-2-[(S)-1-(tert-Butyldimethylsiloxy)-2-methylpropyl]-2,5-dihydro-3,6-diethoxy-5β-isopropylpyrazine-2β-carboxylic acid ethyl ester ,  (2R)-2-[(R)-1-(tert-Butyldimethylsiloxy)-2-methylpropyl]-2,5-dihydro-3,6-diethoxy-5β-isopropylpyrazine-2β-carboxylic acid ethyl ester ,  (2R)-2-[(S)-1-(tert-Butyldimethylsiloxy)pentyl]-2,5-dihydro-3,6-diethoxy-5β-isopropylpyrazine-2β-carboxylic acid ethyl ester ,  (2R)-2-[(R)-1-(tert-Butyldimethylsiloxy)pentyl]-2,5-dihydro-3,6-diethoxy-5β-isopropylpyrazine-2β-carboxylic acid ethyl ester ,  (2R)-2-[(R)-α-(tert-Butyldimethylsiloxy)benzyl]-2,5-dihydro-3,6-diethoxy-5β-isopropylpyrazine-2β-carboxylic acid ethyl ester ,  (2R)-2-[(R)-1-(tert-Butyldimethylsiloxy)-3-methyl-2-butenyl]-2,5-dihydro-3,6-diethoxy-5β-isopropylpyrazine-2β-carboxylic acid ethyl ester ,  (2R,3R)-2-Amino-2-(hydroxymethyl)-3-(tert-butyldimethylsiloxy)-3-phenylpropanoic acid ethyl ester ,  (2R,3R)-2-Amino-2-(hydroxymethyl)-3-(tert-butyldimethylsiloxy)-5-methyl-4-hexenoic acid ethyl ester ,  3-Methyl-2-butenal

Terms in the title (6)： 置換 ,  セリン ,  不斉合成 ,  すず ,  マグネシウム ,  アルドール型反応