Art

J-GLOBAL ID：200902101450863486   Reference number：00A0775096

A new preparation of 2,5-dihydro-1-benzoxepins using Mitsunobu cyclization, and the synthesis of natural radulanins.

Mitsunobu環化を用いた2,5-ジヒドロ-1-ベンゾオキセピンの新しい調製法と天然ラズラニン類の合成

Author (5)： YAMAGUCHI S (Toyama Univ., Toyama, JPN) ,  FURIHATA K (Toyama Univ., Toyama, JPN) ,  MIYAZAWA M (Toyama Univ., Toyama, JPN) ,  YOKOYAMA H (Toyama Univ., Toyama, JPN) ,  HIRAI Y (Toyama Univ., Toyama, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 41  Issue： 24  Page： 4787-4790  Publication year： Jun. 15, 2000 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (1)： Seven-membered heterocyclic compounds  (CF07110I)

Substance index (24)： Radulanin A ,  Radulanin A methyl ether ,  2-(tert-Butyldimethylsiloxy)benzyl bromide ,  1-(Methoxymethoxy)-2-(bromomethyl)benzene ,  [(Z)-2-Methyl-3-(tetrahydro-2H-pyran-2-yloxy)-1-propenyl]trimethylstannane ,  2-[(2Z)-3-Methyl-4-hydroxy-2-butenyl]phenol ,  3-Methyl-2,5-dihydro-1-benzoxepin ,  2-[(2Z)-3-Methyl-4-hydroxy-2-butenyl]-3-methoxy-5-phenethylphenol ,  2-[(2Z)-3-Methyl-4-hydroxy-2-butenyl]-5-phenethylresorcinol ,  2,6-Dimethoxy-4-phenethylbenzaldehyde ,  1,3-Dimethoxy-2-(bromomethyl)-5-phenethylbenzene ,  1,3-Dimethoxy-2-[(2Z)-3-methyl-4-(tetrahydro-2H-pyran-2-yloxy)-2-butenyl]-5-phenethylbenzene ,  2-[(2Z)-3-Methyl-4-(tetrahydro-2H-pyran-2-yloxy)-2-butenyl]-3-methoxy-5-phenethylphenol ,  2-Methoxy-4-phenethyl-6-hydroxybenzaldehyde ,  1-(tert-Butyldimethylsiloxy)-2-(bromomethyl)-3-methoxy-5-phenethylbenzene ,  2-Methoxy-6-(methoxymethoxy)-4-phenethylbenzyl bromide ,  1-(tert-Butyldimethylsiloxy)-2-[(2Z)-3-methyl-4-(tetrahydro-2H-pyran-2-yloxy)-2-butenyl]-3-methoxy-5-phenethylbenzene ,  1-(Methoxymethoxy)-2-[(2Z)-3-methyl-4-(tetrahydro-2H-pyran-2-yloxy)-2-butenyl]-3-methoxy-5-phenethylbenzene ,  2,6-Dihydroxy-4-phenethylbenzaldehyde ,  1,3-Di(tert-butyldimethylsiloxy)-2-(bromomethyl)-5-phenethylbenzene ,  2,6-Bis(methoxymethoxy)-4-phenethylbenzyl bromide ,  1,3-Di(methoxymethoxy)-2-[(2Z)-3-methyl-4-(tetrahydro-2H-pyran-2-yloxy)-2-butenyl]-5-phenethylbenzene ,  1-(Tetrahydro-2H-pyran-2-yloxy)-2-[(2Z)-3-methyl-4-(tetrahydro-2H-pyran-2-yloxy)-2-butenyl]-3-methoxy-5-phenethylbenzene ,  2-[(2Z)-3-Methyl-4-(tetrahydro-2H-pyran-2-yloxy)-2-butenyl]-3-(tetrahydro-2H-pyran-2-yloxy)-5-phenethylphenol

Terms in the title (3)： 環化 ,  ベンゾオキセピン ,  調製法