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J-GLOBAL ID：200902105454205810   Reference number：00A1013086

Stereoselective Conjugate Addition of Alkyl Groups to (S)-4-(tert-Butyldimethylsilyloxy)-2-cyclopentenone Derivatives.

(S)-4-(t-ブチルジメチルシリルオキシ)-2-シクロペンテノン誘導体へのアルキル基の立体選択的共役付加

Author (5)： YAKURA T (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  TANAKA K (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  KITANO T (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  UENISHI J (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  IKEDA M (Kyoto Pharmaceutical Univ., Kyoto, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 56  Issue： 39  Page： 7715-7721  Publication year： Sep. 22, 2000 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： conjugation ,...

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JST classification (2)： Cyclopentanes  (CF04040L) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (19)： Toluene ,  (4S)-4-(tert-Butyldimethylsiloxy)-2-(phenylsulfonyl)-2-cyclopentene-1-one ,  (3S)-3-(tert-Butyldimethylsiloxy)-5-oxo-1-cyclopentene-1-carboxylic acid methyl ester ,  (2S,3R,4S)-2-(Phenylsulfonyl)-3-methyl-4-(tert-butyldimethylsilyloxy)cyclopentanone ,  (2S,3R,4S)-2-(Phenylsulfonyl)-3-ethyl-4-(tert-butyldimethylsilyloxy)cyclopentanone ,  (2S,3R,4S)-2-(Phenylsulfonyl)-3-isobutyl-4-(tert-butyldimethylsilyloxy)cyclopentanone ,  (2S,3R,4S)-2-(Phenylsulfonyl)-3-vinyl-4-(tert-butyldimethylsilyloxy)cyclopentanone ,  (1S)-2α-Methyl-3β-(tert-butyldimethylsilyloxy)-5-oxocyclopentane-1β-carboxylic acid methyl ester ,  (1S)-2α-Butyl-3β-[(tert-butyldimethylsilyl)oxy]-5-oxocyclopentane-1β-carboxylic acid methyl ester ,  (1α)-2β-Methyl-3β-(tert-butyldimethylsiloxy)-5-oxocyclopentanecarboxylic acid methyl ester ,  (1R)-2β-Butyl-3β-[(tert-butyldimethylsilyl)oxy]-5-oxocyclopentane-1α-carboxylic acid methyl ester ,  (4S)-2-(Phenylsulfonyl)-4-(triisopropylsilyloxy)-2-cyclopentene-1-one ,  (4S)-2-(Phenylsulfonyl)-4-methyl-2-cyclopentene-1-one ,  2α-(Phenylsulfonyl)-3β-methyl-4β-(tert-butyldimethylsiloxy)cyclopentanone ,  2α-(Phenylsulfonyl)-3β-ethyl-4β-(tert-butyldimethylsiloxy)cyclopentanone ,  2α-(Phenylsulfonyl)-3β-isobutyl-4β-(tert-butyldimethylsiloxy)cyclopentanone ,  (2R,3S,4S)-2-(Phenylsulfonyl)-3-[(trimethylsilyl)ethynyl]-4-(tert-butyldimethylsilyloxy)cyclopentanone ,  2β-(Phenylsulfonyl)-3α-[(trimethylsilyl)ethynyl]-4β-(tert-butyldimethylsiloxy)cyclopentanone ,  (2R,3S,4S)-2-(Phenylsulfonyl)-3-methyl-4-(triisopropylsilyloxy)cyclopentanone

Terms in the title (4)： シクロペンテノン誘導体 ,  アルキル基 ,  立体 ,  共役付加