Art

J-GLOBAL ID：200902106849225426   Reference number：00A0649104

Highly enantioselective synthesis of 1,3-mercapto alcohols from α,β-unsaturated ketones: asymmetric bifunctional group exchange reaction.

α,β-不飽和ケトンからの1,3-メルカプトアルコール類の高エナンチオ選択的合成 不斉二官能基交換反応

Author (3)： SHIRAKI H (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  NISHIDE K (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  NODE M (Kyoto Pharmaceutical Univ., Kyoto, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 41  Issue： 18  Page： 3437-3441  Publication year： Apr. 29, 2000 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...

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JST classification (2)： Aliphatic ketones  (CF03190Q) ,  Aliphatic thiols  (CF03120R)

Substance index (30)： 2α-(1-Methyl-1-mercaptoethyl)-5β-methylcyclohexan-1β-ol ,  Dimethylaluminum chloride ,  Pulegone ,  (4α)-1β,7,7-Trimethyl-3β-(mercaptomethyl)bicyclo[2.2.1]heptane-2α-ol ,  (+)-Methylenecamphor ,  (4α)-1β,7,7-Trimethyl-3-(benzylthiomethyl)bicyclo[2.2.1]heptane-2-one ,  Methyl vinyl ketone ,  4-Methyl-3-penten-2-one ,  trans-Chalcone ,  4-Chloro-trans-chalcone ,  4-Methoxy-trans-chalcone ,  4-Methyl-trans-chalcone ,  Methyl ((E)-styryl) ketone ,  (E)-1-Phenyl-1-undecene-3-one ,  (4α)-1β,7,7-Trimethyl-3β-[[(R)-3-hydroxybutyl]thiomethyl]bicyclo[2.2.1]heptane-2-one ,  (4α)-1β,7,7-Trimethyl-3β-[[(R)-1,1-dimethyl-3-hydroxybutyl]thiomethyl]bicyclo[2.2.1]heptane-2-one ,  (4α)-1β,7,7-Trimethyl-3β-[[(1S,3S)-1,3-diphenyl-3-hydroxypropyl]thiomethyl]bicyclo[2.2.1]heptane-2-one ,  (4α)-1β,7,7-Trimethyl-3β-[[(1S,3S)-1-(4-chlorophenyl)-3-phenyl-3-hydroxypropyl]thiomethyl]bicyclo[2.2.1]heptane-2-one ,  (4α)-1β,7,7-Trimethyl-3β-[[(1S,3S)-1-(4-methoxyphenyl)-3-phenyl-3-hydroxypropyl]thiomethyl]bicyclo[2.2.1]heptane-2-one ,  (4α)-1β,7,7-Trimethyl-3β-[[(1S,3S)-1-(4-methylphenyl)-3-phenyl-3-hydroxypropyl]thiomethyl]bicyclo[2.2.1]heptane-2-one ,  (4α)-1β,7,7-Trimethyl-3β-[[(1S,3R)-1-phenyl-3-hydroxybutyl]thiomethyl]bicyclo[2.2.1]heptane-2-one ,  (4α)-1β,7,7-Trimethyl-3β-[[(1S,3R)-1-phenyl-3-hydroxyundecyl]thiomethyl]bicyclo[2.2.1]heptane-2-one ,  (R)-4-Mercapto-2-butanol ,  (R)-4-Mercapto-4-methyl-2-pentanol ,  (1S,3S)-1,3-Diphenyl-3-mercapto-1-propanol ,  (1S,3S)-1-Phenyl-3-(4-chlorophenyl)-3-mercapto-1-propanol ,  (1S,3S)-1-Phenyl-3-(4-methoxyphenyl)-3-mercapto-1-propanol ,  (1S,3S)-1-Phenyl-3-(4-methylphenyl)-3-mercapto-1-propanol ,  (2R,4S)-4-Mercapto-4-phenyl-2-butanol ,  (1S,3R)-1-Mercapto-1-phenylundecane-3-ol

Terms in the title (4)： 不飽和ケトン ,  エナンチオ選択的合成 ,  官能基 ,  交換反応