Art

J-GLOBAL ID：200902107614457377   Reference number：02A0716609

1,2-Silyl-Migrative Cyclization of Vinylsilanes Bearing a Hydroxy Group: Stereoselective Synthesis of Multisubstituted Tetrahydropyrans and Tetrahydrofurans.

ヒドロキシル基を持つビニルシランの1,2-シリル基移動的環化 多置換テトラヒドロピランおよびテトラヒドロフランの立体選択的合成

Author (6)： MIURA K (Univ. Tsukuba, Ibaraki, JPN) ,  HONDO T (Univ. Tsukuba, Ibaraki, JPN) ,  OKAJIMA S (Univ. Tsukuba, Ibaraki, JPN) ,  NAKAGAWA T (Univ. Tsukuba, Ibaraki, JPN) ,  TAKAHASHI T (Univ. Tsukuba, Ibaraki, JPN) ,  HOSOMI A (Univ. Tsukuba, Ibaraki, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 67  Issue： 17  Page： 6082-6090  Publication year： Aug. 23, 2002 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： vinyl compound ,...
Semi thesaurus term： hydroxyl group

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JST classification (3)： Pyranes  (CF07092R) ,  Organosilicon compounds  (CF08030C) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (38)： (Z)-5-(Dimethylphenylsilyl)-4-nonen-1-ol ,  (Z)-5-(Trimethylsilyl)-4-nonen-1-ol ,  (Z)-5-(Methyldiphenylsilyl)-4-nonen-1-ol ,  (Z)-5-(tert-Butyldimethylsilyl)-4-nonen-1-ol ,  (Z)-5-(Benzyldimethylsilyl)-4-nonene-1-ol ,  (Z)-5-[Dimethyl(4-methylphenyl)silyl]-4-nonene-1-ol ,  (Z)-5-[Dimethyl(4-methoxyphenyl)silyl]-4-nonene-1-ol ,  (Z)-5-[Dimethyl[4-(trifluoromethyl)phenyl]silyl]-4-nonene-1-ol ,  (Z)-5-(Dimethylphenylsilyl)-4-hexene-1-ol ,  (Z)-5-(Dimethylphenylsilyl)-8-(benzyloxy)-4-octene-1-ol ,  Acetic acid (Z)-4-(dimethylphenylsilyl)-8-hydroxy-4-octenyl ester ,  (Z)-5-(Dimethylphenylsilyl)-5-phenyl-4-pentene-1-ol ,  (E)-5-(Dimethylphenylsilyl)-5-bromo-4-pentene-1-ol ,  (Z)-5-(Dimethylphenylsilyl)-5-(trimethylsilyl)-4-pentene-1-ol ,  rel-2α^*-Butyl-3β^*-(phenyldimethylsilyl)tetrahydro-2H-pyran ,  rel-2α^*-ブチル-3β^*-(トリメチルシリル)テトラヒドロ-2H-ピラン ,  rel-2α^*-ブチル-3β^*-(メチルジフェニルシリル)テトラヒドロ-2H-ピラン ,  rel-2α^*-ブチル-3β^*-(tert-ブチルジメチルシリル)テトラヒドロ-2H-ピラン ,  rel-2α^*-Butyl-3β^*-(benzyldimethylsilyl)tetrahydro-2H-pyran ,  rel-2α^*-Butyl-3β^*-[dimethyl(4-methylphenyl)silyl]tetrahydro-2H-pyran ,  rel-2α^*-Butyl-3β^*-[dimethyl(4-methoxyphenyl)silyl]tetrahydro-2H-pyran ,  rel-2α^*-Butyl-3β^*-[dimethyl[4-(trifluoromethyl)phenyl]silyl]tetrahydro-2H-pyran ,  rel-2α^*-Methyl-3β^*-(phenyldimethylsilyl)tetrahydro-2H-pyran ,  rel-2α^*-[3-(Benzyloxy)propyl]-3β^*-(phenyldimethylsilyl)tetrahydro-2H-pyran ,  rel-Acetic acid 3-[3β^*-(phenyldimethylsilyl)tetrahydro-2H-pyran-2α^*-yl]propyl ester ,  2-[(Trimethylsilyl)(phenyldimethylsilyl)methyl]tetrahydrofuran ,  (Z)-4-(Dimethylphenylsilyl)-3-octen-1-ol ,  (Z)-4-(Dimethyltert-butylsilyl)-3-octen-1-ol ,  (Z)-4-(Benzyldimethylsilyl)-3-octene-1-ol ,  (E)-4-(Dimethylphenylsilyl)-3-octene-1-ol ,  (E)-4-(Dimethyl tert-butylsilyl)-3-octene-1-ol ,  (E)-4-(Benzyldimethylsilyl)-3-octene-1-ol ,  rel-2α^*-ブチル-3β^*-(tert-ブチルジメチルシリル)テトラヒドロフラン ,  (Z)-4-(Dimethylphenylsilyl)-7-(benzyloxy)-3-heptene-1-ol ,  rel-2α^*-[3-(Benzyloxy)propyl]-3β^*-(phenyldimethylsilyl)tetrahydrofuran ,  2-Phenyl-5-(benzyldimethylsilyl)-4-nonene-1-ol ,  rel-2α^*-Butyl-3β^*-(benzyldimethylsilyl)-5-phenyltetrahydro-2H-pyran ,  rel-2β^*-[(S^*)-1-(Benzyldimethylsilyl)pentyl]-4-phenyltetrahydrofuran

Terms in the title (8)： ヒドロキシル基 ,  ビニルシラン ,  シリル基 ,  環化 ,  置換 ,  テトラヒドロピラン ,  テトラヒドロフラン ,  立体選択的合成