Art

J-GLOBAL ID：200902108238380631   Reference number：00A0848676

Catalytic Asymmetric Borane Reduction of Prochiral Ketones by the Use of Chiral β-Diamines.

キラルなβ-ジアミンを用いるプロキラルなケトンの接触不斉ボラン還元

Author (3)： ASAMI M (Yokohama National Univ., Yokohama) ,  SATO S (Yokohama National Univ., Yokohama) ,  WATANABE H (Yokohama National Univ., Yokohama)
Material： Chemistry Letters  (Chem Lett)
Issue： 9  Page： 990-991  Publication year： Sep. 05, 2000 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *catalytic reduction ,...

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JST classification (3)： Aliphatic ketones  (CF03190Q) ,  Condensed derivatives of pyrroles  (CF07077C) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (21)： Acetophenone ,  Propiophenone ,  (2S)-2-(Anilinomethyl)pyrrolidine ,  (2S)-N-Phenylindoline-2α-methanamine ,  (2S)-N-Cyclohexylindoline-2α-methanamine ,  (2S)-N-(2-Methylphenyl)indoline-2α-methanamine ,  (2S)-N-(2,6-Dimethylphenyl)indoline-2α-methanamine ,  (2S)-N-[4-(Trifluoromethyl)phenyl]indoline-2α-methanamine ,  (2S)-N-[3,5-Bis(trifluoromethyl)phenyl]indoline-2α-methanamine ,  (R)-1-Phenylethanol ,  2'-Bromoacetophenone ,  α-Chloroacetophenone ,  Tetralin-1-one ,  2-Octanone ,  4-Phenyl-3-buten-2-one ,  (R)-1-(2-Bromophenyl)ethanol ,  (S)-1-Phenyl-2-chloroethanol ,  (R)-1-Phenyl-1-propanol ,  (R)-Tetralin-1-ol ,  (R)-2-Octanol ,  (2R)-4-Phenyl-3-buten-2-ol

Reference (21)：

• 1) S. Itsuno, K. Ito, A. Hirao, and S. Nakahama, J. Chem. Soc., Chem. Commun., 1983, 469.
• 2) E. J. Corey, R. K. Bakshi, and S. Shibata, J. Am. Chem. Soc., 109, 5551 (1987).
• 3) For reviews: L. Deloux and M. Srebnik, Chem. Rev., 93, 763 (1993);
•  E. J. Corey and C. J. Helal, Angew. Chem., Int. Ed. Engl., 37, 1986 (1998);
•  For recent examples: P. Pinho, D. Guijarro, and P. G. Andersson, Tetrahedron, 54, 7897 (1998);

Terms in the title (5)： キラル ,  ジアミン ,  ケトン ,  ボラン ,  還元