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J-GLOBAL ID：200902108548502761   Reference number：01A0022952

Stereoselective Synthesis of 5-(1-Hydroxyalkyl)-2-Pyrrolidinones Utilizing Oxidation of 5-Alkylidene-2-Pyrrolidinones to Acyliminium Ion Precursors.

5-アルキリデン-2-ピロリジノン類をアシルイミニウムイオンの前駆体へ酸化する方法を用いた5-(1-ヒドロキシアルキル)-2-ピロリジノン類の立体選択的合成

Author (5)： KOSEKI Y (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  KUSANO S (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  ICHI D (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  YOSHIDA K (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  NAGASAKA T (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 56  Issue： 45  Page： 8855-8865  Publication year： Nov. 03, 2000 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： base catalytic reaction ,...
Semi thesaurus term： iminium salt ,...

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JST classification (2)： Pyrroles  (CF07076L) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (38)： N-(3-Methoxybenzyl)-5-(4-methoxyphenyl)-4-pentynamide ,  N-(3-Methoxybenzyl)-4-pentynamide ,  N-(3-Methoxybenzyl)-4-hexynamide ,  1-(3-Methoxybenzyl)-5-[(Z)-4-methoxybenzylidene]-2-pyrrolidone ,  1-(3-Methoxybenzyl)-5-[(E)-4-methoxybenzylidene]pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-5-methylene-2-pyrrolidone ,  1-(3-Methoxybenzyl)-5-methyl-1H-pyrrole-2(3H)-one ,  N-[(1S)-1-Phenylethyl]-4-hexynamide ,  N-[(1R)-1-Phenyl-2-methoxyethyl]-4-hexynamide ,  N-[(1R)-1-Phenyl-2-(tert-pentyloxy)ethyl]-4-hexynamide ,  N-(3-Methoxybenzyl)-8-chloro-4-octynamide ,  N-(3-Methoxybenzyl)-4-heptadecynamide ,  N-(3-Methoxybenzyl)-5-(4-chlorophenyl)-4-pentynamide ,  N-[2-(Benzyloxy)ethyl]-5-(1,3-benzodioxole-5-yl)-4-pentynamide ,  1-(3-Methoxybenzyl)-5-[(Z)-ethylidene]-2-pyrrolidone ,  1-[(1S)-1-Phenylethyl]-5-[(Z)-ethylidene]pyrrolidine-2-one ,  1-[(1R)-1-Phenyl-2-methoxyethyl]-5-[(Z)-ethylidene]pyrrolidine-2-one ,  1-[(1R)-1-Phenyl-2-(tert-pentyloxy)ethyl]-5-[(Z)-ethylidene]pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-5-[(Z)-4-chlorobutylidene]pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-5-[(Z)-tridecylidene]pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-5-[(Z)-4-chlorobenzylidene]pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-5-[(E)-4-chlorobenzylidene]pyrrolidine-2-one ,  1-[2-(Benzyloxy)ethyl]-5-[(E)-(1,3-benzodioxole-5-yl)methylene]pyrrolidine-2-one ,  1-[2-(Benzyloxy)ethyl]-5-[(Z)-(1,3-benzodioxole-5-yl)methylene]pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-5-methoxy-5-(α-hydroxy-4-methoxybenzyl)pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-5-methoxy-5-(1-hydroxyethyl)pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-5-hydroxy-5-(α-hydroxy-4-methoxybenzyl)pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-5-hydroxy-5-(1-hydroxyethyl)pyrrolidine-2-one ,  1-(3-Methoxybenzyl)-2,5-pyrrolidinedione ,  Triethylsilane ,  (5R)-1-(3-Methoxybenzyl)-5-[(αR)-α-hydroxy-4-methoxybenzyl]pyrrolidine-2-one ,  (5R)-1-(3-Methoxybenzyl)-5-[(1R)-1-hydroxyethyl]pyrrolidine-2-one ,  (5S)-1-(3-Methoxybenzyl)-5-[(αR)-α-hydroxy-4-methoxybenzyl]pyrrolidine-2-one ,  (5S)-1-(3-Methoxybenzyl)-5-[(1R)-1-hydroxyethyl]pyrrolidine-2-one ,  (5R)-1-(3-Methoxybenzyl)-5-[(1R)-1-hydroxy-4-chlorobutyl]pyrrolidine-2-one ,  (5R)-1-(3-Methoxybenzyl)-5-[(1R)-1-hydroxytridecyl]pyrrolidine-2-one ,  (5S)-1-(3-Methoxybenzyl)-5-[(1S)-1-hydroxytridecyl]pyrrolidine-2-one ,  (+)-Azamuricatacin

Terms in the title (5)： 2-ピロリジノン ,  前駆体 ,  酸化 ,  ヒドロキシアルキル ,  立体選択的合成