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J-GLOBAL ID：200902108860925670   Reference number：01A1044157

Highly Stereoselective Synthesis of Homoallylic Amines Based on Addition of Allyltrichlorosilanes to Benzoylhydrazones.

アリルトリクロロシランのベンゾイルヒドラゾンへの付加に基づくホモアリル性アミンの高立体選択的合成

Author (4)： HIRABAYASHI R (Univ. Tokyo) ,  OGAWA C (Univ. Tokyo) ,  SUGIURA M (Univ. Tokyo) ,  KOBAYASHI S (Univ. Tokyo)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 123  Issue： 39  Page： 9493-9499  Publication year： Oct. 03, 2001 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (4)： Organosilicon compounds  (CF08030C) ,  Aliphatic aldehydes  (CF03180F) ,  Aliphatic amines,imines,quaternary ammonium,immonium compounds  (CF03070L) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (51)： Benzaldehyde benzoylhydrazone ,  trans-Cinnamaldehyde benzoylhydrazone ,  3-Phenylpropanal benzoylhydrazone ,  Pentanal benzoylhydrazone ,  N′-(Cyclohexylmethylene)benzohydrazide ,  2,2-Dimethylpropanal benzoylhydrazone ,  Allyltrichlorosilane ,  N′-(1-Phenyl-3-butenyl)benzhydrazide ,  N′-(1-trans-Styryl-3-butenyl)benzhydrazide ,  N′-(1-Phenethyl-3-butenyl)benzhydrazide ,  N′-(1-Allylhexyl)benzhydrazide ,  N′-(1-Isobutyl-3-butenyl)benzhydrazide ,  N′-(1-Cyclohexyl-3-butenyl)benzhydrazide ,  N′-(1-tert-Butyl-3-butenyl)benzhydrazide ,  Acetophenone N-benzoyl hydrazone ,  4′-Methoxyacetophenone benzoylhydrazone ,  3′-Nitroacetophenone benzoylhydrazone ,  1-(2-Naphthyl)ethanone benzoylhydrazone ,  Acetone benzoylhydrazone ,  4-Phenyl-2-butanone benzoylhydrazone ,  Methylcyclohexyl ketone benzoylhydrazone ,  Butyrophenone benzoylhydrazone ,  1-(α-Methyl-α-allylbenzyl)-2-benzoylhydrazine ,  N′-[1-(4-Methoxyphenyl)-1-methyl-3-butenyl]benzhydrazide ,  N′-[1-(3-Nitrophenyl)-1-methyl-3-butenyl]benzhydrazide ,  N′-[1-(2-Naphthyl)-1-methyl-3-butenyl]benzhydrazide ,  N′-(1,1-Dimethyl-3-butenyl)benzhydrazide ,  N′-(1-Phenethyl-1-methyl-3-butenyl)benzhydrazide ,  N′-(1-Allylcyclohexyl)benzhydrazide ,  N′-(1-Phenyl-1-propyl-3-butenyl)benzhydrazide ,  ((Z)-2-Butenyl)trichlorosilane ,  N′-(1-Phenyl-2-methyl-3-butenyl)benzhydrazide ,  N′-[1-[(E)-Styryl]-2-methyl-3-butenyl]benzhydrazide ,  N′-(1-Phenethyl-2-methyl-3-butenyl)benzhydrazide ,  N′-(1-Phenethyl-2-methyl-3-pentenyl)benzhydrazide ,  N′-[1-(1-Methyl-2-propenyl)hexyl]benzhydrazide ,  N′-(1-Isobutyl-2-methyl-3-butenyl)benzhydrazide ,  N′-(1-Cyclohexyl-2-methyl-3-butenyl)benzhydrazide ,  N′-(1-tert-Butyl-2-methyl-3-butenyl)benzhydrazide ,  Trichloroprenylsilane ,  N′-(1-Phenyl-2,2-dimethyl-3-butenyl)benzhydrazide ,  N′-[1-[(E)-Styryl]-2,2-dimethyl-3-butenyl]benzhydrazide ,  N′-(1-Phenethyl-2,2-dimethyl-3-butenyl)benzhydrazide ,  (S)-2-(Benzyloxycarbonylamino)-3-phenylpropanal benzoylhydrazone ,  N′-[(R)-1-[(S)-α-(Benzyloxycarbonylamino)phenethyl]-3-butenyl]benzhydrazide ,  (2S)-2-(Benzyloxy)propionaldehyde benzoylhydrazone ,  (2S)-2-(tert-Butyldimethylsiloxy)propionaldehyde benzoylhydrazone ,  N′-[(R)-1-[(S)-1-(Benzyloxy)ethyl]-3-butenyl]benzhydrazide ,  N′-[(R)-1-[(S)-1-(tert-Butyldimethylsiloxy)ethyl]-3-butenyl]benzhydrazide ,  N′-[(R)-1-[(S)-1-Hydroxyethyl]-3-butenyl]benzhydrazide ,  (1S,2S)-1-Phenyl-2-methyl-3-butene-1-amine

Terms in the title (5)： アリルトリクロロシラン ,  ホモ ,  アリル ,  アミン ,  立体選択的合成