Art

J-GLOBAL ID：200902111972936144   Reference number：01A0895937

Synthetic studies toward C-1027 chromophore: construction of a highly unsaturated macrocycle.

C-1027発色団の合成研究 高度不飽和大環状化合物の構築

Author (3)： SASAKI T (Tohoku Univ., Sendai, JPN) ,  INOUE M (Tohoku Univ., Sendai, JPN) ,  HIRAMA M (Tohoku Univ., Sendai, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 42  Issue： 31  Page： 5299-5303  Publication year： Jul. 30, 2001 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *macrocyclic compound ,...

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JST classification (1)： Eight or more-membered heterocyclic compounds  (CF07120T)

Substance index (17)： C-1027 chromophore ,  (2S,3S)-2β-Ethynyl-4-iodo-6β-(2-ethoxyethoxy)-1-oxaspiro[2.4]heptane-4-ene ,  (2S,3S)-2-(4-Methoxybenzyloxy)-3-(4,4′-dimethoxytrityloxymethyl)-4-pentyne-1,3-diol ,  (3S)-N-(tert-Butoxycarbonyl)-3-[3-(methoxymethoxy)-4-hydroxy-5-chlorophenyl]-β-alanine methyl ester ,  (3S)-N-(tert-Butoxycarbonyl)-3-[3-(methoxymethoxy)-4-[[(R)-1-[(1S)-1-hydroxy-2-iodo-4β-(2-ethoxyethoxy)-2-cyclopenten-1α-yl]-2-propynyl]oxy]-5-chlorophenyl]-β-alanine methyl ester ,  (3S)-N-(tert-Butoxycarbonyl)-3-[3-(methoxymethoxy)-4-[[(R)-1-[(1S)-1-hydroxy-2-iodo-4β-(tert-butyldimethylsiloxy)-2-cyclopentene-1α-yl]-2-propynyl]oxy]-5-chlorophenyl]-β-alanine methyl ester ,  (3S)-N-(tert-Butoxycarbonyl)-3-[3-(methoxymethoxy)-4-[[(R)-1-[(1S)-1-(trimethylsiloxy)-2-iodo-4β-(tert-butyldimethylsiloxy)-2-cyclopentene-1α-yl]-3-(trimethylsilyl)-2-propynyl]oxy]-5-chlorophenyl]-β-alanine methyl ester ,  Acetic acid (2S,3S)-2-(4-methoxybenzyloxy)-3-(4,4′-dimethoxytrityloxymethyl)-3-(triethylsiloxy)-4-pentynyl ester ,  (3S)-N-(tert-Butoxycarbonyl)-3-[3-(methoxymethoxy)-4-[[(R)-1-[(1R)-1-(trimethylsiloxy)-2-[(3S,4S)-3-(triethylsiloxy)-3-(4,4′-dimethoxytrityloxymethyl)-4-(4-methoxybenzyloxy)-5-acetoxy-1-pentynyl]-4β-(tert-butyldimethylsiloxy)-2-cyclopenten-1α-yl]-3-(trimethylsilyl)-2-propynyl]oxy]-5-chlorophenyl]-β-alanine methyl ester ,  (3S)-N-(tert-Butoxycarbonyl)-3-[3-(methoxymethoxy)-4-[[(R)-1-[(1R)-1-hydroxy-2-[(3S,4S)-3,5-dihydroxy-3-(4,4′-dimethoxytrityloxymethyl)-4-(4-methoxybenzyloxy)-1-pentynyl]-4β-(tert-butyldimethylsiloxy)-2-cyclopentene-1α-yl]-2-propynyl]oxy]-5-chlorophenyl]-β-alanine ,  (4S)-2,2-Dimethyl-4β-ethynyl-4-[(S)-1-(4-methoxybenzyloxy)-2-acetoxyethyl]-1,3-dioxolane ,  (3S)-N-(tert-Butoxycarbonyl)-3-[3-(methoxymethoxy)-4-[[(R)-1-[(1R)-1-hydroxy-2-[[(4S)-2,2-dimethyl-4-[(S)-1-(4-methoxybenzyloxy)-2-hydroxyethyl]-1,3-dioxolane-4β-yl]ethynyl]-4β-(tert-butyldimethylsiloxy)-2-cyclopentene-1α-yl]-2-propynyl]oxy]-5-chlorophenyl]-β-alanine ,  (βS)-β-(tert-Butoxycarbonylamino)-3-[3-(methoxymethoxy)-4-[[(R)-1-[(1R)-1-hydroxy-2-[[(4S)-2,2-dimethyl-4-[(S)-1-(4-methoxybenzyloxy)-2-hydroxyethyl]-1,3-dioxolane-4β-yl]ethynyl]-4β-(tert-butyldimethylsiloxy)-2-cyclopentene-1α-yl]-2-propynyl]oxy]-5-chlorophenyl]benzenepropanethioic acid S-(2-pyridinyl) ester ,  (2S,6S)-2α-(tert-Butyldimethylsiloxy)-2′,2′-dimethyl-7β-(4-methoxybenzyloxy)-12α-(tert-butoxycarbonylamino)-15-chloro-18α-ethynyl-18aα-hydroxy-19-(methoxymethoxy)-13,16-etheno-4,5-didehydro-1,2,7,8,11,12,18,18a-octahydro-10H-9,17-dioxaspiro[cyclopentacycloheptadecene-6(9H),4′-[1,3]dioxolane]-10-one ,  (2S,6S)-2α,18aα-Dihydroxy-2′,2′-dimethyl-7β-(4-methoxybenzyloxy)-12α-(tert-butoxycarbonylamino)-15-chloro-18α-ethynyl-19-(methoxymethoxy)-13,16-etheno-4,5-didehydro-1,2,7,8,11,12,18,18a-octahydro-10H-9,17-dioxaspiro[cyclopentacycloheptadecene-6(9H),4′-[1,3]dioxolane]-10-one ,  (2S,6S)-2α,19-Bis(methoxymethoxy)-2′,2′-dimethyl-7β-(4-methoxybenzyloxy)-12α-(tert-butoxycarbonylamino)-15-chloro-18α-ethynyl-18aα-hydroxy-13,16-etheno-4,5-didehydro-1,2,7,8,11,12,18,18a-octahydro-10H-9,17-dioxaspiro[cyclopentacycloheptadecene-6(9H),4′-[1,3]dioxolane]-10-one ,  (2S)-2α,19-Bis(methoxymethoxy)-6β,18aα-dihydroxy-6-(hydroxymethyl)-7β-(4-methoxybenzyloxy)-12α-(tert-butoxycarbonylamino)-15-chloro-18α-ethynyl-13,16-etheno-4,5-didehydro-1,2,7,8,11,12,18,18a-octahydro-6H,10H-9,17-dioxacyclopentacycloheptadecene-10-one

Terms in the title (7)： C-1027 ,  発色団 ,  研究 ,  高度 ,  不飽和 ,  大環状化合物 ,  構築