Art

J-GLOBAL ID：200902113473223520   Reference number：99A0616901

Chelation-Controlled 1,3-Asymmetric Induction in Radical Addition to γ-Hydroxy- and γ-Alkoxy-α-methylenecarboxylic Esters.

γ-ヒドロキシ-及びγ-アルコキシ-α-メチレンカルボン酸エステルに対するラジカル付加におけるキレート化制御された1,3-不斉誘導

Author (3)： NAGANO H (Ochanomizu Univ., Tokyo, JPN) ,  TOI S (Ochanomizu Univ., Tokyo, JPN) ,  YAJIMA T (Ochanomizu Univ., Tokyo, JPN)
Material： Synlett
Issue： 1  Page： 53-54  Publication year： Jan. 1999 
JST Material Number： W0113A  ISSN： 0936-5214  CODEN： SYNLES  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *chelation ,...

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JST classification (2)： Aromatic monocyclic carboxylic esters,carboxylic anhydrides,acid halides  (CF05190E) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (29)： (S)-2-Methylene-4-hydroxy-4-phenylbutyric acid ethyl ester ,  (S)-2-Methylene-4-methoxy-4-phenylbutyric acid ethyl ester ,  (S)-4-Phenyl-4-(methoxymethoxy)-2-methylenebutyric acid ethyl ester ,  (S)-5,5-Dimethyl-4-(methoxymethoxy)-2-methylenehexanoic acid ethyl ester ,  (S)-4-Phenyl-4-[(2-methoxyethoxy)methoxy]-2-methylenebutyric acid ethyl ester ,  (S)-6-Methyl-4-[(2-methoxyethoxy)methoxy]-2-methyleneheptanoic acid ethyl ester ,  (S)-5,5-Dimethyl-4-[(2-methoxyethoxy)methoxy]-2-methylenehexanoic acid ethyl ester ,  Isopropyl iodide ,  Iodocyclohexane ,  tert-Butyl iodide ,  Tributyltin ,  (2R,4S)-4-Phenyl-4-hydroxy-2-isobutylbutyric acid ethyl ester ,  (2S,4S)-4-Phenyl-4-hydroxy-2-isobutylbutyric acid ethyl ester ,  (2R,4S)-4-Phenyl-4-methoxy-2-isobutylbutyric acid ethyl ester ,  (2S,4S)-4-Phenyl-4-methoxy-2-isobutylbutyric acid ethyl ester ,  (2R,4S)-4-Phenyl-4-methoxy-2-(cyclohexylmethyl)butyric acid ethyl ester ,  (2S,4S)-4-Phenyl-4-methoxy-2-(cyclohexylmethyl)butyric acid ethyl ester ,  (2R,4S)-4-Phenyl-4-methoxy-2-(2,2-dimethylpropyl)butyric acid ethyl ester ,  (2S,4S)-4-Phenyl-4-methoxy-2-(2,2-dimethylpropyl)butyric acid ethyl ester ,  (2R,4S)-4-Phenyl-4-(methoxymethoxy)-2-isobutylbutyric acid ethyl ester ,  (2S,4S)-4-Phenyl-4-(methoxymethoxy)-2-isobutylbutyric acid ethyl ester ,  (2R,4S)-5,5-Dimethyl-4-(methoxymethoxy)-2-isobutylhexanoic acid ethyl ester ,  (2S,4S)-5,5-Dimethyl-4-(methoxymethoxy)-2-isobutylhexanoic acid ethyl ester ,  (2R,4S)-4-Phenyl-4-[(2-methoxyethoxy)methoxy]-2-isobutylbutyric acid ethyl ester ,  (2S,4S)-4-Phenyl-4-[(2-methoxyethoxy)methoxy]-2-isobutylbutyric acid ethyl ester ,  (2R,4S)-6-Methyl-4-[(2-methoxyethoxy)methoxy]-2-isobutylheptanoic acid ethyl ester ,  (2S,4S)-6-Methyl-4-[(2-methoxyethoxy)methoxy]-2-isobutylheptanoic acid ethyl ester ,  (2R,4S)-5,5-Dimethyl-4-[(2-methoxyethoxy)methoxy]-2-isobutylhexanoic acid ethyl ester ,  (2S,4S)-5,5-Dimethyl-4-[(2-methoxyethoxy)methoxy]-2-isobutylhexanoic acid ethyl ester

Terms in the title (5)： メチレン ,  カルボン酸エステル ,  ラジカル付加 ,  キレート化 ,  不斉誘導