Art

J-GLOBAL ID：200902114775398237   Reference number：01A0306441

Reverse Aromatic Cope Rearrangement of 2-Allyl-3-alkylideneindolines Driven by Olefination of 2-Allylindolin-3-ones: Synthesis of α-Allyl-3-indole Acetate Derivatives.

2-アリルインドリン-3-オンのオレフィン化に誘発された2-アリル-3-アルキリデンインドリンの逆芳香族化Cope転位 α-アリル-3-インドール酢酸エステル誘導体の合成

Author (8)： KAWASAKI T (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  NONAKA Y (Kissei Pharmaceutical Co., Ltd., Nagano, JPN) ,  WATANABE K (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  OGAWA A (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  HIGUCHI K (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  TERASHIMA R (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  MASUDA K (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  SAKAMOTO M (Meiji Pharmaceutical Univ., Tokyo, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 66  Issue： 4  Page： 1200-1204  Publication year： Feb. 23, 2001 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： alkenylation ,...
Semi thesaurus term： Wittig reaction

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JST classification (2)： Condensed derivatives of pyrroles  (CF07077C) ,  Rearrangement reaction,isomerization  (CF02070E)

Substance index (29)： 1-Acetyl-2-allyl-1H-indole-3(2H)-one ,  2-(1,1-Dimethylallyl)-1-acetyl-1H-indol-3(2H)-one ,  1-Acetyl-2-(3-methyl-2-butenyl)indoline-3-one ,  2-(1-Acetyl-2-allylindoline-3-ylidene)acetonitrile ,  2-[1-Acetyl-2-(1,1-dimethyl-2-propenyl)indoline-3-ylidene]acetonitrile ,  2-[1-Acetyl-2-(3-methyl-2-butenyl)indoline-3-ylidene]acetonitrile ,  2-(1-Acetyl-1H-indole-3-yl)-4-pentenenitrile ,  2-(1-Acetyl-1H-indole-3-yl)-5-methyl-4-hexenenitrile ,  2-(1-Acetyl-1H-indole-3-yl)-3,3-dimethyl-4-pentenenitrile ,  1-Acetyl-2-allyl-1H-indole-3-acetonitrile ,  Triphenylphosphinideneacetonitrile ,  Triphenylphosphoranylideneacetic acid methyl ,  Triphenylphosphoranylideneacetic acid tert-butyl ester ,  Methyl 2-(triphenylphosphoranediyl)propionate ,  Triphenyl 2-oxopropylidenephosphorane ,  SKF-45359 ,  2-(1-Acetyl-1H-indole-3-yl)-4-pentenoic acid methyl ester ,  2-(1-Acetyl-1H-indole-3-yl)-4-pentenoic acid tert-butyl ester ,  2-Methyl-2-(1-acetyl-1H-indole-3-yl)-4-pentenoic acid methyl ester ,  1-(1-Acetyl-2-allyl-1H-indole-3-yl)-2-propanone ,  2-(1-Acetyl-1H-indole-3-yl)-5-methyl-4-hexenoic acid methyl ester ,  3-(1-Acetyl-1H-indole-3-yl)-6-methyl-5-heptene-2-one ,  1-Phenyl-2-(1-acetyl-1H-indole-3-yl)-5-methyl-4-hexene-1-one ,  2-[1-Acetyl-2-(3-methyl-2-butenyl)indoline-3-ylidene]acetic acid methyl ester ,  2-(1-Acetyl-1H-indole-3-yl)-3,3-dimethyl-4-pentenoic acid methyl ester ,  1-Acetyl-2-(3-methyl-2-butenyl)-1H-indole-3-acetic acid methyl ester ,  (2R)-1-Acetyl-2-[(1R)-1-methyl-2-propenyl]indoline-3-one ,  (4Z)-2-(1-Acetyl-1H-indole-3-yl)-4-hexenoic acid methyl ester ,  (4E)-2-(1-Acetyl-1H-indole-3-yl)-4-hexenoic acid methyl ester

Terms in the title (8)： アリル ,  インドリン-3-オン ,  オレフィン化 ,  誘発 ,  芳香族化 ,  Cope転位 ,  インドール酢酸 ,  エステル誘導体