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J-GLOBAL ID：200902118126212200   Reference number：01A1013549

Enantioselective [2,3]-sigmatropic and [1,2]-Stevens rearrangements via intramolecular formation of allylic oxonium ylides catalyzed by chiral dirhodium(II) carboxylates.

キラルなジロジウム(II)カルボキシラート類を触媒としたアリル性オキソニウムイリドの分子内生成を経由するエナンチオ選択的な[2,3]-シグマトロピー及び[1,2]-Stevens転位

Author (6)： KITAGAKI S (Hokkaido Univ., Sapporo, JPN) ,  YANAMOTO Y (Hokkaido Univ., Sapporo, JPN) ,  TSUTSUI H (Hokkaido Univ., Sapporo, JPN) ,  ANADA M (Hokkaido Univ., Sapporo, JPN) ,  NAKAJIMA M (Hokkaido Univ., Sapporo, JPN) ,  HASHIMOTO S (Hokkaido Univ., Sapporo, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 42  Issue： 36  Page： 6361-6364  Publication year： Sep. 03, 2001 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *oxygen heterocyclic compound ,...

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JST classification (1)： Condensed derivatives of furan  (CF07073M)

Substance index (20)： N,N-Phthaloyl-L-phenylalanine ,  (S)-N,N-Phthaloylvaline ,  N,N-Phthaloyl-L-phenylglycine ,  N,N-Phthaloyl-L-alanine ,  N,N-Phthaloyl-3-methylvaline ,  (αS)-α-Isopropyl-1,3-dioxo-2,3-dihydro-1H-benzo[f]isoindole-2-acetic acid ,  N,N-(2,3-Naphthalenediylbiscarbonyl)-3-methylvaline ,  2-Diazo-3-oxo-3-[2-(allyloxy)-3-methylphenyl]propionic acid methyl ester ,  3-(2-Allyloxyphenyl)-2-diazo-3-oxopropanoic acid methyl ester ,  (2R)-2-Allyl-7-methyl-3-oxo-2,3-dihydrobenzofuran-2β-carboxylic acid methyl ester ,  (2R)-2-Allyl-3-oxo-2,3-dihydrobenzofuran-2β-carboxylic acid methyl ester ,  2-Diazo-3-oxo-3-[2-[[(E)-2-butenyl]oxy]-3-methylphenyl]propionic acid methyl ester ,  2-Diazo-3-oxo-3-[2-[[(Z)-2-butenyl]oxy]-3-methylphenyl]propionic acid methyl ester ,  2-Diazo-3-[2-(3-methyl-2-butenyloxy)-3-methylphenyl]-3-oxopropanoic acid methyl ester ,  (2R)-2-[(R)-1-Methyl-2-propenyl]-7-methyl-3-oxo-2,3-dihydrobenzofuran-2β-carboxylic acid methyl ester ,  (2R)-2-[(S)-1-Methyl-2-propenyl]-7-methyl-3-oxo-2,3-dihydrobenzofuran-2β-carboxylic acid methyl ester ,  (2R)-2-(1,1-Dimethyl-2-propenyl)-7-methyl-3-oxo-2,3-dihydrobenzofuran-2β-carboxylic acid methyl ester ,  (2R)-2-[(E)-2-Butenyl]-7-methyl-3-oxo-2,3-dihydrobenzofuran-2β-carboxylic acid methyl ester ,  (2R)-2-[(Z)-2-Butenyl]-7-methyl-3-oxo-2,3-dihydrobenzofuran-2β-carboxylic acid methyl ester ,  (2R)-2-(3-Methyl-2-butenyl)-7-methyl-3-oxo-2,3-dihydrobenzofuran-2β-carboxylic acid methyl ester

Terms in the title (6)： キラル ,  カルボキシラート ,  触媒 ,  アリル ,  シグマトロピー ,  Stevens転位