Art

J-GLOBAL ID：200902120050645611   Reference number：02A0534849

Novel Diels-Alder-type dimerization of 5-ethenyl-2-phenylsulfanyl-1H-imidazoles and its application to biomimetic synthesis of 12,12′-dimethylageliferin.

5-エテニル-2-フェニルスルファニル-1H-イミダゾール類の新規Diels-Alder型二量化及びその12,12′-ジメチルアゲリフェリンの生物模倣合成への応用

Author (7)： KAWASAKI I (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  SAKAGUCHI N (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  FUKUSHIMA N (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  FUJIOKA N (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  NIKAIDO F (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  YAMASHITA M (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  OHTA S (Kyoto Pharmaceutical Univ., Kyoto, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 43  Issue： 24  Page： 4377-4380  Publication year： Jun. 10, 2002 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,...

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JST classification (1)： Imidazoles  (CF07083X)

Substance index (27)： 1-Methyl-2-phenylthio-1H-imidazole ,  1-(Methoxymethyl)-2-(phenylthio)-1H-imidazole ,  1-[2-(Trimethylsilyl)ethoxymethyl]-2-(phenylthio)-1H-imidazole ,  1-Methyl-2-(phenylthio)-1H-imidazole-5-carbaldehyde ,  1-(Methoxymethyl)-2-(phenylthio)-1H-imidazole-5-carbaldehyde ,  1-[2-(Trimethylsilyl)ethoxymethyl]-2-(phenylthio)-1H-imidazole-5-carbaldehyde ,  1-Methyl-2-(phenylthio)-5-vinyl-1H-imidazole ,  1-[2-(Trimethylsilyl)ethoxymethyl]-2-(phenylthio)-5-vinyl-1H-imidazole ,  1-Methyl-2-(phenylthio)-5-[(E)-1-propenyl]-1H-imidazole ,  (αE)-1-Methyl-2-(phenylthio)-1H-imidazole-5-acrylic acid ethyl ester ,  (αE)-1-(Methoxymethyl)-2-(phenylthio)-1H-imidazole-5-acrylic acid ethyl ester ,  (αE)-2-(Phenylthio)-1H-imidazole-5-acrylic acid ethyl ester ,  4,5,6,7-Tetrahydro-4β-(1-methyl-2-phenylthio-1H-imidazole-5-yl)-1-methyl-2-phenylthio-1H-benzimidazole ,  (4R)-1-[2-(Trimethylsilyl)ethoxymethyl]-2-(phenylthio)-4β-[1-[2-(trimethylsilyl)ethoxymethyl]-2-(phenylthio)-5-imidazolyl]-4,5,6,7-tetrahydro-1H-benzimidazole ,  (4R)-1,5α,6β-Trimethyl-2-(phenylthio)-4β-[1-methyl-2-(phenylthio)-5-imidazolyl]-4,5,6,7-tetrahydro-1H-benzimidazole ,  (4R)-1-Methyl-2-(phenylthio)-4β-[1-methyl-2-(phenylthio)-5-imidazolyl]-4,5,6,7-tetrahydro-1H-benzimidazole-5α,6β-dicarboxylic acid dimethyl ester ,  (4R)-1-(Methoxymethyl)-2-(phenylthio)-4β-[1-(methoxymethyl)-2-(phenylthio)-5-imidazolyl]-4,5,6,7-tetrahydro-1H-benzimidazole-5α,6β-dicarboxylic acid dimethyl ester ,  (4R)-1-Methyl-2-(phenylthio)-4β-[1-methyl-2-(phenylthio)-5-imidazolyl]-4,5,6,7-tetrahydro-1H-benzimidazole-5α,6β-dimethanol ,  (4R)-1-Methyl-2-(phenylthio)-4β-[1-methyl-2-(phenylthio)-5-imidazolyl]-5α,6β-bis(tert-butyldiphenylsiloxymethyl)-4,5,6,7-tetrahydro-1H-benzimidazole ,  (4R)-1-Methyl-4β-(1-methyl-5-imidazolyl)-5α,6β-bis(tert-butyldiphenylsiloxymethyl)-4,5,6,7-tetrahydro-1H-benzimidazole ,  (4R)-1-Methyl-2-azido-4β-(1-methyl-2-azido-5-imidazolyl)-5α,6β-bis(tert-butyldiphenylsiloxymethyl)-4,5,6,7-tetrahydro-1H-benzimidazole ,  (4R)-1-Methyl-2-(benzylideneamino)-4β-[1-methyl-2-(benzylideneamino)-5-imidazolyl]-5α,6β-bis(tert-butyldiphenylsiloxymethyl)-4,5,6,7-tetrahydro-1H-benzimidazole ,  (4R)-1-Methyl-2-(benzylideneamino)-4β-[1-methyl-2-(benzylideneamino)-5-imidazolyl]-4,5,6,7-tetrahydro-1H-benzimidazole-5α,6β-dimethanol ,  (4R)-1-Methyl-2-(benzylideneamino)-4β-[1-methyl-2-(benzylideneamino)-5-imidazolyl]-5α,6β-bis(azidomethyl)-4,5,6,7-tetrahydro-1H-benzimidazole ,  (4R)-1-Methyl-2-(benzylideneamino)-4β-[1-methyl-2-(benzylideneamino)-5-imidazolyl]-5α,6β-bis(4-bromo-2-pyrrolylcarbonylaminomethyl)-4,5,6,7-tetrahydro-1H-benzimidazole ,  12,12′-Dimethylageliferin ,  2-(Trichloroacetyl)-4-bromo-1H-pyrrole

Terms in the title (3)： 1H-イミダゾール ,  生物模倣 ,  応用