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J-GLOBAL ID：200902120303529222   Reference number：00A0114093

New Okaramine Congeners, Okamines J, K, L, M and Related Compounds, from Penicillium simplicissimum ATCC 90288.

Penicillium simplicissimum ATCC90288の生産する新規オカラミン類縁体オカラミンJ,K,L,M,およびその関連物質について

Author (3)： SHIONO Y (Osaka Prefecture Univ., Osaka, JPN) ,  AKIYAMA K (Osaka Prefecture Univ., Osaka, JPN) ,  HAYASHI H (Osaka Prefecture Univ., Osaka, JPN)
Material： Bioscience, Biotechnology, and Biochemistry  (Bioscience Biotechnology & Biochemistry)
Volume： 63  Issue： 11  Page： 1910-1920  Publication year： Nov. 23, 1999 
JST Material Number： G0021A  ISSN： 0916-8451  CODEN： BBBIEJ  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *Penicillium ,...
Semi thesaurus term： Penicillium simplicissimum ,...

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JST classification (2)： Microorganism biochemistry  (EG03020N) ,  Alkaloids  (CF10030D)

Substance index (21)： Okaramine A ,  Okaramine B ,  Okaramine G ,  Okaramine C ,  Okaramine H ,  Okaramine I ,  Okaramine J ,  (5aR)-3-[[2-(1,1-Dimethyl-2-propenyl)-1H-indole-3-yl]methylene]-7-(3-methyl-2-butenyl)-2,3,4,5aα,6,10b,11,11aα-octahydro-10bα-hydroxy-1H-pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-1,4-dione ,  (3S)-3β-[[2-(1,1-Dimethyl-2-propenyl)-1H-indole-3-yl]methyl]-6-(3-methyl-2-butenyl)-2,3,4,5aα,6,10b,11,11aα-octahydro-10bα-hydroxy-1H-pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-1,4-dione ,  (3S)-3β-[[2-(1,1-Dimethyl-2-propenyl)-1H-indole-3-yl]methyl]-6-acetyl-2,3,4,5aα,6,10b,11,11aα-octahydro-10bα-(1,1-dimethyl-2-propenyl)-1H-pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-1,4-dione ,  2-(1,1-Dimethyl-2-propenyl)cyclo[L-Trp-2-(1,1-dimethyl-2-propenyl)-L-Trp-] ,  (3S)-3α-[1-(1,1-Dimethyl-2-propenyl)-1H-indole-3-ylmethyl]-6α-[2-(1,1-dimethyl-2-propenyl)-1H-indole-3-ylmethyl]piperazine-2,5-dione ,  Cyclo(L-Trp-L-Trp-) ,  (3S)-3α-(1H-Indole-3-ylmethyl)-6α-[2-(1,1-dimethyl-2-propenyl)-1H-indole-3-ylmethyl]piperazine-2,5-dione ,  3α-[(1H-Indole-3-yl)methyl]-6α-[[1-(1,1-dimethylallyl)-1H-indole-3-yl]methyl]piperazine-2,5-dione ,  (10aS)-6,6-Dimethyl-11aβ-hydroxy-16-(1,1-dimethyl-2-propenyl)-6,10aβ,11,11a,16,16aβ-hexahydro-5H-indolo[3′′′,2′′′:4′′,5′′]pyrrolo[1′′,2′′:4′,5′]pyrazino[1′,2′:1,2]azocino[5,4-b]indole-10,18-dione ,  (10aR,18aR)-6,6,17,17,18α-Pentamethyl-10aβ,11aβ-dihydroxy-11α-methoxy-6,10a,11,11a,17,18-hexahydro-5H-azete[1,2-a]indolo[3′′′,2′′′:4′′,5′′]azocino[1′′,2′′:4′,5′]pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-10,20-dione ,  (5aR)-3-[[2-(1,1-Dimethyl-2-propenyl)-1H-indole-3-yl]methylene]-6-(1,1-dimethyl-2-propenyl)-2,3,4,5aα,6,10b,11,11aα-octahydro-10bα-hydroxy-1H-pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-1,4-dione ,  (3S)-3β-[2-(1,1-Dimethyl-2-propenyl)-1H-indole-3-ylmethyl]-6-(1,1-dimethyl-2-propenyl)-2,3,4,5aα,6,10b,11,11aα-octahydro-10bα-hydroxy-1H-pyrazino[1′,2′:1,5]pyrrolo[2,3-b]indole-1,4-dione ,  (10aS)-6,6-Dimethyl-11aβ-hydroxy-15-(3-methyl-2-butenyl)-6,10aβ,11,11a,16,16aβ-hexahydro-5H-indolo[3′′′,2′′′:4′′,5′′]pyrrolo[1′′,2′′:4′,5′]pyrazino[1′,2′:1,2]azocino[5,4-b]indole-10,18-dione ,  (10aS)-6,6-Dimethyl-11aβ-hydroxy-6,10aβ,11,11a,16,16aβ-hexahydro-5H-indolo[3′′′,2′′′:4′′,5′′]pyrrolo[1′′,2′′:4′,5′]pyrazino[1′,2′:1,2]azocino[5,4-b]indole-10,18-dione

Reference (13)：

• 1) Hayashi, H., Takiuchi, K., Murao, S., and Arai, M., Structure and insecticidal activity of new indole alkaloids, okaramines A and B, from Penicillium simplicissimum AK-40. Agric. Biol. Chem., 53, 461-469 (1989).
• 2) Hayashi, H., Asabu, Y., Murao, S., and Arai, M., New okaramine congeners, okaramines D, E, and F, from Penicillium simplicissimum ATCC 90288. Biosci. Biotechnol. Biochem., 59, 246-250 (1995).
• 3) Hayashi, H. and Sakaguchi, A., Okaramine G, a new okaramine congener from Penicillium simplicissimum ATCC 90288. Biosci. Biotechnol. Biochem., 62, 804-806 (1998).
• 4) Hayashi, H., Asabu, Y., Nakayama, M., Murao, S., and Arai, M., Penitrem A, as a convulsive factor against silkworm, from Penicillium simplicissimum AK-40. Chem. Express, 8, 177-180 (1993).
• 5) Hayashi, H., Asabu, Y., Nakayama, M., Murao, S., and Arai, M., A new congener of penitrems, 6-bromopenitrem E, from Penicillium simplicissimum AK-40. Chem. Express, 8, 233-236 (1993).

Terms in the title (4)： Penicillium ,  オカラ ,  類縁体 ,  物質