Art

J-GLOBAL ID：200902124237557681   Reference number：00A0503447

A novel double insertion of the difluoromethylene unit from trifluoromethylcopper into the carbon-copper bond of perfluoroaryl- and perfluorovinylcopper reagents: preparation, mechanism and applications of new fluorinated copper reagents.

ペルフルオロアリール-及びペルフルオロビニル銅試薬の炭素-銅結合へのトリフルオロメチル銅からのジフルオロメチレンユニットの新しい二重挿入 新しいふっ素化銅試薬の調製,機構及び適用

Author (2)： YANG Z-Y (Univ. Iowa, IA, USA) ,  BURTON D J (Univ. Iowa, IA, USA)
Material： Journal of Fluorine Chemistry  (J Fluor Chem)
Volume： 102  Issue： 1/2  Page： 89-103  Publication year： Mar. 2000 
JST Material Number： B0438C  ISSN： 0022-1139  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Thesaurus term： *insertion reaction ,...

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JST classification (1)： Group 11 and group 12 organic compounds  (CF09052N)

Substance index (47)： Iodobenzene ,  Phenyllithium ,  Hexylamine ,  Ethanol ,  t-Butyl alcohol ,  Diethylamine ,  Trifluoromethylcopper(I) ,  (Pentafluorophenyl) copper(I) ,  (Nonafluorophenethyl) copper(I) ,  (Nonafluorophenethyl) bromide ,  (Nonafluorophenethyl) iodide ,  (Nonafluorophenethyl) chloride ,  [(Z)-Pentafluoro-1-propenyl] copper(I) ,  [(E)-Nonafluoro-3-pentenyl] copper(I) ,  Allyl bromide ,  (E)-4,4,5,5,6,7,8,8,8-Nonafluoro-1,6-octadiene ,  Allyl(nonafluorophenethyl) sulfone ,  (1-Propenyl)(nonafluorophenethyl) sulfone ,  β-Bromostyrene ,  1-Phenyl-3,3,4,4-tetrafluoro-4-(pentafluorophenyl)-1-butene ,  1-Iodo-3-methylbenzene ,  1-Iodo-4-methylbenzene ,  1-Iodo-2-nitrobenzene ,  (Nonafluorophenethyl)benzene ,  1-(Nonafluorophenethyl)-3-methylbenzene ,  1-(Nonafluorophenethyl)-4-methylbenzene ,  1-(Nonafluorophenethyl)-2-nitrobenzene ,  Methyllithium ,  Sodium methoxide ,  Sodium ethoxide ,  Sodium isopropoxide ,  Sodium phenolate ,  1-(Nonafluorophenethyl)-3-bromo-4-methylbenzene ,  1-(α,α-Difluoro-β,β-dichloro-4-methylphenethyl)-2,3,4,5,6-pentafluorobenzene ,  1-(α,α-Difluoro-β,β-dichloro-2-methylphenethyl)-2,3,4,5,6-pentafluorobenzene ,  1-(α,α-Difluoro-β,β-dichloro-3-methylphenethyl)-2,3,4,5,6-pentafluorobenzene ,  2,3,5,6-Tetrafluoro-4-(α,α,β,β-tetrafluorophenethyl)biphenyl ,  1-(α,α,β,β-Tetrafluorophenethyl)-2,3,5,6-tetrafluoro-4-methylbenzene ,  1-(3-Methyl-α,α,β,β-tetrafluorophenethyl)-2,3,5,6-tetrafluoro-4-methylbenzene ,  4-(α,α,β,β-Tetrafluorophenethyl)-2,3,5,6-tetrafluorophenol ,  1-(3-Methyl-α,α,β,β-tetrafluorophenethyl)-2,3,5,6-tetrafluoro-4-methoxybenzene ,  1-(α,α,β,β-Tetrafluorophenethyl)-2,3,5,6-tetrafluoro-4-ethoxybenzene ,  1-(3-Methyl-α,α,β,β-tetrafluorophenethyl)-2,3,5,6-tetrafluoro-4-ethoxybenzene ,  1-(4-Methyl-α,α,β,β-tetrafluorophenethyl)-2,3,5,6-tetrafluoro-4-isopropoxybenzene ,  1-(α,α,β,β-Tetrafluorophenethyl)-2,3,5,6-tetrafluoro-4-phenoxybenzene ,  N-Hexyl-4-(2-nitro-α,α,β,β-tetrafluorophenethyl)-2,3,5,6-tetrafluoro-aniline ,  N,N-Diethyl-4-(α,α,β,β-tetrafluorophenethyl)-2,3,5,6-tetrafluoroaniline

Terms in the title (5)： 銅 ,  試薬 ,  炭素 ,  ふっ素化 ,  調製