Art

J-GLOBAL ID：200902124765220567   Reference number：95A0133411

Oxidative Generation of α-Radicals of Carbonyl Compounds from the α-Stannyl Derivatives and Their Reactions with Electron-Rich Olefins.

酸化によるα-スタンニル誘導体からカルボニル化合物のα-ラジカルの生成と,それらと富電子オレフィンとの反応

Author (2)： KOHNO Y (Univ. Tokyo, Tokyo) ,  NARASAKA K (Univ. Tokyo, Tokyo)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 68  Issue： 1  Page： 322-329  Publication year： Jan. 1995 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： stannanes ,...
Semi thesaurus term： furans ,...

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JST classification (2)： Organic Sn,Pb,Po compounds  (CF09040U) ,  Aliphatic ketones  (CF03190Q)

Substance index (24)： (Tributylstannyl)acetic acid ethyl ester ,  (Trimethylgermyl)acetic acid ethyl ester ,  Ethyl (trimethylsilyl)acetate ,  α-(tert-Butyldimethylsilyloxy)styrene ,  Ethyl 4-phenyl-4-oxobutyrate ,  (Tributylstannyl)acetic acid benzyl ester ,  4-Phenyl-4-oxobutanoic acid benzyl ester ,  4-Oxo-5-methylhexanoic acid benzyl ester ,  2-Oxocyclopentaneacetic acid benzyl ester ,  5-Phenyl-5-methyloxolane-2-one ,  2-Methyl-4-oxo-4-phenylbutyric acid methyl ester ,  2-Methyl-4-oxo-4-(2-furanyl)butanoic acid methyl ester ,  2-Ethyl-4-phenyl-4-oxobutanoic acid methyl ester ,  2-Ethyl-4-oxo-4-(2-furanyl)butanoic acid methyl ester ,  2,2-Dimethyl-4-oxo-4-(2-furanyl)butanoic acid methyl ester ,  N,N-Dimethyl-4-oxo-4-phenylbutanamide ,  N,N,3-Trimethyl-4-oxo-4-phenylbutanamide ,  N,N-Dimethyl-4-pentenamide ,  1-Phenyl-1,4-pentanedione ,  1-(2-Furanyl)-1,4-pentanedione ,  1-Phenyl-2-methylpentane-1,4-dione ,  1-Phenyl-4-(2-furyl)butane-1,4-dione ,  2-Phenacylcyclopentanone ,  1-Cyclohexenyloxytributylstannane

Reference (45)：

• 1) Y. Kobayashi, T. Taguchi, and E. Tokuno, Tetrahedron Lett., 1977, 3741;
•  R. M. Moriarty, R. Penmasta, and I. Prakash, Tetrahedron Lett., 28, 873 (1987).
• 2) Y. Ito, T. Konoike, and T. Saegusa, J. Am. Chem. Soc., 97, 649 (1975);
•  E. Baciocchi, A. Casu, and R. Ruzziconi, Tetrahedron Lett., 30, 3707 (1989).
• 3) S. Inaba and I. Ojima, Tetrahedron Lett., 1977, 2009;

Terms in the title (6)： 酸化 ,  誘導体 ,  カルボニル化合物 ,  ラジカル ,  電子 ,  オレフィン