Art

J-GLOBAL ID：200902127456408135   Reference number：02A0279181

Synthetic studies of zoanthamine alkaloids. Stereoselective synthesis of the ABC ring system of norzoanthamine by an intramolecular Diels-Alder reaction.

ゾアンタミンアルカロイドの合成研究 分子内Diels-Alder反応によるノルゾアンタミンのABC環系の立体選択的合成

Author (4)： SAKAI M (Hokkaido Univ., Sapporo, JPN) ,  SASAKI M (Hokkaido Univ., Sapporo, JPN) ,  TANINO K (Hokkaido Univ., Sapporo, JPN) ,  MIYASHITA M (Hokkaido Univ., Sapporo, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 43  Issue： 9  Page： 1705-1708  Publication year： Feb. 25, 2002 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *alicyclic compound ,...
Semi thesaurus term： Aldol condensation

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JST classification (1)： Phenanthrenes  (CF06070G)

Substance index (15)： Norzoanthamine ,  2-Cyclohexen-1-one ,  [Bis[(E)-1-methyl-3-(triisopropylsiloxy)-1-propenyl]cuprio(III)] lithium ,  1-(Trimethylsiloxy)-3-[(E)-1-methyl-3-(triisopropylsiloxy)-1-propenyl]-1-cyclohexene ,  (2R)-2β-[[4-Methyl-5-(tert-butyldimethylsilyl)-2-furanyl]hydroxymethyl]-3α-[(E)-1-methyl-3-(triisopropylsiloxy)-1-propenyl]cyclohexanone ,  (2E,3S)-2-[4-Methyl-5-(tert-butyldimethylsilyl)-2-furanylmethylene]-3α-[(E)-1-methyl-3-(triisopropylsiloxy)-1-propenyl]cyclohexanone ,  (2S)-2β-[4-Methyl-5-(tert-butyldimethylsilyl)-2-furanylmethyl]-3α-[(E)-1-methyl-3-(triisopropylsiloxy)-1-propenyl]cyclohexanone ,  (1R)-1β-Acetoxy-2β-[4-methyl-5-(tert-butyldimethylsilyl)-2-furanylmethyl]-3α-[(E)-1-methyl-3-(triisopropylsiloxy)-1-propenyl]cyclohexane ,  3-[(1R)-2α-[4-Methyl-5-(tert-butyldimethylsilyl)-2-furanylmethyl]-3α-acetoxycyclohexane-1β-yl]isocrotonaldehyde ,  (E)-4-[(1R)-2α-[4-Methyl-5-(tert-butyldimethylsilyl)-2-furanylmethyl]-3α-acetoxycyclohexane-1β-yl]-3-pentene-2-one ,  (Z)-2-Methyl-4-oxo-5-[(1S)-2α-[(E)-1-methyl-3-oxo-1-butenyl]-6β-acetoxycyclohexane-1β-yl]-2-pentenoic acid methyl ester ,  (Z)-2-Methyl-4-oxo-5-[(1S)-2α-[(1E)-1-methyl-3-(tert-butyldimethylsiloxy)-1,3-butadienyl]-6β-acetoxycyclohexane-1β-yl]-2-pentenoic acid methyl ester ,  Acetic acid 2-oxopropyl ,  4-Methyl-5-(tert-butyldimethylsilyl)furan-2-carbaldehyde ,  (1R)-1,4aα-Dimethyl-8β-acetoxy-10-oxo-1,4,4a,4bβ,5,6,7,8,8aα,9,10,10aβ-dodecahydrophenanthrene-1α-carboxylic acid methyl ester

Terms in the title (6)： 研究 ,  分子内Diels-Alder反応 ,  ノルゾアンタミン ,  ABC ,  環 ,  立体選択的合成