Art

J-GLOBAL ID：200902128177664756   Reference number：02A0877377

(Salen)ruthenium-Catalyzed Desymmetrization of Meso-Diols: Catalytic Aerobic Asymmetric Oxidation under Photo-Irradiation.

meso-ジオールの(salen)ルテニウム触媒による非対称化 光照射下における接触的不斉空気酸化

Author (3)： SHIMIZU H (Kyushu Univ.) ,  NAKATA K (Kyushu Univ.) ,  KATSUKI T (Kyushu Univ.)
Material： Chemistry Letters  (Chem Lett)
Issue： 11  Page： 1080-1081  Publication year： Nov. 05, 2002 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *diol ,...

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=02A0877377&from=J-GLOBAL&jstjournalNo=S0742A") }}

JST classification (2)： Catalytic reactions in general  (CB06080F) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (10)： 1α,2α-Cyclohexanedimethanol ,  (3aα,7aα)-Octahydroisobenzofuran-1-one ,  (3aβ,7aβ)-Octahydroisobenzofuran-1-one ,  (1R,5S)-3-Oxabicyclo[3.2.0]-2-one ,  (1R,5S)-3-Oxabicyclo[3.3.0]-2-one ,  1,3,3aα,4,7,7aα-Hexahydro-isobenzofuran-1-one ,  1α,2α-Cyclobutanedimethanol ,  1α,2α-Cyclopentanedimethanol ,  1α,2α-Cycloheptanedimethanol ,  Cyclohexene-4α,5α-dimethanol

Reference (16)：

• 1) a) G. Fantin and P. Pedrini, in “Asymmetric Oxidation Reactions,” ed. by T. Katsuki, Oxford University Press, Oxford (2001), pp 200–214.
•  b) J. B. Jones, in “Asymmetric Synthesis,” ed. by J. D. Morrison, Academic Press, New York (1984), Vol. 5, pp 309–344.
• 2) a) Y. Ishii, K. Suzuki, T. Ikariya, M. Saburi, and S. Yoshikawa, J. Org. Chem., 51, 2822 (1986).
•  b) Y. Ishii, K. Osakada, T. Ikariya, and M. Saburi, Chem. Lett., 1982, 1179.
• 3) Asymmetric Oppenauer oxidation-like desymmetrization of meso-diols (up to 50% ee) has recently been reported: M. Ito, A. Osaku, and T. Ikariya, The 84th Annual Meeting of the Chemical Society of Japan, Tokyo, March 2002, Abstr., No. 3 G4–14.

Terms in the title (5)： ジオール ,  ルテニウム触媒 ,  非対称 ,  光照射 ,  空気酸化