Art

J-GLOBAL ID：200902131424097488   Reference number：99A0796005

Enantioselective Reduction of Ketones by Polymethylhydrosiloxane in the Presence of Chiral Zinc Catalysts.

キラルな亜鉛触媒存在下でのポリメチルヒドロシロキサンによるケトンのエナンチオ選択的還元

Author (5)： MIMOUN H (Firmenich S.A., La Plaine-Geneva, CHE) ,  DE SAINT LAUMER J Y (Firmenich S.A., La Plaine-Geneva, CHE) ,  GIANNINI L (Univ. Lausanne, Lausanne, CHE) ,  SCOPELLITI R (Univ. Lausanne, Lausanne, CHE) ,  FLORIANI C (Univ. Lausanne, Lausanne, CHE)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 121  Issue： 26  Page： 6158-6166  Publication year： Jul. 07, 1999 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...
Semi thesaurus term： polymethylhydrosiloxane

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JST classification (2)： Aromatic monocyclic ketones  (CF05170I) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (56)： N,N′-Bis(1-naphthylmethylene)cyclohexane-1β,2α-diamine ,  N,N′-Bis(2-naphthylmethylene)cyclohexane-1β,2α-diamine ,  N,N′-Bis(1,3-benzodioxole-5-ylmethylene)cyclohexane-1β,2α-diamine ,  N,N′-Bis(2,4,6-trimethylbenzylidene)cyclohexane-1β,2α-diamine ,  N,N′-Bis(2,4,6-trimethoxyphenylmethylene)cyclohexane-1β,2α-diamine ,  N,N′-Bis[(S)-1-(1-naphthyl)ethyl]butane-2,3-diimine ,  N,N′-Bis[(S)-1-phenylethyl]butane-2,3-diimine ,  N,N′-Bis[(S)-1-phenylethyl]ethanediimine ,  (1R,2R)-1,2-Cyclohexanediamine ,  N,N′-Bis(1-naphthylmethyl)cyclohexane-1β,2α-diamine ,  (1R)-1β,2α-Bis(isopropylamino)cyclohexane ,  N,N′-Diisobutylcyclohexane-1β,2α-diamine ,  (1R)-1β,2α-Bis(neopentylamino)cyclohexane ,  N,N′-Dicyclohexylcyclohexane-1β,2α-diamine ,  (-)-Stilbenediamine ,  (αS,βS)-N,N′-Bis(2-methoxyethyl)bibenzyl-α,β-diamine ,  (αS,βS)-N,N′-Dibenzylbibenzyl-α,β-diamine ,  (αS,βS)-N,N′-Bis(1-naphthylmethyl)bibenzyl-α,β-diamine ,  (αS,βS)-N,N′-Bis(3-methoxybenzyl)bibenzyl-α,β-diamine ,  (αS,βS)-N,N′-Bis(4-methoxybenzyl)bibenzyl-α,β-diamine ,  (αS,βS)-N,N′-Bis(2,4,6-trimethylbenzyl)bibenzyl-α,β-diamine ,  N,N′-Ethylenebis[(S)-α-methylbenzylamine] ,  (3R,4R)-N,N′-Dibenzyl-2,2,5,5-tetramethylhexane-3,4-diamine ,  (2S)-2-(Anilinomethyl)pyrrolidine ,  1β,2α-Dipyrrolizinocyclohexane ,  1β,2α-Di(isoindoline-2-yl)cyclohexane ,  (R)-α-(5-Vinylquinuclidine-2-yl)quinoline-4-methanol ,  (Pyrrolidine-2β-yl)diphenylmethanol ,  (2S,3R)-1,2-Diphenyl-3-(dimethylamino)-2-butanol ,  (-)-DAIB ,  (1S,2R)-1-Phenyl-2-(methylisopropylamino)-1-propanol ,  1,2-Bis[(4S)-4β-methyl-5α-phenyl-2-oxazoline-2-yl]benzene ,  2-[[[(S)-1-Phenylethyl]imino]methyl]pyridine ,  ((R)-1-Aminoethyl)phosphonic acid ,  Acetophenone ,  3'-Methoxyacetophenone ,  4'-Methoxyacetophenone ,  Propiophenone ,  2-Acetylnaphthalene ,  4'-Methylacetophenone ,  1-Acetylnaphthalene ,  Tetralin-1-one ,  2-Acetylfuran ,  Methyl cyclohexyl ketone ,  5,7-Megastigmadien-9-one ,  (S)-1-Phenylethanol ,  (S)-1-(3-Methoxyphenyl)ethanol ,  (S)-1-p-Anisylethanol ,  (S)-1-Phenyl-1-propanol ,  (S)-1-(2-Naphthyl)ethanol ,  (S)-1-p-Tolylethanol ,  (S)-1-(1-Naphthyl)ethanol ,  (S)-Tetralin-1-ol ,  (S)-1-(2-Furyl)ethanol ,  (S)-1-Cyclohexylethanol ,  (S)-4-(2,6,6-Trimethyl-1-cyclohexenyl)-3-butene-2-ol

Terms in the title (5)： キラル ,  亜鉛触媒 ,  ポリメチルヒドロシロキサン ,  ケトン ,  選択的還元