Art

J-GLOBAL ID：200902133534402637   Reference number：00A0809757

Diastereoselective Allylation and Crotylation Reactions of Aldehydes with Potassium Allyl- and Crotyltrifluoroborates under Lewis Acid Catalysis.

Lewis酸触媒条件下でアリルまたはクロチルトリフルオロほう酸カリウムによるアルデヒドのジアステレオ選択的なアリル化とクロチル化

Author (4)： BATEY R A (Univ. Toronto, Ontario, CAN) ,  THADANI A N (Univ. Toronto, Ontario, CAN) ,  SMIL D V (Univ. Toronto, Ontario, CAN) ,  LOUGH A J (Univ. Toronto, Ontario, CAN)
Material： Synthesis  (Journal of Synthetic Organic Chemistry)
Issue： Special Issue  Page： 990-998  Publication year： 2000 
JST Material Number： D0738A  ISSN： 0039-7881  CODEN： SYNTBF  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *Lewis acid catalyst ,...

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=00A0809757&from=J-GLOBAL&jstjournalNo=D0738A") }}

JST classification (4)： Organoboron compounds  (CF08020R) ,  Aliphatic aldehydes  (CF03180F) ,  Inorganic acid esters of aliphatic alcohol and thiol  (CF03140N) ,  Other catalysts  (CB06123Z)

Substance index (47)： Octanal ,  Benzaldehyde ,  4-Nitrobenzaldehyde ,  Cinnamaldehyde ,  4-Methoxybenzaldehyde ,  4-(Methylthio)benzaldehyde ,  4-Formylbenzonitrile ,  3,4-Dichlorobenzaldehyde ,  Vanillin ,  α-Allyl-4-nitrobenzenemethanol ,  1-Undecen-4-ol ,  1-Styryl-3-butene-1-ol ,  1-Phenyl-3-buten-1-ol ,  α-Allyl-4-methoxybenzyl alcohol ,  1-[4-(Methylthio)phenyl]-3-butene-1-ol ,  α-Allyl-4-cyanobenzenemethanol ,  3,4-Dichloro-α-allylbenzyl alcohol ,  4-(1-Hydroxy-3-butenyl)-2-methoxyphenol ,  rel-(3R^*,4R^*)-3-Methyl-1-undecene-4-ol ,  rel-(3S^*,4R^*)-3-Methyl-1-undecene-4-ol ,  rel-(1S^*,2R^*)-2-Methyl-1-phenyl-3-butene-1-ol ,  rel-(1S^*,2S^*)-2-Methyl-1-phenyl-3-butene-1-ol ,  rel-(1R^*,2S^*)-1-(4-Methoxyphenyl)-2-methyl-3-butene-1-ol ,  rel-(1S^*,2S^*)-1-(4-Methoxyphenyl)-2-methyl-3-butene-1-ol ,  rel-(1S^*,2R^*)-1-(4-Nitrophenyl)-2-methyl-3-butene-1-ol ,  rel-(1S^*,2S^*)-1-(4-Nitrophenyl)-2-methyl-3-butene-1-ol ,  2-(tert-Butyldimethylsiloxy)propanal ,  tert-Butyldimethylsiloxyphenylacetaldehyde ,  rel-(2S^*,3S^*)-2-(tert-Butyldimethylsilyloxy)-5-hexene-3-ol ,  rel-(2R^*,3S^*)-2-(tert-Butyldimethylsilyloxy)-5-hexene-3-ol ,  rel-(1S^*,2S^*)-1-(tert-Butyldimethylsilyloxy)-1-phenyl-4-pentene-2-ol ,  rel-(1R^*,2S^*)-1-(tert-Butyldimethylsilyloxy)-1-phenyl-4-pentene-2-ol ,  rel-(2R^*,3S^*,4R^*)-2-(tert-Butyldimethylsilyloxy)-4-methyl-5-hexene-3-ol ,  rel-(2R^*,3S^*,4S^*)-2-(tert-Butyldimethylsilyloxy)-4-methyl-5-hexene-3-ol ,  rel-(2S^*,3S^*,4S^*)-2-(tert-Butyldimethylsilyloxy)-4-methyl-5-hexene-3-ol ,  rel-(1R^*,2S^*,3R^*)-1-(tert-Butyldimethylsilyloxy)-3-methyl-1-phenyl-4-pentene-2-ol ,  rel-(1R^*,2S^*,3S^*)-1-(tert-Butyldimethylsilyloxy)-3-methyl-1-phenyl-4-pentene-2-ol ,  3-(tert-Butyldimethylsiloxy)-4-methylpentanal ,  3-Phenyl-3-(tert-butyldimethylsiloxy)propanal ,  rel-(4S^*,6S^*)-6-(tert-Butyldimethylsilyloxy)-7-methyl-1-octene-4-ol ,  rel-(4S^*,6R^*)-6-(tert-Butyldimethylsilyloxy)-7-methyl-1-octene-4-ol ,  rel-(1S^*,3S^*)-1-(tert-Butyldimethylsilyloxy)-1-phenyl-5-hexene-3-ol ,  rel-(1R^*,3S^*)-1-(tert-Butyldimethylsilyloxy)-1-phenyl-5-hexene-3-ol ,  rel-(1S^*,3R^*,4R^*)-1-(tert-Butyldimethylsilyloxy)-4-methyl-1-phenyl-5-hexene-3-ol ,  rel-(1R^*,3R^*,4R^*)-1-(tert-Butyldimethylsilyloxy)-4-methyl-1-phenyl-5-hexene-3-ol ,  rel-(1S^*,3R^*,4S^*)-1-(tert-Butyldimethylsilyloxy)-4-methyl-1-phenyl-5-hexene-3-ol ,  rel-(1R^*,3R^*,4S^*)-1-(tert-Butyldimethylsilyloxy)-4-methyl-1-phenyl-5-hexene-3-ol

Terms in the title (8)： Lewis酸触媒 ,  アリル ,  ほう酸 ,  カリウム ,  アルデヒド ,  ジアステレオ選択 ,  アリル化 ,  チル