Art

J-GLOBAL ID：200902136379034919   Reference number：00A1046154

Stoichiometric and Catalytic Activation of Si-H Bonds by a Triruthenium Carbonyl Cluster, (μ₃,η²:η³:η⁵-acenaphthylene)Ru₃(CO)₇: Isolation of the Oxidative Adducts, Catalytic Hydrosilylation of Aldehydes, Ketones, and Acetals, and Catalytic Polymerization of Cyclic Ethers.

三ルテニウムカルボニルクラスタ(μ₃,η²:η³:η⁵-アセナフチレン)Ru₃(CO)₇によるSi-H結合の化学量論的及び触媒的活性化 酸化的付加物の単離,アルデヒド,ケトン及びアセタールの触媒的ヒドロシリル化ならびに環状エーテルの触媒重合

Author (5)： NAGASHIMA H (Kyushu Univ., Fukuoka, JPN) ,  SUZUKI A (Kyushu Univ., Fukuoka, JPN) ,  IURA T (Kyushu Univ., Fukuoka, JPN) ,  RYU K (Kyushu Univ., Fukuoka, JPN) ,  MATSUBARA K (Kyushu Univ., Fukuoka, JPN)
Material： Organometallics
Volume： 19  Issue： 18  Page： 3579-3590  Publication year： Sep. 04, 2000 
JST Material Number： E0965A  ISSN： 0276-7333  CODEN： ORGND7  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (3)： Platinum family element complexes  (CE01100E) ,  Organic platinum group compound  (CF09058L) ,  Organosilicon compounds  (CF08030C)

Substance index (49)： Acenaphthylene ,  (1-Hexenyl)phenyldimethylsilane ,  (2-Hexenyl)phenyldimethylsilane ,  2-Hexene ,  1,2-Bis(dimethylsilyl)ethane ,  Acetone ,  Acetophenone ,  1,2-Bis(isopropoxydimethylsilyl)ethane ,  1,2-Bis(α-methylbenzyloxydimethylsilyl)ethane ,  Tetralin-1-one ,  Cyclooctanone ,  3,3-Dimethyl-2-butanone ,  1-Phenylethanol ,  1,2-Bis(tetralin-1-yloxydimethylsilyl)ethane ,  Tetralin-1-ol ,  1,2-Bis(cyclooctyloxydimethylsilyl)ethane ,  Cyclooctanol ,  1,2-Bis(1,2,2-trimethylpropoxydimethylsilyl)ethane ,  4-tert-Butylcyclohexanone ,  1,2-Bis[(4α-tert-butylcyclohexane-1α-yloxy)dimethylsilyl]ethane ,  1,2-Bis[(4β-tert-butylcyclohexane-1α-yloxy)dimethylsilyl]ethane ,  1α-(Phenyldimethylsiloxy)-4α-tert-butylcyclohexane ,  1α-(Dimethylphenylsiloxy)-4β-tert-butylcyclohexane ,  1α-(Triethylsiloxy)-4α-tert-butylcyclohexane ,  1α-(Triethylsiloxy)-4β-tert-butylcyclohexane ,  1α-(Triphenylsiloxy)-4α-tert-butylcyclohexane ,  1α-(Triphenylsiloxy)-4β-tert-butylcyclohexane ,  1α-(Diphenylsiloxy)-4α-tert-butylcyclohexane ,  1α-(Diphenylsiloxy)-4β-tert-butylcyclohexane ,  4,7-Megastigmadien-9-one ,  Citral ,  4-Methyl-3-penten-2-one ,  1-Acetyl-1-cyclohexene ,  1,2-Bis[[1-methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-1-propenyloxy]dimethylsilyl]ethane ,  1,2-Bis[(3,7-dimethyl-2,6-octadienyloxy)dimethylsilyl]ethane ,  1-(Diphenylsiloxy)-3,7-dimethyl-2,6-octadiene ,  1,2-Bis[(1,3-dimethyl-2-butenyloxy)dimethylsilyl]ethane ,  1,2-Bis[(1-cyclohexenyloxy)dimethylsilyl]ethane ,  2-Cyclohexenyloxydiphenylsilane ,  1,2-Bis[[1-(1-cyclohexenyl)ethoxy]dimethylsilyl]ethane ,  1,2-Bis[(1-cyclohexylideneethoxy)dimethylsilyl]ethane ,  Benzaldehyde dimethyl acetal ,  Styrene oxide ,  Cyclohexene oxide ,  Tetrahydrofuran ,  Methyl benzyl ether ,  Phenylethyl alcohol ,  Cyclohexanol ,  Butoxydimethylphenylsilane

Terms in the title (13)： アセナフチレン ,  CO ,  Si-H結合 ,  触媒 ,  活性化 ,  酸化的付加 ,  単離 ,  アルデヒド ,  ケトン ,  アセタール ,  ヒドロシリル化 ,  環状エーテル ,  重合