Art

J-GLOBAL ID：200902137626417210   Reference number：00A0770815

Fluoride Ion-Mediated Intramolecular Aldol Cyclization of 7-(t-Butyldimethylsiloxy)-7-octenal.

ふっ化物イオンの仲介による7-(t-ブチルジメチルシロキシ)-7-オクテナールの分子内アルドール環化

Author (5)： HACHIYA I (Sci. Univ. Tokyo, Tokyo) ,  KOBAYASHI N (Sci. Univ. Tokyo, Tokyo) ,  KIJIMA H (Sci. Univ. Tokyo, Tokyo) ,  PUDHOM K (Sci. Univ. Tokyo, Tokyo) ,  MUKAIYAMA T (Sci. Univ. Tokyo, Tokyo)
Material： Chemistry Letters  (Chem Lett)
Issue： 8  Page： 932-933  Publication year： Aug. 05, 2000 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： cyclization reaction ,...
Semi thesaurus term： *Aldol condensation

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JST classification (2)： Aliphatic aldehydes  (CF03180F) ,  7 or more-membered monocyclic alicyclic compounds  (CF04060H)

Substance index (5)： Tetrabutylammonium fluoride ,  2,6,6-Trimethyl-4α,8β-bis(benzyloxy)-5α-(p-methoxybenzyloxy)-7β-(tert-butyldimethylsilyloxy)-2-cyclooctene-1-one ,  (2R,3R,5R,6R)-2,6-Bis(benzyloxy)-3-(p-methoxybenzyloxy)-4,4-dimethyl-5,7-bis(tert-butyldimethylsilyloxy)-7-nonenal ,  (2R,3R,5R,6R)-2,6-Bis(benzyloxy)-3-(p-methoxybenzyloxy)-4,4-dimethyl-5,7-bis(tert-butyldimethylsilyloxy)-7-octenal ,  (2R,3R,5S)-2-(Benzyloxy)-3-(p-methoxybenzyloxy)-4,4-dimethyl-5-(tert-butyldimethylsilyloxy)-7-(triisopropylsilyloxy)-7-octenal

Reference (25)：

• 1) J. Mulzer, in “Comprehensive Organic Synthesis,” ed. by B. M. Trost, I. Fleming, and E. Winterfeldt, Pergamon Press, Oxford, U. K. (1991), Vol. 6, p. 323;
•  G. Rousseau, Tetrahedron, 51, 2777 (1995).
• 2) J. Tsuji, “Palladium Reagents and Catalysts. Innovations in Organic Synthesis,” John Wiley, New York (1995);
•  J. T. Link and L. E. Overman, in “Metal-catalyzed Cross Coupling Reactions in Organic Synthesis,” ed. by F. Diederich and P. J. Stang, Wiley–VCH, Weinheim (1998), Chap. 6, p. 231.
• 3) T. N. Mittchell, in “Metal-catalyzed Cross Coupling Reactions in Organic Synthesis,” ed. by F. Diederich and P. J. Stang, Wiley–VCH, Weinheim (1998), Chap. 4, p. 167.

Terms in the title (4)： ふっ化物イオン ,  仲介 ,  アルドール ,  環化